ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Figure 1Loading Img
RETURN TO ISSUEPREVPhysical Insights in...Physical Insights into Light Interacting with MatterNEXT

Tuning Electrogenerated Chemiluminescence Intensity Enhancement Using Hexagonal Lattice Arrays of Gold Nanodisks

  • Thomas S. Heiderscheit
    Thomas S. Heiderscheit
    Department of Chemistry, Rice University, 6100 Main Street, Houston, Texas 77005, United States
  • Shunpei Oikawa
    Shunpei Oikawa
    Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo, Hokkaido 060-0810, Japan
  • Stephen Sanders
    Stephen Sanders
    Department of Physics and Astronomy, University of New Mexico, Albuquerque, New Mexico 87106, United States
  • Hiro Minamimoto
    Hiro Minamimoto
    Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo, Hokkaido 060-0810, Japan
  • Emily K. Searles
    Emily K. Searles
    Department of Chemistry, Rice University, 6100 Main Street, Houston, Texas 77005, United States
  • Christy F. Landes*
    Christy F. Landes
    Department of Chemistry, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    Department of Electrical and Computer Engineering, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    Department of Chemical and Biomolecular Engineering, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    *Email: cflandes@rice
  • Kei Murakoshi*
    Kei Murakoshi
    Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo, Hokkaido 060-0810, Japan
    *Email: [email protected]
  • Alejandro Manjavacas*
    Alejandro Manjavacas
    Department of Physics and Astronomy, University of New Mexico, Albuquerque, New Mexico 87106, United States
    Instituto de Óptica (IO−CSIC), Consejo Superior de Investigaciones Científicas, 28006 Madrid, Spain
    *Email: [email protected]
  • , and 
  • Stephan Link*
    Stephan Link
    Department of Chemistry, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    Department of Electrical and Computer Engineering, Rice University, 6100 Main Street, Houston, Texas 77005, United States
    *Email: [email protected]
    More by Stephan Link
Cite this: J. Phys. Chem. Lett. 2021, 12, 10, 2516–2522
Publication Date (Web):March 5, 2021
https://doi.org/10.1021/acs.jpclett.0c03564
Copyright © 2021 American Chemical Society

    Article Views

    1278

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options
    Supporting Info (1)»

    Abstract

    Abstract Image

    Electrogenerated chemiluminescence (ECL) microscopy shows promise as a technique for mapping chemical reactions on single nanoparticles. The technique’s spatial resolution is limited by the quantum yield of the emission and the diffusive nature of the ECL process. To improve signal intensity, ECL dyes have been coupled with plasmonic nanoparticles, which act as nanoantennas. Here, we characterize the optical properties of hexagonal arrays of gold nanodisks and how they impact the enhancement of ECL from the coreaction of tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate and tripropylamine. We find that varying the lattice spacing results in a 23-fold enhancement of ECL intensity because of increased dye-array near-field coupling as modeled using finite element method simulations.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Supporting Information

    ARTICLE SECTIONS
    Jump To

    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.jpclett.0c03564.

    • Experimental and numerical methods, calculation of the average TIRDFS and HADFS spectra, TIRDFS spectra in air and polymer medium, FEM extinction spectra, analysis method for determining the long wavelength cutoff for constructive interference, ECL intensity enhancement calculation, lattice/ITO surface available surface area calculation, and the method for obtaining ECL spectra (PDF)

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 10 publications.

    1. Nobuaki Oyamada, Hiro Minamimoto, Tomohiro Fukushima, Ruifeng Zhou, Kei Murakoshi. Beyond single-molecule chemistry for electrified interfaces using molecule polaritons. Bulletin of the Chemical Society of Japan 2024, 97 (2) https://doi.org/10.1093/bulcsj/uoae007
    2. Qihui Ye, Chen Wang, Jiaojiao Chen, Shuai Guo, Gang Song. Circular Dichroism Enhancement Induced by Strong Coupling and Weak Coupling in Metal Disk-Chiral TDBCs-Metal Disk Structure. Plasmonics 2023, 18 (3) , 871-876. https://doi.org/10.1007/s11468-023-01811-2
    3. Baodong Gai, Jingwei Guo, Yuqi Jin. Lattice relaxation effects on the collective resonance spectra of a finite dipole array. Physical Chemistry Chemical Physics 2023, 25 (14) , 10054-10062. https://doi.org/10.1039/D3CP00195D
    4. Cheng Ma, Zhichen Zhang, Tingting Tan, Jun-Jie Zhu. Recent Progress in Plasmonic based Electrochemiluminescence Biosensors: A Review. Biosensors 2023, 13 (2) , 200. https://doi.org/10.3390/bios13020200
    5. Terefe Tafese Bezuneh, Tadesse Haile Fereja, Shimeles Addisu Kitte, Haijuan Li, Yongdong Jin. Gold nanoparticle-based signal amplified electrochemiluminescence for biosensing applications. Talanta 2022, 248 , 123611. https://doi.org/10.1016/j.talanta.2022.123611
    6. Gail A. Vinnacombe‐Willson, Ylli Conti, Steven J. Jonas, Paul S. Weiss, Agustín Mihi, Leonardo Scarabelli. Surface Lattice Plasmon Resonances by Direct In Situ Substrate Growth of Gold Nanoparticles in Ordered Arrays. Advanced Materials 2022, 34 (37) https://doi.org/10.1002/adma.202205330
    7. Hiro MINAMIMOTO, Kei MURAKOSHI. Highly Localized Photoelectrochemical Reactions at Nanostructured Interfaces. Denki Kagaku 2022, 90 (2) , 122-128. https://doi.org/10.5796/denkikagaku.22-FE0016
    8. Hiro MINAMIMOTO, Kei MURAKOSHI. Precise Control of Nanoscale Interface for Efficient Electrochemical Reactions. Electrochemistry 2021, 89 (6) , 525-535. https://doi.org/10.5796/electrochemistry.21-00080
    9. Hemen Gogoi, Bala Gopal Maddala, Fariyad Ali, Anindya Datta. Role of Solvent in Electron‐Phonon Relaxation Dynamics in Core‐Shell Au−SiO 2 Nanoparticles. ChemPhysChem 2021, 22 (21) , 2201-2206. https://doi.org/10.1002/cphc.202100592
    10. Shanlin Pan, Xiao Li, Jeetika Yadav. Single-nanoparticle spectroelectrochemistry studies enabled by localized surface plasmon resonance. Physical Chemistry Chemical Physics 2021, 23 (35) , 19120-19129. https://doi.org/10.1039/D1CP02801D

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect