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Universal Gas-Uptake Behavior of a Zeolitic Imidazolate Framework ZIF-8 at High Pressure

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    Universal Gas-Uptake Behavior of a Zeolitic Imidazolate Framework ZIF-8 at High Pressure
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    • Jinhyuk Choi
      Jinhyuk Choi
      Department of Earth System Sciences, Yonsei University, Seoul 03722, Republic of Korea
      More by Jinhyuk Choi
    • Junhyuck Im
      Junhyuck Im
      Department of Earth System Sciences, Yonsei University, Seoul 03722, Republic of Korea
      More by Junhyuck Im
    • Kyungkyou Noh
      Kyungkyou Noh
      Department of ICMC Convergence Technology, Soongsil University, Seoul 06978, Republic of Korea
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    • Jaheon Kim
      Jaheon Kim
      Department of Chemistry  and  Department of ICMC Convergence Technology, Soongsil University, Seoul 06978, Republic of Korea
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      Orcidhttp://orcid.org/0000-0001-6430-8790
    • Thomas Vogt
      Thomas Vogt
      NanoCenter and Department of Chemistry & Biochemistry, University of South Carolina, Columbia, South Carolina 29208, United States
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    • Yongjae Lee*
      Yongjae Lee
      Department of Earth System Sciences, Yonsei University, Seoul 03722, Republic of Korea
      Center for High Pressure Science & Technology Advanced Research (HPSTAR), Shanghai 201203, China
      *E-mail: [email protected]
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      Orcidhttp://orcid.org/0000-0002-2043-0804
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    The Journal of Physical Chemistry C

    Cite this: J. Phys. Chem. C 2019, 123, 42, 25769–25774
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.jpcc.9b08539
    Published September 23, 2019
    Copyright © 2019 American Chemical Society
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    Abstract

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    We report the pressure-induced insertion (PII) of gases in a zeolitic imidazolate framework (ZIF) at high pressure. ZIF-8 crystals were compressed in the presence of nonpolar CO2 and SF6 as well as polar CHClF2 (aka R22) up to 4.07, 0.81, and 2.06 GPa, respectively, in a diamond anvil cell, and their X-ray powder diffraction data were analyzed by Rietveld methods. ZIF-8 showed pressure-induced amorphization in SF6 but maintained its crystallinity in the presence of other gases. In general, the unit cell volume of ZIF-8 expanded via PII of CO2 or R22 up to ca. 0.5 GPa and contracted linearly after completion of the PII processes. The total volumes of the inserted guest molecules, which were estimated from the residual electron densities, indicated that the inserted guest molecules fully occupy the pores of ZIF-8. The relationship between the total occupied volumes by guests and applied pressures was best represented with an asymptotic logarithmic curve regardless of the type of molecules. These results reveal the universal gas-uptake behavior of ZIF-8 at high pressure, which requires only the penetration of molecules into the pores of the framework of ZIF-8.

    Copyright © 2019 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.jpcc.9b08539.

    • X-ray powder diffraction patterns in different pressure-transmitting media under varying pressures, refined structural models of ZIF-8 under high pressure with their Rietveld fits, quantitative X-ray fluorescence result, calculated electron density maps, change of the volumes of the unit cell and void of ZIF-8 as a function of pressure, and gas adsorption isotherms of ZIF-8 under subatmospheric pressure (PDF)

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    Cited By

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    This article is cited by 13 publications.

    1. Joshua Edzards, Holger-Dietrich Saßnick, Ana Guilherme Buzanich, Ana M. Valencia, Franziska Emmerling, Sebastian Beyer, Caterina Cocchi. Effects of Ligand Substituents on the Character of Zn-Coordination in Zeolitic Imidazolate Frameworks. The Journal of Physical Chemistry C 2023, 127 (43) , 21456-21464. https://doi.org/10.1021/acs.jpcc.3c06054
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    10. Shan Jiang, Jingyan Liu, Jiwen Guan, Xin Du, Shoushun Chen, Yang Song, Yining Huang. Enhancing CO2 adsorption capacity of ZIF-8 by synergetic effect of high pressure and temperature. Scientific Reports 2023, 13 (1) https://doi.org/10.1038/s41598-023-44960-4
    11. Fuping Zeng, Kexin Zhu, Dazhi Su, Xiaoxuan Feng, Xinnuo Guo, Qiang Yao, Ju Tang. Trapping and Adsorption Characteristics of ZIF-8 on SF and Its Decomposition Products . IEEE Transactions on Dielectrics and Electrical Insulation 2023, 30 (6) , 2650-2656. https://doi.org/10.1109/TDEI.2023.3280889
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    The Journal of Physical Chemistry C

    Cite this: J. Phys. Chem. C 2019, 123, 42, 25769–25774
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.jpcc.9b08539
    Published September 23, 2019
    Copyright © 2019 American Chemical Society
    Request reuse permissions

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