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Nonspherical Epoxy Resin Polymer Particles Synthesized via Solvent-Free Polyaddition Reactions

  • Shoichiro Aoki
    Shoichiro Aoki
    Division of Applied Chemistry, Environmental and Biomedical Engineering, Graduate School of Engineering, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan
  • Tatsuro Yoshida
    Tatsuro Yoshida
    Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan
  • Hung K. Nguyen
    Hung K. Nguyen
    Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro, Tokyo 152-8552, Japan
  • Ken Nakajima
    Ken Nakajima
    Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro, Tokyo 152-8552, Japan
    More by Ken Nakajima
  • Tomoyasu Hirai
    Tomoyasu Hirai
    Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan
    Nanomaterials Microdevices Research Center, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan
  • Yoshinobu Nakamura
    Yoshinobu Nakamura
    Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan
    Nanomaterials Microdevices Research Center, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan
  • , and 
  • Syuji Fujii*
    Syuji Fujii
    Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan
    Nanomaterials Microdevices Research Center, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan
    *Email: [email protected]
    More by Syuji Fujii
Cite this: Langmuir 2023, 39, 16, 5872–5879
Publication Date (Web):April 11, 2023
https://doi.org/10.1021/acs.langmuir.3c00311
Copyright © 2023 American Chemical Society

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    Abstract

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    Cubic liquid marbles (LMs) were fabricated by using various epoxy monomers as internal liquids and millimeter-sized polymer plates as stabilizers. Successively, cubic polymer particles were synthesized via solvent-free polyaddition reactions by exposing the cubic LMs to NH3 vapor used as a curing agent. The effect of the solubility parameters (SPs) for the epoxy monomers on the formation of the cubic polymer particles was investigated. As a result, we succeeded in fabricating cubic polymer particles reflecting the shapes of the original LMs by using epoxy monomers with SP values of 23.70–21.66 (MPa)1/2. Furthermore, the shapes of the LMs could be controlled on demand (e.g., pentahedral and rectangular) by control of the number of polymer plates per LM and/or coalescence of the LMs, resulting in fabrication of polymer particles with shapes reflecting those of the LMs.

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.langmuir.3c00311.

    • Characteristics of PET plates (morphology and surface chemistry), epoxy monomers (surface tension, density, and contact angle), and epoxy resin particles (morphology); and details on the process used to obtain shape-designable LMs (PDF)

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