Switching Photon Upconversion by Using Photofluorochromic Annihilator with Low-Lying TripletClick to copy article linkArticle link copied!
- Jianlei HanJianlei HanCAS Center for Excellence in Nanoscience, CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology (NCNST), ZhongGuanCun BeiYiTiao, Beijing 100190, P. R. ChinaMore by Jianlei Han
- Jian Zhang*Jian Zhang*Email: [email protected]College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Institute of Molecular and Nano Science, Shandong Normal University, Jinan 250014, P. R. ChinaMore by Jian Zhang
- Yonghong ShiYonghong ShiCAS Center for Excellence in Nanoscience, CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology (NCNST), ZhongGuanCun BeiYiTiao, Beijing 100190, P. R. ChinaMore by Yonghong Shi
- Pengfei Duan*Pengfei Duan*Email: [email protected]College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Institute of Molecular and Nano Science, Shandong Normal University, Jinan 250014, P. R. ChinaUniversity of Chinese Academy of Sciences, No. 19(A) Yuquan Road, Shijingshan District, Beijing 100049, P. R. ChinaMore by Pengfei Duan
Abstract
Photon upconversion based on triplet–triplet annihilation (TTA-UC) has attracted great attention due to its remarkable features including the high upconversion quantum yield, low threshold, and flexible combination of sensitizer and annihilator. Endowing TTA-UC with responsiveness will offer additional application dimensions; however, it is a challenge to develop annihilators with responsive features in the excited triplet state. Here we demonstrate the synthesis and photophysical behaviors of photofluorochromic annihilators derived from fluorescent diarylethenes. A series of turn-on mode fluorescent diarylethenes based on 1,2-bis(2-ethyl-1-benzothiophen-1,1-dioxide-3-yl)perfuorocyclopentene were synthesized, and their photochromism and photofluorochromism behaviors were thoroughly investigated. When sensitized by near-infrared ruthenium phthalocyanine, TTA-UC could be observed under excitation of 730 nm, accompanied by upconverted emission ranging from 500 to 700 nm. Because of the photoresponsive properties of the annihilators, TTA-UC can be switched between “on” and “off” by alternating irradiation of ultraviolet and visible light.
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