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Slow Passivation and Inverted Hysteresis for Hybrid Tin Perovskite Solar Cells Attaining 13.5% via Sequential Deposition

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    Physical Insights into Energy Science

    Slow Passivation and Inverted Hysteresis for Hybrid Tin Perovskite Solar Cells Attaining 13.5% via Sequential Deposition
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    • Efat Jokar
      Efat Jokar
      Department of Applied Chemistry and Institute of Molecular Science, National Chiao Tung University, 1001 Ta-Hsueh Road, Hsinchu 30010, Taiwan
      Center for Emergent Functional Matter Science, National Chiao Tung University, 1001 Ta-Hsueh Road, Hsinchu 30010, Taiwan
      More by Efat Jokar
    • He-Shiang Chuang
      He-Shiang Chuang
      Department of Applied Chemistry and Institute of Molecular Science, National Chiao Tung University, 1001 Ta-Hsueh Road, Hsinchu 30010, Taiwan
      More by He-Shiang Chuang
    • Chun-Hsiao Kuan
      Chun-Hsiao Kuan
      Department of Applied Chemistry and Institute of Molecular Science, National Chiao Tung University, 1001 Ta-Hsueh Road, Hsinchu 30010, Taiwan
      More by Chun-Hsiao Kuan
    • Hui-Ping Wu
      Hui-Ping Wu
      Department of Applied Chemistry and Institute of Molecular Science, National Chiao Tung University, 1001 Ta-Hsueh Road, Hsinchu 30010, Taiwan
      More by Hui-Ping Wu
    • Cheng-Hung Hou
      Cheng-Hung Hou
      Research Center for Applied Sciences, Academia Sinica, Taipei 11529, Taiwan
      More by Cheng-Hung Hou
      Orcidhttps://orcid.org/0000-0002-5150-7106
    • Jing-Jong Shyue
      Jing-Jong Shyue
      Research Center for Applied Sciences, Academia Sinica, Taipei 11529, Taiwan
      Department of Materials Science and Engineering, National Taiwan University, Taipei 10617, Taiwan
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      Orcidhttps://orcid.org/0000-0002-8508-659X
    • Eric Wei-Guang Diau*
      Eric Wei-Guang Diau
      Department of Applied Chemistry and Institute of Molecular Science, National Chiao Tung University, 1001 Ta-Hsueh Road, Hsinchu 30010, Taiwan
      Center for Emergent Functional Matter Science, National Chiao Tung University, 1001 Ta-Hsueh Road, Hsinchu 30010, Taiwan
      *E-mail: [email protected]
      More by Eric Wei-Guang Diau
      Orcidhttps://orcid.org/0000-0001-6113-5679
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    The Journal of Physical Chemistry Letters

    Cite this: J. Phys. Chem. Lett. 2021, 12, 41, 10106–10111
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    https://doi.org/10.1021/acs.jpclett.1c03107
    Published October 11, 2021
    Copyright © 2021 American Chemical Society
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    Abstract

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    Herein, we report a sequential deposition procedure to passivate the surface of a hybrid mixed cationic tin perovskite (E1G20) with phenylhydrazinium thiocyanate (PHSCN) dissolved in trifluoroethanol solvent. The photoluminescence lifetime of the PHSCN film was enhanced by a factor of 6, while the charge-extraction rate from perovskite to C60 layer was enhanced by a factor of 2.5, in comparison to those of the E1G20 film. A slow surface passivation was observed; the performance of the PHSCN device improved upon increasing the storage period to attain an efficiency of 13.5% for a current–voltage scan in the forward bias direction. An inverted effect of hysteresis was observed in that the efficiency of the forward scan was greater than that of the reverse scan. An ion-migration model as a result of the effect of the phenylhydrazinium surface passivation is proposed to account for the observed phenomena. The device was stable upon shelf storage in a glovebox for 3000 h.

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    • Experimental methods, supplementary figures and tables for SEM, GIWAX, XPS, UPS, ultraviolet–visible (UV–vis)/PL, AFM, c-AFM, performance statistics, J–V curves, incident photon-to-current efficiency (IPCE), and summary of reported device performance (PDF)

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    Cite this: J. Phys. Chem. Lett. 2021, 12, 41, 10106–10111
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    https://doi.org/10.1021/acs.jpclett.1c03107
    Published October 11, 2021
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