Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect
ACS Publications. Most Trusted. Most Cited. Most Read
The Degradation and Blinking of Single CsPbI3 Perovskite Quantum Dots

OR SEARCH CITATIONS

My Activity
Publications

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Phys. Chem. C 2018, 122, 25, 13407-13415
    Article

    The Degradation and Blinking of Single CsPbI3 Perovskite Quantum Dots
    Click to copy article linkArticle link copied!

    • Gangcheng Yuan
      Gangcheng Yuan
      ARC Centre of Excellence in Exciton Science, School of Chemistry, University of Melbourne, Parkville, Victoria 3010, Australia
      More by Gangcheng Yuan
    • Cameron Ritchie
      Cameron Ritchie
      ARC Centre of Excellence in Exciton Science, School of Chemistry, University of Melbourne, Parkville, Victoria 3010, Australia
      More by Cameron Ritchie
    • Maria Ritter
      Maria Ritter
      ARC Centre of Excellence in Exciton Science, School of Chemistry, University of Melbourne, Parkville, Victoria 3010, Australia
      More by Maria Ritter
    • Sean Murphy
      Sean Murphy
      ARC Centre of Excellence in Exciton Science, School of Chemistry, University of Melbourne, Parkville, Victoria 3010, Australia
      More by Sean Murphy
    • Daniel E. Gómez
      Daniel E. Gómez
      RMIT University, Melbourne, Victoria 3000, Australia
      More by Daniel E. Gómez
      Orcidhttp://orcid.org/0000-0002-7871-4068
    • Paul Mulvaney*
      Paul Mulvaney
      ARC Centre of Excellence in Exciton Science, School of Chemistry, University of Melbourne, Parkville, Victoria 3010, Australia
      *E-mail: [email protected]
      More by Paul Mulvaney
      Orcidhttp://orcid.org/0000-0002-8007-3247
    Other Access OptionsSupporting Information (1)

    The Journal of Physical Chemistry C

    Cite this: J. Phys. Chem. C 2018, 122, 25, 13407–13415
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.jpcc.7b11168
    Published December 15, 2017
    Copyright © 2017 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    We demonstrate using single molecule spectroscopy that inorganic CsPbI3 perovskite quantum dots (PQDs) undergo an irreversible, photoaccelerated reaction with water that results in a blue-shift of the photoluminescence (PL) and ultimately to complete quenching of the emission. We find that decomposition does not take place in the presence of oxygen alone but that it requires light and water. We also analyze the blinking for some stable PQDs and find a continuous distribution of emission states with a linear correlation between intensity and lifetime. We postulate that, in addition to charging and discharging processes, blinking arises from the activation and deactivation of nonradiative recombination centers in the PQDs.

    Copyright © 2017 American Chemical Society

    Subjects

    what are subjects

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Supporting Information

    Click to copy section linkSection link copied!

    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.jpcc.7b11168.

    • Figure S1: schematic of the chamber for measurement. Figure S2: absorption spectra, emission spectra, and a TEM image of CsPbBr3 PQDs. Figure S3: continuous confocal scanning PL images of CsPbBr3 PQDs. Figure S4: the correlation between the PL intensity and the PL lifetime. Figure S5: probability distribution of on durations is fitted to a biexponential function. A brief description of the calculation of QD-size-based effective mass approximation (EMA) (PDF)

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!

    This article is cited by 116 publications.

    1. Bo Wang, Jia Wei Melvin Lim, Siow Mean Loh, Rishikanta Mayengbam, Senyun Ye, Minjun Feng, Huajun He, Xiao Liang, Rui Cai, Qiannan Zhang, Leong-Chuan Kwek, Hilmi Volkan Demir, Subodh G. Mhaisalkar, Steven A. Blundell, Tze Chien Sum. Weakly Confined Organic–Inorganic Halide Perovskite Quantum Dots as High-Purity Room-Temperature Single Photon Sources. ACS Nano 2024, 18 (16) , 10807-10817. https://doi.org/10.1021/acsnano.3c12311
    2. Yuchen Zhang, Jiayue Xu, Tingxun Yan, Jiahao Pan, Xing Xing, Zhenda Lu. Illuminating the Nanoparticle Array: Unveiling the Interplay between Photodegradation and Aggregation Degree of CsPbBr3 Nanocrystals. The Journal of Physical Chemistry C 2023, 127 (33) , 16545-16552. https://doi.org/10.1021/acs.jpcc.3c04062
    3. Jinwoo Park, Kyung Yeon Jang, Song Hee Lee, Dong-Hyeok Kim, So-Hye Cho, Tae-Woo Lee. Stable Orthorhombic CsPbBr3 Light Emitters: Encapsulation-Assisted In Situ Synthesis. Chemistry of Materials 2023, 35 (16) , 6266-6273. https://doi.org/10.1021/acs.chemmater.3c00732
    4. Yiyue Zhang, Lata Chouhan, Eduard Fron, Luca Leoncino, Karim Elkhouly, Harshita Bhatia, Weiming Qiu, Maarten B.J. Roeffaers, Johan Hofkens, Elke Debroye, Bapi Pradhan. Operationally Stable and Efficient CsPbI3–xBrx Perovskite Nanocrystal Light-Emitting Diodes Enabled by Ammonium Ligand Surface Treatment. ACS Photonics 2023, 10 (8) , 2774-2783. https://doi.org/10.1021/acsphotonics.3c00480
    5. Chenjia Mi, Matthew L. Atteberry, Varun Mapara, Lamia Hidayatova, Gavin C. Gee, Madalina Furis, Wai Tak Yip, Binbin Weng, Yitong Dong. Biexciton-like Auger Blinking in Strongly Confined CsPbBr3 Perovskite Quantum Dots. The Journal of Physical Chemistry Letters 2023, 14 (23) , 5466-5474. https://doi.org/10.1021/acs.jpclett.3c01145
    6. Sumanta Paul, Gautam Kishore, Anunay Samanta. Photoluminescence Blinking of Quantum Confined CsPbBr3 Perovskite Nanocrystals: Influence of Size. The Journal of Physical Chemistry C 2023, 127 (21) , 10207-10214. https://doi.org/10.1021/acs.jpcc.3c01336
    7. Xiaohe Zhou, Riya Bose, Xiangyu Zhu, Abhas Mehta, Moon J. Kim, Anton V. Malko. Highly Emissive Zero-Dimensional Cesium Lead Iodide Perovskite Nanocrystals with Thermally Activated Delayed Photoluminescence. The Journal of Physical Chemistry Letters 2023, 14 (12) , 2933-2939. https://doi.org/10.1021/acs.jpclett.3c00219
    8. Aito Takeuchi, Yoshitaka Kumabe, Takashi Tachikawa. Intricate Reaction Pathways on CH3NH3PbI3 Photocatalysts in Aqueous Solution Unraveled by Single-Particle Spectroscopy. The Journal of Physical Chemistry Letters 2023, 14 (10) , 2565-2572. https://doi.org/10.1021/acs.jpclett.3c00350
    9. Daocheng Hong, Yuchen Zhang, Shuhan Pan, Hanyu Liu, Wei Mao, Zhenda Lu, Yuxi Tian. Moisture-Dependent Blinking of Individual CsPbBr3 Nanocrystals Revealed by Single-Particle Spectroscopy. The Journal of Physical Chemistry Letters 2022, 13 (46) , 10751-10758. https://doi.org/10.1021/acs.jpclett.2c03159
    10. Michael K. Abney, Mokshin Suri, Tushti Shah, Francis Leonard Deepak, Brian A. Korgel. Reversible Light-Induced Enhancement of Photoluminescence Lifetime and Intensity in Perovskite-Phase CsPbI3 Nanocrystals. The Journal of Physical Chemistry C 2022, 126 (30) , 12712-12720. https://doi.org/10.1021/acs.jpcc.2c04305
    11. Sumanta Paul, Anunay Samanta. Phase-Stable and Highly Luminescent CsPbI3 Perovskite Nanocrystals with Suppressed Photoluminescence Blinking. The Journal of Physical Chemistry Letters 2022, 13 (25) , 5742-5750. https://doi.org/10.1021/acs.jpclett.2c01463
    12. Tasnim Ahmed, Sumanta Paul, Anunay Samanta. Photoluminescence Blinking Revealing Static and Dynamic Heterogeneity of the Hole Transfer Process in Phenothiazine-Adsorbed FAPbBr3 Single Nanocrystals. The Journal of Physical Chemistry C 2022, 126 (21) , 9109-9116. https://doi.org/10.1021/acs.jpcc.2c02521
    13. Chenglian Zhu, Malwina Marczak, Leon Feld, Simon C. Boehme, Caterina Bernasconi, Anastasiia Moskalenko, Ihor Cherniukh, Dmitry Dirin, Maryna I. Bodnarchuk, Maksym V. Kovalenko, Gabriele Rainò. Room-Temperature, Highly Pure Single-Photon Sources from All-Inorganic Lead Halide Perovskite Quantum Dots. Nano Letters 2022, 22 (9) , 3751-3760. https://doi.org/10.1021/acs.nanolett.2c00756
    14. E. Krishnan Vishnu, Anoop Ajaya Kumar Nair, K. George Thomas. Core-Size-Dependent Trapping and Detrapping Dynamics in CdSe/CdS/ZnS Quantum Dots. The Journal of Physical Chemistry C 2021, 125 (46) , 25706-25716. https://doi.org/10.1021/acs.jpcc.1c08137
    15. Saptarshi Mandal, Swarnali Ghosh, Soumen Mukherjee, Debjit Roy, Chayan K. De, Kingshuk Mukhuti, Prasun K. Mandal. Near-Ergodic CsPbBr3 Perovskite Nanocrystal with Minimal Statistical Aging. The Journal of Physical Chemistry Letters 2021, 12 (41) , 10169-10174. https://doi.org/10.1021/acs.jpclett.1c02326
    16. Riya Bose, Xiaohe Zhou, Tianle Guo, Haoze Yang, Jun Yin, Aditya Mishra, Jason D. Slinker, Osman M. Bakr, Omar F. Mohammed, Anton V. Malko. Single-Particle Spectroscopy as a Versatile Tool to Explore Lower-Dimensional Structures of Inorganic Perovskites. ACS Energy Letters 2021, 6 (10) , 3695-3708. https://doi.org/10.1021/acsenergylett.1c01604
    17. Amitrajit Mukherjee, Mrinmoy Roy, Nithin Pathoor, Mohammed Aslam, Arindam Chowdhury. Influence of Atmospheric Constituents on Spectral Instability and Defect-Mediated Carrier Recombination in Hybrid Perovskite Nanoplatelets. The Journal of Physical Chemistry C 2021, 125 (31) , 17133-17143. https://doi.org/10.1021/acs.jpcc.1c02207
    18. Bo-Wei Hsu, Yung-Tang Chuang, Chun-Yuan Cheng, Chien-Yu Chen, Yen-Ju Chen, Alexandra Brumberg, Lin Yang, Yu-Sheng Huang, Richard D. Schaller, Lih-J. Chen, Chih-Sung Chuu, Hao-Wu Lin. Very Robust Spray-Synthesized CsPbI3 Quantum Emitters with Ultrahigh Room-Temperature Cavity-Free Brightness and Self-Healing Ability. ACS Nano 2021, 15 (7) , 11358-11368. https://doi.org/10.1021/acsnano.1c00733
    19. Amrita Dey, Junzhi Ye, Apurba De, Elke Debroye, Seung Kyun Ha, Eva Bladt, Anuraj S. Kshirsagar, Ziyu Wang, Jun Yin, Yue Wang, Li Na Quan, Fei Yan, Mengyu Gao, Xiaoming Li, Javad Shamsi, Tushar Debnath, Muhan Cao, Manuel A. Scheel, Sudhir Kumar, Julian A. Steele, Marina Gerhard, Lata Chouhan, Ke Xu, Xian-gang Wu, Yanxiu Li, Yangning Zhang, Anirban Dutta, Chuang Han, Ilka Vincon, Andrey L. Rogach, Angshuman Nag, Anunay Samanta, Brian A. Korgel, Chih-Jen Shih, Daniel R. Gamelin, Dong Hee Son, Haibo Zeng, Haizheng Zhong, Handong Sun, Hilmi Volkan Demir, Ivan G. Scheblykin, Iván Mora-Seró, Jacek K. Stolarczyk, Jin Z. Zhang, Jochen Feldmann, Johan Hofkens, Joseph M. Luther, Julia Pérez-Prieto, Liang Li, Liberato Manna, Maryna I. Bodnarchuk, Maksym V. Kovalenko, Maarten B. J. Roeffaers, Narayan Pradhan, Omar F. Mohammed, Osman M. Bakr, Peidong Yang, Peter Müller-Buschbaum, Prashant V. Kamat, Qiaoliang Bao, Qiao Zhang, Roman Krahne, Raquel E. Galian, Samuel D. Stranks, Sara Bals, Vasudevanpillai Biju, William A. Tisdale, Yong Yan, Robert L. Z. Hoye, Lakshminarayana Polavarapu. State of the Art and Prospects for Halide Perovskite Nanocrystals. ACS Nano 2021, 15 (7) , 10775-10981. https://doi.org/10.1021/acsnano.0c08903
    20. Isabelle M. Palstra, A. Femius Koenderink. A Python Toolbox for Unbiased Statistical Analysis of Fluorescence Intermittency of Multilevel Emitters. The Journal of Physical Chemistry C 2021, 125 (22) , 12050-12060. https://doi.org/10.1021/acs.jpcc.1c01670
    21. Isabelle M. Palstra, Ilse Maillette de Buy Wenniger, Biplab K. Patra, Erik C. Garnett, A. Femius Koenderink. Intermittency of CsPbBr3 Perovskite Quantum Dots Analyzed by an Unbiased Statistical Analysis. The Journal of Physical Chemistry C 2021, 125 (22) , 12061-12072. https://doi.org/10.1021/acs.jpcc.1c01671
    22. Ayendrila Das, Krishna Mishra, Subhadip Ghosh. Revealing Explicit Microsecond Carrier Diffusion from One Emission Center to Another in an All-Inorganic Perovskite Nanocrystal. The Journal of Physical Chemistry Letters 2021, 12 (22) , 5413-5422. https://doi.org/10.1021/acs.jpclett.1c01154
    23. Theodore A. Cohen, Yunping Huang, Nico A. Bricker, Connor S. Juhl, Tyler J. Milstein, J. Devin MacKenzie, Christine K. Luscombe, Daniel R. Gamelin. Modular Zwitterion-Functionalized Poly(isopropyl methacrylate) Polymers for Hosting Luminescent Lead Halide Perovskite Nanocrystals. Chemistry of Materials 2021, 33 (10) , 3779-3790. https://doi.org/10.1021/acs.chemmater.1c00902
    24. Yuning Liu, Biyu Long, Renjie Chen, Sumei Huang, Wei Ou-Yang, Xiaohong Chen. Enhanced Efficiency and Stability of NiOx-Based Perovskite Solar Cells Using [6,6]-Phenyl-C61-butyric Acid Methyl-Doped Poly(9-vinylcarbazole)-Modified Layer. ACS Applied Energy Materials 2021, 4 (4) , 3812-3821. https://doi.org/10.1021/acsaem.1c00219
    25. Kevin Ho, Mingyang Wei, Edward H. Sargent, Gilbert C. Walker. Grain Transformation and Degradation Mechanism of Formamidinium and Cesium Lead Iodide Perovskite under Humidity and Light. ACS Energy Letters 2021, 6 (3) , 934-940. https://doi.org/10.1021/acsenergylett.0c02247
    26. Saif M. H. Qaid, Hamid M. Ghaithan, Bandar Ali Al-Asbahi, Abdullah S. Aldwayyan. Achieving Optical Gain of the CsPbBr3 Perovskite Quantum Dots and Influence of the Variable Stripe Length Method. ACS Omega 2021, 6 (8) , 5297-5309. https://doi.org/10.1021/acsomega.0c05414
    27. Lata Chouhan, Syoji Ito, Elizabeth Mariam Thomas, Yuta Takano, Sushant Ghimire, Hiroshi Miyasaka, Vasudevanpillai Biju. Real-Time Blinking Suppression of Perovskite Quantum Dots by Halide Vacancy Filling. ACS Nano 2021, 15 (2) , 2831-2838. https://doi.org/10.1021/acsnano.0c08802
    28. Min Kim, Daniele Cortecchia, Tetiana Borzda, Wojciech Mróz, Luca Leoncino, David Dellasega, Soo-Hyoung Lee, Annamaria Petrozza. Coordinating Solvent-Assisted Synthesis of Phase-Stable Perovskite Nanocrystals with High Yield Production for Optoelectronic Applications. Chemistry of Materials 2021, 33 (2) , 547-553. https://doi.org/10.1021/acs.chemmater.0c03463
    29. Wenli Guo, Jialun Tang, Guofeng Zhang, Bin Li, Changgang Yang, Ruiyun Chen, Chengbing Qin, Jianyong Hu, Haizheng Zhong, Liantuan Xiao, Suotang Jia. Photoluminescence Blinking and Biexciton Auger Recombination in Single Colloidal Quantum Dots with Sharp and Smooth Core/Shell Interfaces. The Journal of Physical Chemistry Letters 2021, 12 (1) , 405-412. https://doi.org/10.1021/acs.jpclett.0c03065
    30. Dong Wang, Dongyan Zhang, Bryce Sadtler. Irreversibility in Anion Exchange Between Cesium Lead Bromide and Iodide Nanocrystals Imaged by Single-Particle Fluorescence. The Journal of Physical Chemistry C 2020, 124 (49) , 27158-27168. https://doi.org/10.1021/acs.jpcc.0c08323
    31. Wenkai Zhang, Daniel Zilevu, Sidney E. Creutz, Dongmao Zhang. Quantification of the Optical Properties of Perovskite Nanocrystals Using a Combination of Polarized Resonance Synchronous and Polarized Anti-Stokes, On-Resonance, and Stokes-Shifted Spectroscopy. The Journal of Physical Chemistry C 2020, 124 (37) , 20388-20397. https://doi.org/10.1021/acs.jpcc.0c05064
    32. Yoshua Albert Darmawan, Mitsuaki Yamauchi, Sadahiro Masuo. In Situ Observation of a Photodegradation-Induced Blueshift in Perovskite Nanocrystals Using Single-Particle Spectroscopy Combined with Atomic Force Microscopy. The Journal of Physical Chemistry C 2020, 124 (34) , 18770-18776. https://doi.org/10.1021/acs.jpcc.0c04923
    33. Riya Bose, Yangzi Zheng, Tianle Guo, Jun Yin, Mohamed Nejib Hedhili, Xiaohe Zhou, Jean-Francois Veyan, Issam Gereige, Ahmed Al-Saggaf, Yuri N. Gartstein, Osman M. Bakr, Omar F. Mohammed, Anton V. Malko. Interface Matters: Enhanced Photoluminescence and Long-Term Stability of Zero-Dimensional Cesium Lead Bromide Nanocrystals via Gas-Phase Aluminum Oxide Encapsulation. ACS Applied Materials & Interfaces 2020, 12 (31) , 35598-35605. https://doi.org/10.1021/acsami.0c07694
    34. Chunyang Yin, Yan Lv, Xiangtong Zhang, Yu Zhang, William W. Yu, Chunfeng Zhang, Zhi-Gang Yu, Xiaoyong Wang, Min Xiao. Transition from Doublet to Triplet Excitons in Single Perovskite Nanocrystals. The Journal of Physical Chemistry Letters 2020, 11 (14) , 5750-5755. https://doi.org/10.1021/acs.jpclett.0c01939
    35. Xiongjian Huang, Qianyi Guo, Shiliang Kang, Tianchang Ouyang, Qinpeng Chen, Xiaofeng Liu, Zhiguo Xia, Zhongmin Yang, Qinyuan Zhang, Jianrong Qiu, Guoping Dong. Three-Dimensional Laser-Assisted Patterning of Blue-Emissive Metal Halide Perovskite Nanocrystals inside a Glass with Switchable Photoluminescence. ACS Nano 2020, 14 (3) , 3150-3158. https://doi.org/10.1021/acsnano.9b08314
    36. Raihana Begum, Xin Yu Chin, Bahulayan Damodaran, Thomas J. N. Hooper, Subodh Mhaisalkar, Nripan Mathews. Cesium Lead Halide Perovskite Nanocrystals Prepared by Anion Exchange for Light-Emitting Diodes. ACS Applied Nano Materials 2020, 3 (2) , 1766-1774. https://doi.org/10.1021/acsanm.9b02450
    37. Dong Wang, John Cavin, Bo Yin, Arashdeep S. Thind, Albina Y. Borisevich, Rohan Mishra, Bryce Sadtler. Role of Solid-State Miscibility during Anion Exchange in Cesium Lead Halide Nanocrystals Probed by Single-Particle Fluorescence. The Journal of Physical Chemistry Letters 2020, 11 (3) , 952-959. https://doi.org/10.1021/acs.jpclett.9b03633
    38. Franziska Krieg, Quy K. Ong, Max Burian, Gabriele Rainò, Denys Naumenko, Heinz Amenitsch, Adrian Süess, Matthias J. Grotevent, Frank Krumeich, Maryna I. Bodnarchuk, Ivan Shorubalko, Francesco Stellacci, Maksym V. Kovalenko. Stable Ultraconcentrated and Ultradilute Colloids of CsPbX3 (X = Cl, Br) Nanocrystals Using Natural Lecithin as a Capping Ligand. Journal of the American Chemical Society 2019, 141 (50) , 19839-19849. https://doi.org/10.1021/jacs.9b09969
    39. Tasnim Ahmed, Sudipta Seth, Anunay Samanta. Mechanistic Investigation of the Defect Activity Contributing to the Photoluminescence Blinking of CsPbBr3 Perovskite Nanocrystals. ACS Nano 2019, 13 (11) , 13537-13544. https://doi.org/10.1021/acsnano.9b07471
    40. Tianle Guo, Riya Bose, Xiaohe Zhou, Yuri N. Gartstein, Haoze Yang, Sunah Kwon, Moon J. Kim, Marat Lutfullin, Lutfan Sinatra, Issam Gereige, Ahmed Al-Saggaf, Osman M. Bakr, Omar F. Mohammed, Anton V. Malko. Delayed Photoluminescence and Modified Blinking Statistics in Alumina-Encapsulated Zero-Dimensional Inorganic Perovskite Nanocrystals. The Journal of Physical Chemistry Letters 2019, 10 (21) , 6780-6787. https://doi.org/10.1021/acs.jpclett.9b02594
    41. Chao Zheng, Oleg Rubel. Unraveling the Water Degradation Mechanism of CH3NH3PbI3. The Journal of Physical Chemistry C 2019, 123 (32) , 19385-19394. https://doi.org/10.1021/acs.jpcc.9b05516
    42. Gabriele Rainò, Annelies Landuyt, Franziska Krieg, Caterina Bernasconi, Stefan T. Ochsenbein, Dmitry N. Dirin, Maryna I. Bodnarchuk, Maksym V. Kovalenko. Underestimated Effect of a Polymer Matrix on the Light Emission of Single CsPbBr3 Nanocrystals. Nano Letters 2019, 19 (6) , 3648-3653. https://doi.org/10.1021/acs.nanolett.9b00689
    43. Juvinch R. Vicente, Ali Rafiei Miandashti, Kurt Waldo E. Sy Piecco, Joseph R. Pyle, Martin E. Kordesch, Jixin Chen. Single-Particle Organolead Halide Perovskite Photoluminescence as a Probe for Surface Reaction Kinetics. ACS Applied Materials & Interfaces 2019, 11 (19) , 18034-18043. https://doi.org/10.1021/acsami.9b03822
    44. Lige Liu, Luogen Deng, Sheng Huang, Pei Zhang, Jan Linnros, Haizheng Zhong, Ilya Sychugov. Photodegradation of Organometal Hybrid Perovskite Nanocrystals: Clarifying the Role of Oxygen by Single-Dot Photoluminescence. The Journal of Physical Chemistry Letters 2019, 10 (4) , 864-869. https://doi.org/10.1021/acs.jpclett.9b00143
    45. Dharmendar Kumar Sharma, Shuzo Hirata, Vasudevanpillai Biju, Martin Vacha. Stark Effect and Environment-Induced Modulation of Emission in Single Halide Perovskite Nanocrystals. ACS Nano 2019, 13 (1) , 624-632. https://doi.org/10.1021/acsnano.8b07677
    46. Sudipta Seth, Tasnim Ahmed, Anunay Samanta. Photoluminescence Flickering and Blinking of Single CsPbBr3 Perovskite Nanocrystals: Revealing Explicit Carrier Recombination Dynamics. The Journal of Physical Chemistry Letters 2018, 9 (24) , 7007-7014. https://doi.org/10.1021/acs.jpclett.8b02979
    47. Bin Li, He Huang, Guofeng Zhang, Changgang Yang, Wenli Guo, Ruiyun Chen, Chengbing Qin, Yan Gao, Vasudevan P. Biju, Andrey L. Rogach, Liantuan Xiao, Suotang Jia. Excitons and Biexciton Dynamics in Single CsPbBr3 Perovskite Quantum Dots. The Journal of Physical Chemistry Letters 2018, 9 (24) , 6934-6940. https://doi.org/10.1021/acs.jpclett.8b03098
    48. Natalie A. Gibson, Brent A. Koscher, A. Paul Alivisatos, Stephen R. Leone. Excitation Intensity Dependence of Photoluminescence Blinking in CsPbBr3 Perovskite Nanocrystals. The Journal of Physical Chemistry C 2018, 122 (22) , 12106-12113. https://doi.org/10.1021/acs.jpcc.8b03206
    49. Gangcheng Yuan, Daniel E. Gómez, Nicholas Kirkwood, Klaus Boldt, Paul Mulvaney. Two Mechanisms Determine Quantum Dot Blinking. ACS Nano 2018, 12 (4) , 3397-3405. https://doi.org/10.1021/acsnano.7b09052
    50. Hyong Joon Lee, Jin Hyuck Heo, Sang Hyuk Im. Interfacial modification strategies to secure phase-stability for inorganic perovskite solar cells. Applied Physics Reviews 2024, 11 (3) https://doi.org/10.1063/5.0202332
    51. Han Xiao, Lingwei Zeng, Lei Lei, Daqin Chen. Research Progress of Femtosecond Laser‐Printed Perovskite Quantum Dots in Amorphous Glass. Annalen der Physik 2024, 17 https://doi.org/10.1002/andp.202400152
    52. Xiaoyun Wan, Cunyun Xu, Hao Wang, Zezhuan Jiang, Fuling Li, Gaobo Xu, Zhongjun Dai, Xiaofeng He, Qunliang Song. Efficient Tin–Lead Perovskite Solar Cells with a Ultrawide Usage Windows of Precursor Solution Opened by SnF 2. Small 2024, 20 (32) https://doi.org/10.1002/smll.202401136
    53. Pedro Conceição, Andrés Perdomo, Diogo F. Carvalho, Jennifer P. Teixeira, Pedro M. P. Salomé, Tito Trindade. Sonochemical-assisted synthesis of CsPbBr 3 perovskite quantum dots using vegetable oils. Green Chemistry 2024, 26 (13) , 7837-7848. https://doi.org/10.1039/D4GC00759J
    54. Yufei Liu, Jianting Lin, Qiang Han, Chenggang Yang, Lin Li, Jianrong Xiao, Rongnan Yi, Xiaoliang Liu. Phase transition mechanism of CsPbI 2 Br perovskite films induced by moisture. Journal of Physics D: Applied Physics 2024, 57 (24) , 245103. https://doi.org/10.1088/1361-6463/ad31e2
    55. Yitong Dong, Chenjia Mi, Gavin Gee, Chance Lander, Matthew Atteberry, Novruz Akhmedov, Lamia Hidayatova, Jesse DiCenso, Wai Tak Yip, Yihan Shao. Towards non-blinking perovskite quantum dots. 2024https://doi.org/10.21203/rs.3.rs-4214840/v1
    56. Changgang Yang, Guofeng Zhang, Yunan Gao, Bin Li, Xue Han, Jialu Li, Mi Zhang, Zhihao Chen, Yixin Wei, Ruiyun Chen, Chengbing Qin, Jianyong Hu, Zhichun Yang, Ganying Zeng, Liantuan Xiao, Suotang Jia. Size-dependent photoluminescence blinking mechanisms and volume scaling of biexciton Auger recombination in single CsPbI3 perovskite quantum dots. The Journal of Chemical Physics 2024, 160 (17) https://doi.org/10.1063/5.0199389
    57. Aryamol Stephen, A. Biju, Sona C. P, Jayaram Peediyekkal. Recent trends in synthesis, properties, and applications of CsPbX3 quantum dots: A review. Journal of Luminescence 2024, 269 , 120462. https://doi.org/10.1016/j.jlumin.2024.120462
    58. Bin Li, Guofeng Zhang, Yuke Gao, Xiaopeng Chen, Ruiyun Chen, Chengbing Qin, Jianyong Hu, Ruixiang Wu, Liantuan Xiao, Suotang Jia. Single quantum dot spectroscopy for exciton dynamics. Nano Research 2024, 116 https://doi.org/10.1007/s12274-024-6504-x
    59. Mrinmoy Roy, Milan Sykora, M. Aslam. Chemical Aspects of Halide Perovskite Nanocrystals. Topics in Current Chemistry 2024, 382 (1) https://doi.org/10.1007/s41061-024-00453-0
    60. Vanna Chrismas Silalahi, Dokyum Kim, Minjun Kim, Samir Adhikari, Seongmoon Jun, Yong-Hoon Cho, Donghan Lee, Chang-Lyoul Lee, Yudong Jang. Over a thousand-fold enhancement of the spontaneous emission rate for stable core−shell perovskite quantum dots through coupling with novel plasmonic nanogaps. Nanophotonics 2024, 13 (3) , 369-376. https://doi.org/10.1515/nanoph-2023-0751
    61. Han Xiao, Jidong Lin, Ronghua Chen, Tao Pang, Ping Huang, Yunlong Yu, Bin Zhuang, Qingying Ye, Ruidan Zhang, Daqin Chen. Humidity‐Induced Reversible Crystallization of Laser‐Printing Perovskite Quantum Dots in Glass. Laser & Photonics Reviews 2024, 18 (1) https://doi.org/10.1002/lpor.202300705
    62. Shuo Wang, Qian Zhao, Abhijit Hazarika, Simiao Li, Yue Wu, Yaxin Zhai, Xihan Chen, Joseph M. Luther, Guoran Li. Thermal tolerance of perovskite quantum dots dependent on A-site cation and surface ligand. Nature Communications 2023, 14 (1) https://doi.org/10.1038/s41467-023-37943-6
    63. V. A Baitova, M. A Knyazeva, I. A Mukanov, A. O Tarasevich, A. V Naumov, A. G Son, S. A Kozyukhin, I. Yu Eremchev. Evolyutsiya lyuminestsentnykh svoystv odinochnykh nanokristallov perovskita CsPbBr3 v protsesse fotodegradatsii. Pisʹma v žurnal êksperimentalʹnoj i teoretičeskoj fiziki 2023, 118 (7-8 (10)) , 570-577. https://doi.org/10.31857/S1234567823200041
    64. V. A. Baitova, M. A. Knyazeva, I. A. Mukanov, A. O. Tarasevich, A. V. Naumov, A. G. Son, S. A. Kozyukhin, I. Yu. Eremchev. Evolution of the Luminescence Properties of Single CsPbBr3 Perovskite Nanocrystals During Photodegradation. JETP Letters 2023, 118 (8) , 560-567. https://doi.org/10.1134/S002136402360283X
    65. Mohammed Abdul Haque, Amruta Lohar, Richa Gahlaut, Imran Shaikh, Shrikrishna Sartale, Shailaja Mahamuni. The effect of surface treatment and polymer matrix on photoluminescence intermittency of strongly confined CsPbBr3 quantum dots. Journal of Materials Science: Materials in Electronics 2023, 34 (22) https://doi.org/10.1007/s10854-023-11016-2
    66. Sanghun Han, Gayoung Seo, Taeyeong Yong, Seongmin Choi, Younghoon Kim, Jongmin Choi. Stabilized Perovskite Quantum Dot Solids via Nonpolar Solvent Dispersible Covalent Ligands. Advanced Science 2023, 10 (23) https://doi.org/10.1002/advs.202301793
    67. Toranosuke Takagi, Shun Omagari, Martin Vacha. Suppression of blinking in single CsPbBr 3 perovskite nanocrystals through surface ligand exchange. Physical Chemistry Chemical Physics 2023, 25 (28) , 19004-19012. https://doi.org/10.1039/D3CP01844J
    68. Dongyan Zhang, Xinyi Sarah Wu, Dong Wang, Bryce Sadtler. Size-dependent miscibility controls the kinetics of anion exchange in cesium lead halide nanocrystals. The Journal of Chemical Physics 2023, 159 (1) https://doi.org/10.1063/5.0149821
    69. Ashutosh Mohapatra, Shamit Kumar, Tusar Kanta Acharya, Chandan Goswami, Saikat Bhaumik. Highly stable multi-encapsulated red-emitting cesium lead halide nanocrystals for efficient copper ion detection and imaging in live cells. Journal of Alloys and Compounds 2023, 947 , 169453. https://doi.org/10.1016/j.jallcom.2023.169453
    70. Subitan Laskar, Athrey C Dakshinamurthy, Sivakumar Chithamallu, C. Sudarshan, C. Sudakar. Whispering gallery mode micro-lasing in CsPbI 3 quantum dots coated on TiO 2 microspherical resonating cavities. Optics Letters 2023, 48 (10) , 2643. https://doi.org/10.1364/OL.487579
    71. Hayeon Won, Jong-Hwa Kim, Jinjoo Jung, Do-Hyung Kim. A comparative study on the optical and structural degradation behaviors and enhanced stability of CsPbBr3 embedded in oxide barriers. Solid State Sciences 2023, 136 , 107087. https://doi.org/10.1016/j.solidstatesciences.2022.107087
    72. Seyeong Lim, Sanghun Han, Dohyun Kim, Jihyun Min, Jongmin Choi, Taiho Park. Key Factors Affecting the Stability of CsPbI 3 Perovskite Quantum Dot Solar Cells: A Comprehensive Review. Advanced Materials 2023, 35 (4) https://doi.org/10.1002/adma.202203430
    73. Ashutosh Mohapatra, Manav R. Kar, Saikat Bhaumik. Suppression of halide migration and improved stability in double-coated cesium lead halide perovskite nanocrystals for application in down-conversion white-light-emitting diodes. Journal of Alloys and Compounds 2022, 927 , 166972. https://doi.org/10.1016/j.jallcom.2022.166972
    74. Siqi Sun, Pei Jia, Qizhang Huang, Min Lu, Po Lu, Feisong Qin, Guang Sun, Yanbo Gao, Xue Bai, Zhennan Wu, Yu Zhang. Spectrally stable and efficient pure-blue light-emitting diodes based on CsPb(Br/Cl)3 nanocrystals with surface passivation by organic sulfonate. Materials Today Physics 2022, 28 , 100899. https://doi.org/10.1016/j.mtphys.2022.100899
    75. Antoine Dumont, Eric Nicholson, Chenyue Qiu, Jinbo Pan, Zachary Gariepy, Shixuan Du, Jane Howe, Chandra Veer Singh, Zheng‐Hong Lu. Restructuring and Reshaping of CsPbX 3 Perovskites by Lithium Salts. Advanced Materials Interfaces 2022, 9 (30) https://doi.org/10.1002/admi.202201296
    76. Siqi Sun, Pei Jia, Min Lu, Po Lu, Yanbo Gao, Yuan Zhong, Chengyuan Tang, Yu Zhang, Zhennan Wu, Jinyang Zhu, Yuantao Zhang, William W. Yu, Xue Bai. Enhanced Flexibility and Stability of Emissive Layer Enable High‐Performance Flexible Light‐Emitting Diodes by Cross‐Linking of Biomass Material. Advanced Functional Materials 2022, 32 (33) https://doi.org/10.1002/adfm.202204286
    77. Roberto N. Muñoz, Laszlo Frazer, Gangcheng Yuan, Paul Mulvaney, Felix A. Pollock, Kavan Modi. Memory in quantum dot blinking. Physical Review E 2022, 106 (1) https://doi.org/10.1103/PhysRevE.106.014127
    78. Zhixing Wu, Zhiying Feng, Yikun Hua, Chaocang Weng, Xiaohong Chen, Sumei Huang. Synergetic effect of organic metal compound modified SnO2 in high performance perovskite solar cells. Solar Energy 2022, 234 , 170-178. https://doi.org/10.1016/j.solener.2022.02.009
    79. José Mendoza Carreño, Nicolás Passarelli, Clara Otero‐Martínez, Lakshminarayana Polavarapu, Luis A. Pérez, Juan Sebastián Reparaz, María Isabel Alonso, Agustín Mihi. Enhanced Photoluminescence of Cesium Lead Halide Perovskites by Quasi‐3D Photonic Crystals. Advanced Optical Materials 2022, 10 (3) https://doi.org/10.1002/adom.202101324
    80. Zhen Wang, Zeyu Zhang, Li Xie, Shurong Wang, Chenguang Yang, Changqing Fang, Feng Hao. Recent Advances and Perspectives of Photostability for Halide Perovskite Solar Cells. Advanced Optical Materials 2022, 10 (3) https://doi.org/10.1002/adom.202101822
    81. Yunping Huang, Theodore A. Cohen, Breena M. Sperry, Helen Larson, Hao A. Nguyen, Micaela K. Homer, Florence Y. Dou, Laura M. Jacoby, Brandi M. Cossairt, Daniel R. Gamelin, Christine K. Luscombe. Organic building blocks at inorganic nanomaterial interfaces. Materials Horizons 2022, 9 (1) , 61-87. https://doi.org/10.1039/D1MH01294K
    82. Bin Li, Guo-Feng Zhang, Rui-Yun Chen, Cheng-Bing Qin, Jian-Yong Hu, Lian-Tuan Xiao, Suo-Tang Jia, , . Research progress of single quantum-dot spectroscopy and exciton dynamics. Acta Physica Sinica 2022, 71 (6) , 067802. https://doi.org/10.7498/aps.71.20212050
    83. Noor Fitrah Abu Bakar, Huey Ling Tan, Ying Pei Lim, Nadia Adrus, Jaafar Abdullah. Environmental impact of quantum dots. 2022, 837-867. https://doi.org/10.1016/B978-0-323-85457-3.00011-6
    84. Ashutosh Mohapatra, Manav Raj Kar, Saikat Bhaumik. Suppression of Halide Migration and Improved Stability in Double-Coated Cesium Lead Halide Perovskite Nanocrystals for Application in Down-Conversion White-Light-Emitting Diodes. SSRN Electronic Journal 2022, 6 https://doi.org/10.2139/ssrn.4119154
    85. Mrinmoy Roy, Vikram, Bhawna, Aftab Alam, M. Aslam. Photoinduced quasi-2D to 3D phase transformation in hybrid halide perovskite nanoplatelets. Physical Chemistry Chemical Physics 2021, 23 (48) , 27355-27364. https://doi.org/10.1039/D1CP03529K
    86. Hamid Pashaei Adl, Setatira Gorji, Guillermo Muñoz-Matutano, Raúl I. Sánchez-Alarcón, Rafael Abargues, Andrés F. Gualdrón-Reyes, Iván Mora-Seró, Juan P. Martínez-Pastor. Homogeneous and inhomogeneous broadening in single perovskite nanocrystals investigated by micro-photoluminescence. Journal of Luminescence 2021, 240 , 118453. https://doi.org/10.1016/j.jlumin.2021.118453
    87. Handong Jin, Julian A. Steele, Ruolin Cheng, Nagma Parveen, Maarten B. J. Roeffaers, Johan Hofkens, Elke Debroye. Experimental Evidence of Chloride‐Induced Trap Passivation in Lead Halide Perovskites through Single Particle Blinking Studies. Advanced Optical Materials 2021, 9 (23) https://doi.org/10.1002/adom.202002240
    88. Shuang Liang, Mingyue Zhang, Gill M. Biesold, Woosung Choi, Yanjie He, Zili Li, Dingfeng Shen, Zhiqun Lin. Recent Advances in Synthesis, Properties, and Applications of Metal Halide Perovskite Nanocrystals/Polymer Nanocomposites. Advanced Materials 2021, 33 (50) https://doi.org/10.1002/adma.202005888
    89. Nathan D. Cottam, Chengxi Zhang, Joni L. Wildman, Amalia Patanè, Lyudmila Turyanska, Oleg Makarovsky. Light‐Induced Stark Effect and Reversible Photoluminescence Quenching in Inorganic Perovskite Nanocrystals. Advanced Optical Materials 2021, 9 (13) https://doi.org/10.1002/adom.202100104
    90. Yanyan Zhao, Cunjin Wang, Xiaoyun Hu, Jun Fan. Recent Progress in CsPbX 3 Perovskite Nanocrystals for Enhanced Stability and Photocatalytic Applications. ChemNanoMat 2021, 7 (7) , 789-804. https://doi.org/10.1002/cnma.202100094
    91. Tianyu Chen, Mengna Huang, Zhongju Ye, Jianhao Hua, Shen Lin, Lin Wei, Lehui Xiao. Blinking CsPbBr3 perovskite nanocrystals for the nanoscopic imaging of electrospun nanofibers. Nano Research 2021, 14 (5) , 1397-1404. https://doi.org/10.1007/s12274-020-3189-7
    92. Saptarshi Mandal, Swarnali Ghosh, Soumen Mukherjee, Chayan K. De, Debjit Roy, Tridib Samanta, Prasun K. Mandal. Unravelling halide-dependent charge carrier dynamics in CsPb(Br/Cl) 3 perovskite nanocrystals. Nanoscale 2021, 13 (6) , 3654-3661. https://doi.org/10.1039/D0NR08428J
    93. Bin Li, Xiang-Yang Miao, . Photoluminescence blinking properties of single CsPbBr<sub>3</sub> perovskite quantum dots. Acta Physica Sinica 2021, 70 (20) , 207802. https://doi.org/10.7498/aps.70.20210908
    94. Yingying Tang, Arnon Lesage, Peter Schall. CsPbI 3 nanocrystal films: towards higher stability and efficiency. Journal of Materials Chemistry C 2020, 8 (48) , 17139-17156. https://doi.org/10.1039/D0TC04475J
    95. Cong Tai Trinh, Duong Nguyen Minh, Kwang Jun Ahn, Youngjong Kang, Kwang-Geol Lee. Verification of Type-A and Type-B-HC Blinking Mechanisms of Organic–Inorganic Formamidinium Lead Halide Perovskite Quantum Dots by FLID Measurements. Scientific Reports 2020, 10 (1) https://doi.org/10.1038/s41598-020-58926-3
    96. Xue Han, Guofeng Zhang, Bin Li, Changgang Yang, Wenli Guo, Xiuqing Bai, Peng Huang, Ruiyun Chen, Chengbing Qin, Jianyong Hu, Yifei Ma, Haizheng Zhong, Liantuan Xiao, Suotang Jia. Blinking Mechanisms and Intrinsic Quantum‐Confined Stark Effect in Single Methylammonium Lead Bromide Perovskite Quantum Dots. Small 2020, 16 (51) https://doi.org/10.1002/smll.202005435
    97. Zhibin Shangguan, Xi Zheng, Jing Zhang, Wansheng Lin, Weijie Guo, Cheng Li, Tingzhu Wu, Yue Lin, Zhong Chen. The Stability of Metal Halide Perovskite Nanocrystals—A Key Issue for the Application on Quantum-Dot-Based Micro Light-Emitting Diodes Display. Nanomaterials 2020, 10 (7) , 1375. https://doi.org/10.3390/nano10071375
    98. Tejmani Behera, Nithin Pathoor, Chinmay Phadnis, Susmita Buragohain, Arindam Chowdhury. Spatially correlated photoluminescence blinking and flickering of hybrid-halide perovskite micro-rods. Journal of Luminescence 2020, 223 , 117202. https://doi.org/10.1016/j.jlumin.2020.117202
    99. Lata Chouhan, Sushant Ghimire, Challapalli Subrahmanyam, Tsutomu Miyasaka, Vasudevanpillai Biju. Synthesis, optoelectronic properties and applications of halide perovskites. Chemical Society Reviews 2020, 49 (10) , 2869-2885. https://doi.org/10.1039/C9CS00848A
    100. Kieran O. Russell, Mark A. Osborne, Aidan A. E. Fisher. Crystallographic phase changes and damage thresholds of CsPbI 3 microwire waveguides through continuous wave photoablation. Materials Advances 2020, 1 (2) , 161-166. https://doi.org/10.1039/D0MA00043D
    Load all citations
    Download PDF
    Go to The Journal of Physical Chemistry C
    Get e-Alerts
    Get e-Alerts

    The Journal of Physical Chemistry C

    Cite this: J. Phys. Chem. C 2018, 122, 25, 13407–13415
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.jpcc.7b11168
    Published December 15, 2017
    Copyright © 2017 American Chemical Society
    Request reuse permissions

    Article Views

    4650

    Altmetric

    -

    Citations

    116
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.