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Comparative Study of Water-Based LA133 and CMC/SBR Binders for Sulfur Cathode in Advanced Lithium–Sulfur Batteries

  • Weiwen Wang
    Weiwen Wang
    Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, 220 Handan Road, Shanghai 200433, P. R. China
    More by Weiwen Wang
  • , 
  • Xinyang Yue
    Xinyang Yue
    Department of Materials Science, Fudan University, 220 Handan Road, Shanghai 200433, P. R.China
    More by Xinyang Yue
  • , 
  • Jingke Meng
    Jingke Meng
    Department of Materials Science, Fudan University, 220 Handan Road, Shanghai 200433, P. R.China
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  • , 
  • Xinxin Wang
    Xinxin Wang
    Department of Materials Science, Fudan University, 220 Handan Road, Shanghai 200433, P. R.China
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  • , 
  • Yongning Zhou
    Yongning Zhou
    Department of Materials Science, Fudan University, 220 Handan Road, Shanghai 200433, P. R.China
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    Orcidhttp://orcid.org/0000-0002-9791-3468
  • , 
  • Qinchao Wang*
    Qinchao Wang
    Department of Materials Science, Fudan University, 220 Handan Road, Shanghai 200433, P. R.China
    *E-mail: [email protected] (Q.W.).
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  • , and 
  • Zhengwen Fu*
    Zhengwen Fu
    Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, 220 Handan Road, Shanghai 200433, P. R. China
    *E-mail: [email protected] (Z.F.).
    More by Zhengwen Fu
    Orcidhttp://orcid.org/0000-0002-4649-0194
Cite this: J. Phys. Chem. C 2019, 123, 1, 250–257
Publication Date (Web):December 18, 2018
https://doi.org/10.1021/acs.jpcc.8b10736
Copyright © 2018 American Chemical Society
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    Abstract

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    Two most widely used commercial water-based binders, polyacrylic latex (LA133) and sodium carboxymethyl cellulose/styrene butadiene rubber (CMC/SBR), are utilized for constructing sulfur cathodes to investigate their influence on the electrochemical properties of lithium–sulfur batteries. Compared with the CMC/SBR binder, the LA133 binder is found to possess not only higher charge densities (−49.6 versus −38.9 mV) but also better chain flexibility, which promises the homogeneous dispersion of the sulfur–carbon composite cathode materials and ensures an effective conducting framework, resulting in the high utilization of active sulfur. The electrode performance of the batteries further demonstrates that the LA133 cathode with higher dispersion degree delivers lower internal resistance, faster Li-ion diffusion rate, more efficient conversion of sulfur redox, higher reversible capacity (1176.2 versus 867.3 mAh g–1), and better rate capability and electrode stability.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.jpcc.8b10736.

    • Details of the fitted EIS data, the calculated Li-ion diffusion coefficients, and optical images of the sulfur cathodes (PDF)

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