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Figure-Eight-Shaped and Cage-Shaped Cyclic Polystyrenes
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    Figure-Eight-Shaped and Cage-Shaped Cyclic Polystyrenes
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    Department of Polymer Science and Engineering, Pusan National University, Busan, 46241, Korea
    Department of Chemical and Biological Engineering, Korea University, Seoul, 02841, Korea
    § Department of Chemistry and Division of Advanced Materials Science, Pohang University of Science and Technology (POSTECH), Pohang, 37673, Korea
    *(H.P.) Telephone: +82-51-510-2402. E-mail: [email protected]
    *(T.C.) Telephone: +82-54-279-2109. E-mail: [email protected]
    *(J.H.) Telephone: +82-2-3290-5977. E-mail: [email protected]
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    Macromolecules

    Cite this: Macromolecules 2016, 49, 10, 3672–3680
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    https://doi.org/10.1021/acs.macromol.6b00093
    Published May 3, 2016
    Copyright © 2016 American Chemical Society

    Abstract

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    Nonlinear polystyrenes (PS) with similar molecular weights but with different molecular structures having star-, figure-8-, and cage-shaped architectures were synthesized by combining atom transfer radical polymerization (ATRP) and click chemistry. Figure-8- and cage-shaped PS were fractionated by using a gradient normal phase liquid chromatography as confirmed by SEC-LS, MALDI–TOF MS, 1H NMR, and FT-IR spectrometry. Their purities were estimated by using a two-dimensional liquid chromatography (2D-LC). The glass transition temperatures of these topologically different polymers were in the order of cage-, figure-8-, and star-shaped polymers possibly due to the multiple links that constrain the overall molecular diffusivity in the case of multicyclic polymers (figure-8, and cage). Monte Carlo simulation on the glass transition behavior of model system also agreed well with the experimental results.

    Copyright © 2016 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.macromol.6b00093.

    • 1H NMR spectra of initiator (1), coupling agents (4, 7), star polymers (2, 3) and FT-IR spectra of star polymers (2, 3) and coupling agents (4, 7) (PDF)

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    Macromolecules

    Cite this: Macromolecules 2016, 49, 10, 3672–3680
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.macromol.6b00093
    Published May 3, 2016
    Copyright © 2016 American Chemical Society

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