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    Structure-Dependent Dissociation of Water on Cobalt Oxide
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    • Matthias Schwarz
      Matthias Schwarz
      Lehrstuhl für Physikalische Chemie II, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058 Erlangen, Germany
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      Orcidhttp://orcid.org/0000-0002-7308-3172
    • Firas Faisal
      Firas Faisal
      Lehrstuhl für Physikalische Chemie II, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058 Erlangen, Germany
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    • Susanne Mohr
      Susanne Mohr
      Lehrstuhl für Physikalische Chemie II, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058 Erlangen, Germany
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      Orcidhttp://orcid.org/0000-0001-6735-4477
    • Chantal Hohner
      Chantal Hohner
      Lehrstuhl für Physikalische Chemie II, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058 Erlangen, Germany
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    • Kristin Werner
      Kristin Werner
      Lehrstuhl für Physikalische Chemie II, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058 Erlangen, Germany
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      Orcidhttp://orcid.org/0000-0001-9540-6692
    • Tao Xu
      Tao Xu
      Lehrstuhl für Physikalische Chemie II, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058 Erlangen, Germany
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    • Tomáš Skála
      Tomáš Skála
      Department of Surface and Plasma Science, Faculty of Mathematics and Physics, Charles University, V Holešovičkách 2, 18000 Prague, Czech Republic
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      Orcidhttp://orcid.org/0000-0003-2909-9422
    • Nataliya Tsud
      Nataliya Tsud
      Department of Surface and Plasma Science, Faculty of Mathematics and Physics, Charles University, V Holešovičkách 2, 18000 Prague, Czech Republic
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      Orcidhttp://orcid.org/0000-0001-7439-7731
    • Kevin C. Prince
      Kevin C. Prince
      Elettra-Sincrotrone Trieste SCpA, Strada Statale 14, km 163.5, 34149 Basovizza-Trieste, Italy
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      Orcidhttp://orcid.org/0000-0002-5416-7354
    • Vladimír Matolín
      Vladimír Matolín
      Department of Surface and Plasma Science, Faculty of Mathematics and Physics, Charles University, V Holešovičkách 2, 18000 Prague, Czech Republic
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    • Yaroslava Lykhach*
      Yaroslava Lykhach
      Lehrstuhl für Physikalische Chemie II, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058 Erlangen, Germany
      *E-mail: [email protected] (Y.L.).
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      Orcidhttp://orcid.org/0000-0003-3989-0365
    • Jörg Libuda*
      Jörg Libuda
      Lehrstuhl für Physikalische Chemie II, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058 Erlangen, Germany
      Erlangen Catalysis Resource Center and Interdisciplinary Center Interface Controlled Processes, Friedrich-Alexander-Universität Erlangen-Nürnberg, 91058 Erlangen, Germany
      *E-mail: [email protected] (J.L.).
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      Orcidhttp://orcid.org/0000-0003-4713-5941
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    The Journal of Physical Chemistry Letters

    Cite this: J. Phys. Chem. Lett. 2018, 9, 11, 2763–2769
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    https://doi.org/10.1021/acs.jpclett.8b01033
    Published May 9, 2018
    Copyright © 2018 American Chemical Society
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    Abstract

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    Understanding the correlation between structure and reactivity of oxide surfaces is vital for the rational design of catalytic materials. In this work, we demonstrate the exceptional degree of structure sensitivity of the water dissociation reaction for one of the most important materials in catalysis and electrocatalysis. We studied H2O on two atomically defined cobalt oxide surfaces, CoO(100) and Co3O4(111). Both surfaces are terminated by O2– and Co2+ in different coordination. By infrared reflection absorption spectroscopy and synchrotron radiation photoelectron spectroscopy we show that H2O adsorbs molecularly on CoO(100), while it dissociates and forms very strongly bound OH and partially dissociated (H2O)n(OH)m clusters on Co3O4(111). We rationalize this structure dependence by the coordination number of surface Co2+. Our results show that specific well-ordered cobalt oxide surfaces interact very strongly with H2O whereas others do not. We propose that this structure dependence plays a key role in catalysis with cobalt oxide nanomaterials.

    Copyright © 2018 American Chemical Society

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.jpclett.8b01033.

    • Experimental details and synchrotron radiation photoelectron spectroscopy data for water adsorption at 200 K (PDF)

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    The Journal of Physical Chemistry Letters

    Cite this: J. Phys. Chem. Lett. 2018, 9, 11, 2763–2769
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.jpclett.8b01033
    Published May 9, 2018
    Copyright © 2018 American Chemical Society
    Request reuse permissions

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