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How Slippery are SLIPS? Measuring Effective Slip on Lubricated Surfaces with Colloidal Probe Atmoc Force Microscopy

Cite this: Langmuir 2019, 35, 8, 2976–2982
Publication Date (Web):February 5, 2019
https://doi.org/10.1021/acs.langmuir.8b03767
Copyright © 2019 American Chemical Society
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    Abstract

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    Lubricant-infused surfaces have attracted great attention recently and are described as slippery liquid-infused porous surfaces (SLIPS). Here, we measured the hydrodynamic drainage forces on SLIPS by colloid probe atomic force microscopy (AFM) and quantified the effective slip length over a nanothin silicone oil layer on hydrophobized [octadecyltrichlorosilane (OTS)-coated] silicon wafers. The thickness of a stable silicone oil film on OTS–Si under sucrose solution was determined to be 1.8 ± 1.3 nm and was found to induce an average effective slip length of 29 ± 3 nm, very close to that of an uninfused OTS substrate. These relatively low values of effective slip are confirmed by the relatively large macroscopic roll-off angle values of water droplets on the same substrates. Both nano- and macroscale results reflect the immobilized nature of a silicone oil layer of thickness around 2 nm within an underlying monolayer. These results have important implications in the design of drag-reducing coatings using lubricant infusion.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.langmuir.8b03767.

    • Additional statistical details regarding hydrodynamic force experiments, tapping mode atomic force micrographs of clean and OTS-coated silicon wafers, optical micrographs of OTS-coated silicon wafers infused with different thicknesses of silicon oil submerged in water, Hamaker constants and spreading parameters for a silicone oil layer on different substrates in air, water, and sucrose solution, advancing and receding CAs for values presented in Table 1, pointed tip AFM approach and withdraw force curves on OTS silicon wafers in air and water with different silicone oil layer thicknesses, and linearized hydrodynamic approach force curve using colloid probe AFM in sucrose solution compared to standard data representation at separation distance <300 nm (PDF)

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    16. Christopher Vega-Sánchez, Sam Peppou-Chapman, Liwen Zhu, Chiara Neto. Nanobubbles explain the large slip observed on lubricant-infused surfaces. Nature Communications 2022, 13 (1) https://doi.org/10.1038/s41467-022-28016-1
    17. Huilong Yan, Wenyao Zhang, Yonghe Cui, Fang Qian, Dongmin Wei, Panpan Guo, Kai Jiao, Jin Huang, Qiuwang Wang, Cunlu Zhao. Durable drag reduction and anti-corrosion for liquid flows inside lubricant-infused aluminum/copper capillaries. Chemical Engineering Science 2022, 79 , 118275. https://doi.org/10.1016/j.ces.2022.118275
    18. Huilong Yan, Fang Qian, Kai Jiao, Wenyao Zhang, Zhoutuo Tan, Lingru Zhao, Qiuwang Wang, Cunlu Zhao. Copper capillaries with lubricant-infused walls: fabrication and drag reduction performance. Microfluidics and Nanofluidics 2022, 26 (10) https://doi.org/10.1007/s10404-022-02581-9
    19. A. A. Ganne. On the Issue of the Stability of Water-Repellent Infusion Liquids on Hydrophilic and Hydrophobic Silica Substrates. Colloid Journal 2022, 84 (4) , 411-415. https://doi.org/10.1134/S1061933X22040068
    20. Kirill A. Emelyanenko, Alexandre M. Emelyanenko, Ludmila B. Boinovich. Disjoining pressure analysis of the lubricant nanofilm stability of liquid-infused surface upon lubricant depletion. Journal of Colloid and Interface Science 2022, 618 , 121-128. https://doi.org/10.1016/j.jcis.2022.03.047
    21. Christopher Vega‐Sánchez, Chiara Neto. Pressure Drop Measurements in Microfluidic Devices: A Review on the Accurate Quantification of Interfacial Slip. Advanced Materials Interfaces 2022, 9 (5) https://doi.org/10.1002/admi.202101641
    22. Nithi Atthi, Mantana Suwan, Nuchjarin Sangwong, Pattaraluck Pattamang, Witsaroot Sripumkhai, Rattanawan Meananeatra, Pawasuth Saengdee, Oraphan Thongsook, Norabadee Ranron, Krynnaras Pankong, Warinrampai Uahchinkul, Wutthinan Jeamsaksiri, Sitthisuntorn Supothina. Fabrication of slippery liquid-infused porous surfaces for anti-fouling applications. Japanese Journal of Applied Physics 2021, 60 (SC) , SCCJ04. https://doi.org/10.35848/1347-4065/abf514
    23. Philipp Baumli, Maria D'Acunzi, Katharina I. Hegner, Abhinav Naga, William S.Y. Wong, Hans-Jürgen Butt, Doris Vollmer. The challenge of lubricant-replenishment on lubricant-impregnated surfaces. Advances in Colloid and Interface Science 2021, 287 , 102329. https://doi.org/10.1016/j.cis.2020.102329
    24. Alex Vena, Stefan Kolle, Shane Stafslien, Joanna Aizenberg, Philseok Kim. Self‐Stratifying Porous Silicones with Enhanced Liquid Infusion and Protective Skin Layer for Biofouling Prevention. Advanced Materials Interfaces 2021, 8 (2) https://doi.org/10.1002/admi.202000359
    25. Chenghong Wang, Zhiguang Guo. A comparison between superhydrophobic surfaces (SHS) and slippery liquid-infused porous surfaces (SLIPS) in application. Nanoscale 2020, 12 (44) , 22398-22424. https://doi.org/10.1039/D0NR06009G
    26. Xiangsheng Chen, Gang Wen, Zhiguang Guo. What are the design principles, from the choice of lubricants and structures to the preparation method, for a stable slippery lubricant-infused porous surface?. Materials Horizons 2020, 7 (7) , 1697-1726. https://doi.org/10.1039/D0MH00088D
    27. Sam Peppou-Chapman, Jun Ki Hong, Anna Waterhouse, Chiara Neto. Life and death of liquid-infused surfaces: a review on the choice, analysis and fate of the infused liquid layer. Chemical Society Reviews 2020, 49 (11) , 3688-3715. https://doi.org/10.1039/D0CS00036A
    28. Sam Peppou-Chapman, Chiara Neto. Mapping Depletion of Lubricant Films on Antibiofouling Wrinkled Slippery Surfaces. ACS Applied Materials & Interfaces 2018, 10 (39) , 33669-33677. https://doi.org/10.1021/acsami.8b11768
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