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Probing the Defect-Induced Magnetocaloric Effect on Ferrite/Graphene Functional Nanocomposites and their Magnetic Hyperthermia

  • T. Prabhakaran*
    T. Prabhakaran
    Advanced Ceramics and Nanotechnology Laboratory, Department of Materials Engineering, Faculty of Engineering, University of Concepcion, Concepcion 4070409, Chile
    Materials and Low-temperature Laboratory, Institute of Physics “Gleb Wataghin”, Universidade Estadual de Campinas (UNICAMP), Campinas 13083-859, São Paulo, Brazil
    *E-mail: [email protected] (T.P.).
  • R. Udayabhaskar
    R. Udayabhaskar
    Instituto de Investigaciónes Científicas y Tecnológicas (IDICTEC), Universidad de Atacama, Copayapu 485, Copiapó 1531772, Chile
  • R. V. Mangalaraja*
    R. V. Mangalaraja
    Advanced Ceramics and Nanotechnology Laboratory, Department of Materials Engineering, Faculty of Engineering, University of Concepcion, Concepcion 4070409, Chile
    Technological Development Unit (UDT), University of Concepcion, Coronel Industrial Park, Coronel 4191996, Chile
    *E-mail: [email protected]. Phone: +56-41-2207389. Fax: +56-41-2203391 (R.V.M.).
  • Saeed Farhang Sahlevani
    Saeed Farhang Sahlevani
    Advanced Ceramics and Nanotechnology Laboratory, Department of Materials Engineering, Faculty of Engineering, University of Concepcion, Concepcion 4070409, Chile
  • Rafael M. Freire
    Rafael M. Freire
    Department of Physics, University of Santiago and CEDENNA, Santiago 7190006, Chile
  • Juliano C. Denardin
    Juliano C. Denardin
    Department of Physics, University of Santiago and CEDENNA, Santiago 7190006, Chile
  • F. Béron
    F. Béron
    Materials and Low-temperature Laboratory, Institute of Physics “Gleb Wataghin”, Universidade Estadual de Campinas (UNICAMP), Campinas 13083-859, São Paulo, Brazil
    More by F. Béron
  • Kokkarachedu Varaprasad
    Kokkarachedu Varaprasad
    Centro de Investigaciónde Polímeros Avanzados (CIPA), Avenida Collao 1202, Edificio de Laboratorio CIPA, Concepción 00043, Chile
  • Miguel Angel Gracia-Pinilla
    Miguel Angel Gracia-Pinilla
    Facultad de Ciencias Físico-Matemáticas, Universidad Autónoma de Nuevo León, Av. Universidad, Cd. Universitaria, San Nicolás de los Garza 66420, Nuevo León, Mexico
    Centro de Investigación en Innovación y Desarrollo en Ingeniería y Tecnología, PIIT, Universidad Autónoma de Nuevo León, Apodaca, Nuevo León, 66600, Mexico
  • Marcus Vinicius-Araújo
    Marcus Vinicius-Araújo
    Instituto de Física, Universidade Federal de Goiás, Goiânia 74690-900, Goiás, Brazil
  • , and 
  • Andris F. Bakuzis
    Andris F. Bakuzis
    Instituto de Física, Universidade Federal de Goiás, Goiânia 74690-900, Goiás, Brazil
Cite this: J. Phys. Chem. C 2019, 123, 42, 25844–25855
Publication Date (Web):October 1, 2019
https://doi.org/10.1021/acs.jpcc.9b07076
Copyright © 2019 American Chemical Society

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    Abstract

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    Recently, the development of an alternative magnetic refrigerant for the conventional fossil fuels attracts the researchers. We discussed the structural defect-induced magnetocaloric effect (MCE) in Ni0.3Zn0.7Fe2O4/graphene (NZF/G) nanocomposites for the first time. Single-phase spinel ferrite nanocomposites with an average size of 7–11.4 nm were achieved by using the microwave-assisted coprecipitation method. The effect of graphene loading on the structural and magnetism of NZF/G nanocomposites was elaborated. Raman analysis proved that the interface interaction between NZF and graphene yielded different densities of structural defects. In view of magnetism, superparamagnetic NZF nanoparticles showed a magnetic entropy change (−ΔSMmax) of −0.678 J·kg–1 K–1 at 135 K, whereas the NZF/G nanocomposites exhibited superior −ΔSMmax at cryogenic temperatures and the defect-induced MCE change was indeed similar to the ID/IG intensity ratio. The nanocomposites exhibited different magnetic orderings between 5 and 295 K, and it was varying for ID/IG, 1.83 > 1.68 > 1.57 as antiferromagnetic (AFM) > AFM/ferrimagnetic (FiM) > FiM, respectively. Till now, NZF/G nanocomposites showed an inverse MCE of 4.378 J·kg–1 K–1 at 35 K and a refrigerant capacity of 88 J·kg–1 for 40 kOe, which was greater than the ferrites reported so far. Finally, MCE and magnetic hyperthermia were correlated at ambient conditions. These results pave the way for ferrite/graphene nanocomposites for cooling applications.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.jpcc.9b07076.

    • Particle size distribution of ferrites and ferrite/graphene nanocomposites; IR absorption wavenumber and vibrational bands assignment; deconvoluted Lorentzian fitting of Raman spectra; magnetic entropy change under low applied field (200–4000 Oe); Arrot’s plots to show the magnetic transition; relative cooling power versus field trend; comparison of present results with earlier reports on MCE; and particle size effect on magnetization, MCE, and heating rate (magnetic hyperthermia) behavior (PDF)

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    Cited By

    This article is cited by 7 publications.

    1. Prabhakaran Thandapani, Radhamanohar Aepuru, Fanny Béron, Mangalaraja Ramalinga Viswanathan, Kokkarachedu Varaprasad, Fabio Luis Zabotto, José A. Jiménez, Juliano C. Denardin. Multiferroic Electroactive Polymer Blend/Ferrite Nanocomposite Flexible Films for Cooling Devices. ACS Applied Polymer Materials 2023, 5 (8) , 5926-5936. https://doi.org/10.1021/acsapm.3c00589
    2. Necda ÇAM, Ümit AKINCI. Magnetic materials as an environmentally friendly cooling and heating systems: Tuning magnetocaloric properties in the magnetic nanotubes. International Journal of Energy Studies 2023, 8 (4) , 601-618. https://doi.org/10.58559/ijes.1353919
    3. V. V. Korolev, A. G. Ramazanova, K. V. Efimova, S. S. Guseinov. Effect of Graphene Flakes on the Physical and Chemical Properties of Magnetite Magnetic Fluids. Russian Journal of Physical Chemistry A 2022, 96 (4) , 756-758. https://doi.org/10.1134/S0036024422040161
    4. Ashreen Norman, Emmellie Laura Albert, Che Azurahanim Che Abdullah. Graphene oxide and carbon dots: Facile green route synthesis, characterization, and their potential biomedical applications. 2022, 523-549. https://doi.org/10.1016/B978-0-12-823296-5.00019-8
    5. Yuanyuan lian, Lin Wang, Junyang Cao, Tingting Liu, Zhenju Xu, Bowen Yang, Tianqiao Huang, Xiaodan Jiang, Nannan Wu. Recent advances on the magnetic nanoparticle–based nanocomposites for magnetic induction hyperthermia of tumor: a short review. Advanced Composites and Hybrid Materials 2021, 4 (4) , 925-937. https://doi.org/10.1007/s42114-021-00373-3
    6. Raghvendra Singh Yadav, Ivo Kuřitka, Jarmila Vilčáková. Spinel ferrite nanocomposites formation and characterization. 2021, 21-42. https://doi.org/10.1016/B978-0-12-821290-5.00003-4
    7. Mario S. Reis, Ning Ma. Caloric effects of quantum materials: An outlook. Physics Open 2020, 4 , 100028. https://doi.org/10.1016/j.physo.2020.100028

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