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Controlled Synthesis of Polyaniline-Based Nanomaterials with Self-Assembly and Interface Manipulation

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Download Hi-Res ImageDownload to MS-PowerPointCite This:Langmuir 2024, 40, 4, 2183-2190
    Article

    Controlled Synthesis of Polyaniline-Based Nanomaterials with Self-Assembly and Interface Manipulation
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    • Dana Kanzhigitova
      Dana Kanzhigitova
      Department of Chemical and Materials Engineering, School of Engineering and Digital Science, Nazarbayev University, Astana 010000, Kazakhstan
      Department of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, Almaty 050040, Kazakhstan
      More by Dana Kanzhigitova
    • Munziya Abutalip
      Munziya Abutalip
      Lab of Renewable Energy, National Laboratory Astana, Nazarbayev University, Astana 010000, Kazakhstan
      More by Munziya Abutalip
    • Faisal Nazir
      Faisal Nazir
      Department of Chemical and Materials Engineering, School of Engineering and Digital Science, Nazarbayev University, Astana 010000, Kazakhstan
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    • Magzhan Amze
      Magzhan Amze
      Department of Chemical and Materials Engineering, School of Engineering and Digital Science, Nazarbayev University, Astana 010000, Kazakhstan
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    • Perizat Askar
      Perizat Askar
      Department of Chemical and Materials Engineering, School of Engineering and Digital Science, Nazarbayev University, Astana 010000, Kazakhstan
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    • Yelriza Yeszhan
      Yelriza Yeszhan
      Department of Chemical and Materials Engineering, School of Engineering and Digital Science, Nazarbayev University, Astana 010000, Kazakhstan
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    • Tri Thanh Pham
      Tri Thanh Pham
      Department of Biology, School of Sciences and Humanities, Nazarbayev University, Astana 010000, Kazakhstan
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      Orcidhttps://orcid.org/0000-0003-1026-2146
    • Raikhan Rakhmetullayeva
      Raikhan Rakhmetullayeva
      Department of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, Almaty 050040, Kazakhstan
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    • Salimgerey Adilov*
      Salimgerey Adilov
      Department of Chemistry, School of Sciences and Humanities, Nazarbayev University, Astana 010000, Kazakhstan
      *Email: [email protected]
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    • Nurxat Nuraje*
      Nurxat Nuraje
      Department of Chemical and Materials Engineering, School of Engineering and Digital Science, Nazarbayev University, Astana 010000, Kazakhstan
      Lab of Renewable Energy, National Laboratory Astana, Nazarbayev University, Astana 010000, Kazakhstan
      *Email: [email protected]
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      Orcidhttps://orcid.org/0000-0002-4335-8905
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    Langmuir

    Cite this: Langmuir 2024, 40, 4, 2183–2190
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.langmuir.3c03167
    Published January 18, 2024
    Copyright © 2024 American Chemical Society
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    Abstract

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    Versatile nanostructures of conducting polymers are highly relevant based on unique properties, including electrical, optical, and thermal, with changes in morphology. This contribution reports a facile and reproducible synthesis approach for the design of conducting polymer nanostructures from zero- to three-dimensional composites. Two polymerization steps, namely, self-assembly-directed and interface thin layer-templated polymerizations in this synthesis, were kinetically controlled to fabricate such nanostructures directly. The uniquely designed bicontinuous nanoreactor offers an easy synthesis technique for fabricating 3D multifunctional conducting polymer composites. Self-assembly-directed polymerization could be controlled to form nanorods and further directed to form nanobowl/hollow spherical structures. The interface thin layer template process was tuned to produce hollow spherical and 2D film nanostructures. Kinetic control of polymerization was able to provide access to unprecedented nanostructures of the conducting polymers ranging from DNA origami to gecko-inspired nanostructures, with potential applications in drug delivery, energy storage, and adhesive materials. For example, this is the first conducting polymer material that can demonstrate similar adhesiveness (around 8 N/cm2) to gecko finger hairs.

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.langmuir.3c03167.

    • Synthesis procedure; 1H and 13C NMR spectra; schematic illustration for the bicontinuous microemulsion reactor and photos of three bicontinous reaction solutions; FTIR spectra; SEM images; monomer structure, schematic illustration for ladder formation, polymer chain packing to form nanorods, and TEM image of nanorod lattice fringe; DSC curves and Raman spectra; KPFM data; 2D film formation of polyaniline derivatives; schematic design for adhesion measurement using AFM and representative curves for films without and with p-TS; images of the film with fewer nanobowls displaying less adhesiveness and the film with dense-packed nanobowls/hollow spheres showing strong adhesiveness (PDF)

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    Cited By

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    This article is cited by 2 publications.

    1. Mobina Moradi, Milad Rezaei, Pirooz Marashi, William Mark Rainforth. Smart Doped Polyaniline Coating for Wireless Anodic Protection of AISI 304 Stainless Steel in a Corrosive Medium Containing Sulfate and Chloride Ions: Electrochemical and DFT Evaluations. Langmuir 2024, 40 (25) , 13303-13318. https://doi.org/10.1021/acs.langmuir.4c01718
    2. Jiaqi Xu, Yuchen Wang, Mengxuan Zhu, Rui Wang, Heng Jiang, Dechen Bo, Changzi Jin, Xin Liu. Construction of Functional Phenolic Resin and Carbon Hollow Spheres by Manipulating Structural Inhomogeneity. Langmuir 2024, 40 (17) , 9039-9048. https://doi.org/10.1021/acs.langmuir.4c00355
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    Langmuir

    Cite this: Langmuir 2024, 40, 4, 2183–2190
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.langmuir.3c03167
    Published January 18, 2024
    Copyright © 2024 American Chemical Society
    Request reuse permissions

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