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Solvent-Induced Galvanoluminescence of Metal–Organic Framework Electroluminescent Diodes
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    Solvent-Induced Galvanoluminescence of Metal–Organic Framework Electroluminescent Diodes
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    Max-Planck Institute for Polymer Research, Ackermannweg 10, 55128, Mainz, Germany
    Soft Condensed Matter, Debye Institute, Utrecht University, Princetonplein 5, 3584 CC, Utrecht, The Netherlands
    § Molecular Materials and Nanosystems, Eindhoven University of Technology, 5600 MB Eindhoven, The Netherlands
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    The Journal of Physical Chemistry C

    Cite this: J. Phys. Chem. C 2016, 120, 20, 11045–11048
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    https://doi.org/10.1021/acs.jpcc.6b03846
    Published May 11, 2016
    Copyright © 2016 American Chemical Society

    Abstract

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    Alternating current (AC) electroluminescent diodes were fabricated from MOF-5, a metal organic framework consisting of tetrahedral [Zn4O]6+ units linked by 1,4-benzenedicarboxylate ligands. An additional insulating layer was incorporated to prevent formation of electrical shorts. The electroluminescence spectrum was dramatically red-shifted with respect to the photoluminescence spectrum. By deliberately varying trapped solvent molecules, we demonstrate that the light emission does not originate from MOF-5 but is due to galvanoluminescence, emission of weak optical radiation in the visible region that occurs during anodic oxidation of the Al top electrode in contact with electrolytes.

    Copyright © 2016 American Chemical Society

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    This article is cited by 12 publications.

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    The Journal of Physical Chemistry C

    Cite this: J. Phys. Chem. C 2016, 120, 20, 11045–11048
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.jpcc.6b03846
    Published May 11, 2016
    Copyright © 2016 American Chemical Society

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