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Photo- and Thermoresponsive Liquid Marbles Based on Fatty Acid as Phase Change Material Coated by Polypyrrole: From Design to Applications

  • Yusuke Tsumura
    Yusuke Tsumura
    Division of Applied Chemistry, Environmental and Biomedical Engineering, Graduate School of Engineering, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan
  • Anne-Laure Fameau
    Anne-Laure Fameau
    Université Lille, CNRS, INRAE, Centrale Lille, UMR 8207 - UMET - Unité Matériaux et Transformations, F-59000 Lille, France
  • Kanade Matsui
    Kanade Matsui
    Division of Applied Chemistry, Environmental and Biomedical Engineering, Graduate School of Engineering, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan
  • Tomoyasu Hirai
    Tomoyasu Hirai
    Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan
    Nanomaterials Microdevices Research Center, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan
  • Yoshinobu Nakamura
    Yoshinobu Nakamura
    Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan
    Nanomaterials Microdevices Research Center, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan
  • , and 
  • Syuji Fujii*
    Syuji Fujii
    Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan
    Nanomaterials Microdevices Research Center, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan
    *Email: [email protected]
    More by Syuji Fujii
Cite this: Langmuir 2023, 39, 2, 878–889
Publication Date (Web):January 5, 2023
https://doi.org/10.1021/acs.langmuir.2c03086
Copyright © 2023 American Chemical Society

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    Abstract

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    Responsive liquid marbles (LMs), which can change their shape, stability, and motion by the application of stimuli, attract a growing interest due to their wide range of applications. Our approach to design photo- and thermoresponsive LMs is based on the use of micrometer-sized fatty acid (FA) particles as phase change material covered with polypyrrole (PPy) overlayers with photothermal property. The core–shell particles were synthesized by aqueous chemical oxidative seeded dispersion polymerization. First, we investigated the effect of the alkyl chain length of FA on the resulting FA/PPy core–shell particles by characterizing their size and its distribution, shape, morphology, chemical composition, and photothermal behavior. Then LMs were fabricated by rolling water droplets on the dried FA/PPy particle powder bed and their light and temperature dual stimuli-responsive nature was studied as a function of the FA alkyl chain length. For all FAs studied, LMs disrupted in a domino manner by light irradiation as the first trigger: the temperature of the FA/PPy particles on the LM surface increased by light irradiation, followed by phase change of FA core of the particles from solid to liquid, resulting in disruption of the LM and release of the encapsulated water. The disruption time was closely correlated to the melting point of FA linked to the alkyl chain length and light irradiation power, and it could be controlled and tuned easily between quasi instantaneous and approximately 10 s. Finally, we showed potential applications of the LMs as a carrier for controlled delivery and release of substances and a sensor.

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.langmuir.2c03086.

    • Characterization methods for FA seed particles and FA/PPy particles; characteristics of FA seed particles and FA/PPy particles (PDF)

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    Cited By

    This article is cited by 4 publications.

    1. Apirak Kunanopparatn, Masaki Hayashi, Yuya Atsuta, Yamato Iwata, Kenshin Yamamoto, Kanade Matsui, Tomoyasu Hirai, Yoshinobu Nakamura, Fuangfa Unob, Apichat Imyim, Syuji Fujii. pH-Responsive Liquid Marbles Stabilized with Chitosan-Stearic Acid-Conjugated Particles. ACS Sustainable Chemistry & Engineering 2024, 12 (10) , 4175-4185. https://doi.org/10.1021/acssuschemeng.3c07724
    2. Abhishek Kaushal, Shraga Shoval, Bernard P. Binks, Edward Bormashenko. Universality of Scaling Laws Governing Contact and Spreading Time Spans of Bouncing Liquid Marbles and its Physical Origin. Langmuir 2023, 39 (35) , 12488-12496. https://doi.org/10.1021/acs.langmuir.3c01710
    3. Dev Patel, Wanying Wei, Harmann Singh, Kai Xu, Christopher Beck, Michael Wildy, John Schossig, Xiao Hu, Dong Choon Hyun, Wenshuai Chen, Ping Lu. Efficient and Secure Encapsulation of a Natural Phase Change Material in Nanofibers Using Coaxial Electrospinning for Sustainable Thermal Energy Storage. ACS Sustainable Chemistry & Engineering 2023, 11 (31) , 11570-11579. https://doi.org/10.1021/acssuschemeng.3c02094
    4. Shoichiro Aoki, Tatsuro Yoshida, Hung K. Nguyen, Ken Nakajima, Tomoyasu Hirai, Yoshinobu Nakamura, Syuji Fujii. Nonspherical Epoxy Resin Polymer Particles Synthesized via Solvent-Free Polyaddition Reactions. Langmuir 2023, 39 (16) , 5872-5879. https://doi.org/10.1021/acs.langmuir.3c00311