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Upconverting Nanoparticles Working As Primary Thermometers In Different Media

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† Departamento de Física and CICECO-Aveiro Institute of Materials, Universidade de Aveiro, 3810−193 Aveiro (Portugal)
‡ Departamento de Química and CICECO-Aveiro Institute of Materials, Universidade de Aveiro, 3810−193 Aveiro (Portugal)
*(L.D.C.) E-mail: [email protected]
Cite this: J. Phys. Chem. C 2017, 121, 25, 13962–13968
Publication Date (Web):June 9, 2017
https://doi.org/10.1021/acs.jpcc.7b04827
Copyright © 2017 American Chemical Society
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    Abstract

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    In the past decade, noninvasive luminescent thermometry has become popular due to the limitations of traditional contact thermometers to operate at scales below 100 μm, as required by current demands in disparate areas. Generally, the calibration procedure requires an independent measurement of the temperature to convert the thermometric parameter (usually an intensity ratio) to temperature. A new calibration procedure is necessary whenever the thermometer operates in a different medium. However, recording multiple calibrations is a time-consuming task, and not always possible to perform, e.g., in living cells and in electronic devices. Typically, a unique calibration relation is assumed to be valid, independent of the medium, which is a bottleneck of the secondary luminescent thermometers developed up to now. Here we report a straightforward method to predict the temperature calibration curve of any upconverting thermometer based on two thermally coupled electronic levels independently of the medium, demonstrating that these systems are intrinsically primary thermometers. SrF2:Yb/Er powder and water suspended nanoparticles were used as an illustrative example.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.jpcc.7b04827.

    • Additional experimental procedures concerning (i) the synthesis and the structural characterization of the nanoparticles and (ii) the upconversion measurements, including luminous flux and quantum yield; emission spectra and calibration curves of SrF2-2 and SrF2-3 in powders; method of energy gap determination; parameters characterizing the thermometer’s performance; thermometric parameter in the limit of low laser power density; calculated temperature for SrF2-2 and SrF2-3 in powders; and upconversion emission spectra of SrF2-4 in water suspension (PDF)

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