ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Figure 1Loading Img

Control over Molecular Architectures of Carbohydrate-Based Block Copolymers for Stretchable Electrical Memory Devices

  • Chih-Chien Hung
    Chih-Chien Hung
    Institute of Polymer Science and Engineering, National Taiwan University, Taipei 10617, Taiwan
  • Saki Nakahira
    Saki Nakahira
    Faculty of Engineering and Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo 060-8628, Japan
  • Yu-Cheng Chiu
    Yu-Cheng Chiu
    Department of Chemical Engineering, National Taiwan University of Science and Technology, Taipei 10607, Taiwan
  • Takuya Isono
    Takuya Isono
    Faculty of Engineering and Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo 060-8628, Japan
    More by Takuya Isono
  • Hung-Chin Wu
    Hung-Chin Wu
    Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan
    More by Hung-Chin Wu
  • Kodai Watanabe
    Kodai Watanabe
    Faculty of Engineering and Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo 060-8628, Japan
  • Yun-Chi Chiang
    Yun-Chi Chiang
    Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan
  • Shoichi Takashima
    Shoichi Takashima
    Faculty of Engineering and Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo 060-8628, Japan
  • Redouane Borsali
    Redouane Borsali
    CERMAV-CNRS, BP 53, Cedex 9 38041 Grenoble, France
  • Shih-Huang Tung*
    Shih-Huang Tung
    Institute of Polymer Science and Engineering  and  Advanced Research Center for Green Materials Science and Technology, National Taiwan University, Taipei 10617, Taiwan
    *E-mail [email protected] (W.-C.C.).
  • Toshifumi Satoh*
    Toshifumi Satoh
    Faculty of Engineering and Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo 060-8628, Japan
    *E-mail [email protected] (T.S.).
  • , and 
  • Wen-Chang Chen*
    Wen-Chang Chen
    Institute of Polymer Science and Engineering,  Department of Chemical Engineering  and  Advanced Research Center for Green Materials Science and Technology, National Taiwan University, Taipei 10617, Taiwan
    *E-mail [email protected] (S.-H.T.).
Cite this: Macromolecules 2018, 51, 13, 4966–4975
Publication Date (Web):June 19, 2018
https://doi.org/10.1021/acs.macromol.8b00874
Copyright © 2018 American Chemical Society

    Article Views

    1750

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options
    Supporting Info (1)»

    Abstract

    Abstract Image

    We synthesized a series of new intrinsically stretchable block copolymers (BCPs) in linear AB-type, ABA-type, and star-shaped architectures composed of oligosaccharide (MH) and flexible poly(n-butyl acrylate) (PBA) blocks for the application in field-effect transistor memory. The BCP thin films are used as the charge trapping layers in the memory devices where the BCPs phase separate into ordered MH microdomains in soft PBA matrices. The MH microdomain works as the charge-trapping sites while the soft PBA matrix provides a stretchability. In particular, the BCPs of the ABA-type and star-shaped architectures with the end MH blocks not only show superior memory performances but also form physical networks that impart mechanical resilience to the thin films such that they can endure 100% strain without formation of cracks. The mobilities and the memory windows of the devices are nearly constant even when the charge trapping layers are stretched and released at 50% strain for 1000 cycles. This work highlights the importance of the molecular architectures on the BCPs intended for stretchable electronic materials.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Supporting Information

    ARTICLE SECTIONS
    Jump To

    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.macromol.8b00874.

    • Experimental sections and supplementary tables and figures (PDF)

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 31 publications.

    1. Ke He, Cong Wang, Yongli He, Jiangtao Su, Xiaodong Chen. Artificial Neuron Devices. Chemical Reviews 2023, 123 (23) , 13796-13865. https://doi.org/10.1021/acs.chemrev.3c00527
    2. Chih-Chien Hung, Yan-Cheng Lin, Tsung-Han Chuang, Yun-Chi Chiang, Yu-Cheng Chiu, Muhammad Mumtaz, Redouane Borsali, Wen-Chang Chen. Harnessing of Spatially Confined Perovskite Nanocrystals Using Polysaccharide-based Block Copolymer Systems. ACS Applied Materials & Interfaces 2022, 14 (26) , 30279-30289. https://doi.org/10.1021/acsami.2c09296
    3. Satoshi Katsuhara, Yasuko Takagi, Naoki Sunagawa, Kiyohiko Igarashi, Takuya Yamamoto, Kenji Tajima, Takuya Isono, Toshifumi Satoh. Enhanced Self-Assembly and Mechanical Properties of Cellulose-Based Triblock Copolymers: Comparisons with Amylose-Based Triblock Copolymers. ACS Sustainable Chemistry & Engineering 2021, 9 (29) , 9779-9788. https://doi.org/10.1021/acssuschemeng.1c02180
    4. Yan-Cheng Lin, Chih-Chien Hung, Chun-Kai Chen, Yun-Chi Chiang, Li-Che Hsu, Jian-Sian Li, Chu-Chen Chueh, Tomoya Higashihara, Wen-Chang Chen. Pyrene-Incorporated Side Chain in π-Conjugated Polymers for Non-Volatile Transistor-Type Memory Devices with Improved Stretchability. ACS Applied Polymer Materials 2021, 3 (4) , 2109-2119. https://doi.org/10.1021/acsapm.1c00159
    5. Li-Che Hsu, Saburo Kobayashi, Takuya Isono, Yun-Chi Chiang, Brian J. Ree, Toshifumi Satoh, Wen-Chang Chen. Highly Stretchable Semiconducting Polymers for Field-Effect Transistors through Branched Soft–Hard–Soft Type Triblock Copolymers. Macromolecules 2020, 53 (17) , 7496-7510. https://doi.org/10.1021/acs.macromol.0c00381
    6. Yan-Cheng Lin, Chun-Kai Chen, Yun-Chi Chiang, Chih-Chien Hung, Mao-Chun Fu, Shin Inagaki, Chu-Chen Chueh, Tomoya Higashihara, Wen-Chang Chen. Study on Intrinsic Stretchability of Diketopyrrolopyrrole-Based π-Conjugated Copolymers with Poly(acryl amide) Side Chains for Organic Field-Effect Transistors. ACS Applied Materials & Interfaces 2020, 12 (29) , 33014-33027. https://doi.org/10.1021/acsami.0c07496
    7. Takuya Isono, Saki Nakahira, Hui-Ching Hsieh, Satoshi Katsuhara, Hiroaki Mamiya, Takuya Yamamoto, Wen-Chang Chen, Redouane Borsali, Kenji Tajima, Toshifumi Satoh. Carbohydrates as Hard Segments for Sustainable Elastomers: Carbohydrates Direct the Self-Assembly and Mechanical Properties of Fully Bio-Based Block Copolymers. Macromolecules 2020, 53 (13) , 5408-5417. https://doi.org/10.1021/acs.macromol.0c00611
    8. Shuwen Zhang, Yecheng Wang, Xi Yao, Paul Le Floch, Xuxu Yang, Jia Liu, Zhigang Suo. Stretchable Electrets: Nanoparticle–Elastomer Composites. Nano Letters 2020, 20 (6) , 4580-4587. https://doi.org/10.1021/acs.nanolett.0c01434
    9. Yan-Cheng Lin, Fei-Hao Chen, Yun-Chi Chiang, Chu-Chen Chueh, Wen-Chang Chen. Asymmetric Side-Chain Engineering of Isoindigo-Based Polymers for Improved Stretchability and Applications in Field-Effect Transistors. ACS Applied Materials & Interfaces 2019, 11 (37) , 34158-34170. https://doi.org/10.1021/acsami.9b10943
    10. Ender Ercan, Ping-Chun Tsai, Jung-Yao Chen, Jeun-Yen Lam, Li-Che Hsu, Chu-Chen Chueh, Wen-Chang Chen. Stretchable and Ambient Stable Perovskite/Polymer Luminous Hybrid Nanofibers of Multicolor Fiber Mats and Their White LED Applications. ACS Applied Materials & Interfaces 2019, 11 (26) , 23605-23615. https://doi.org/10.1021/acsami.9b05527
    11. Yuan Zhang, Tianyun Guan, Guang Han, Tianying Guo, Wangqing Zhang. Star Block Copolymer Nanoassemblies: Block Sequence is All-Important. Macromolecules 2019, 52 (2) , 718-728. https://doi.org/10.1021/acs.macromol.8b02427
    12. Jia-Hua Yeh, Suhendro Purbo Prakoso, Leon Lukhas Santoso, Shi-Ju Chen, Bryan Chiang, Ju-Chieh Cheng, Ru-Ning Zhang, Yu-Cheng Chiu. A sustainable biomass-based electret for face mask and non-volatile transistor memory. Organic Electronics 2024, 124 , 106944. https://doi.org/10.1016/j.orgel.2023.106944
    13. Hong-Liang Wang, Yu-Ting Du, Xiao-Juan Zhang, Hai-Xian Ren, Lu Qin, Xiao-Bo Luo, Pei-Yang Gu, Lingyun Xu, Shi-Yuan Zhou. A metastable small organic molecule for secure memory devices. New Journal of Chemistry 2024, 5 https://doi.org/10.1039/D3NJ04177H
    14. Ming Lu, Chenlin Huang, Zhishan Xu, Yue Yuan, Mingcheng Wang, Mingyue Xiao, Liqun Zhang, Pengbo Wan. A Skin‐Bioinspired Urchin‐Like Microstructure‐Contained Photothermal‐Therapy Flexible Electronics for Ultrasensitive Human‐Interactive Sensing. Advanced Functional Materials 2023, 33 (40) https://doi.org/10.1002/adfm.202306591
    15. Polyxeni P. Angelopoulou, Ioannis Moutsios, Gkreti-Maria Manesi, Dimitri A. Ivanov, Georgios Sakellariou, Apostolos Avgeropoulos. Designing high χ copolymer materials for nanotechnology applications: A systematic bulk vs. thin films approach. Progress in Polymer Science 2022, 135 , 101625. https://doi.org/10.1016/j.progpolymsci.2022.101625
    16. Francis Owusu, Frank A. Nüesch, Dorina M. Opris. Stretchable High Response Piezoelectric Elastomers Based on Polable Polynorbornene Fillers in a Polydimethylsiloxane Matrix. Advanced Functional Materials 2022, 32 (41) https://doi.org/10.1002/adfm.202207083
    17. Zhenfeng Guo, Yuvraj Patil, Akira Shinohara, Kazuhiko Nagura, Manabu Yoshida, Takashi Nakanishi. Organic molecular and polymeric electrets toward soft electronics. Molecular Systems Design & Engineering 2022, 7 (6) , 537-552. https://doi.org/10.1039/D1ME00180A
    18. Hong Li, Muhammad Mumtaz, Takuya Isono, Toshifumi Satoh, Wen-Chang Chen, Redouane Borsali. Self-assembly of carbohydrate-based block copolymer systems: glyconanoparticles and highly nanostructured thin films. Polymer Journal 2022, 54 (4) , 455-464. https://doi.org/10.1038/s41428-021-00604-w
    19. Xiao-Hua Hu, Shisheng Xiong. Fabrication of Nanodevices Through Block Copolymer Self-Assembly. Frontiers in Nanotechnology 2022, 4 https://doi.org/10.3389/fnano.2022.762996
    20. Hui Wen Yong, Ashok Kakkar. Nanoengineering Branched Star Polymer‐Based Formulations: Scope, Strategies, and Advances. Macromolecular Bioscience 2021, 21 (8) https://doi.org/10.1002/mabi.202100105
    21. Kai-Ting Huang, Chu-Chen Chueh, Wen-Chang Chen. Recent advance in renewable materials and green processes for optoelectronic applications. Materials Today Sustainability 2021, 11-12 , 100057. https://doi.org/10.1016/j.mtsust.2020.100057
    22. Yu-Che Chen, Yan-Cheng Lin, Hui-Ching Hsieh, Li-Che Hsu, Wei-Chen Yang, Takuya Isono, Toshifumi Satoh, Wen-Chang Chen. Improving the performance of photonic transistor memory devices using conjugated block copolymers as a floating gate. Journal of Materials Chemistry C 2021, 9 (4) , 1259-1268. https://doi.org/10.1039/D0TC05326K
    23. Qiuwei Shi, Jiangxin Wang, Izzat Aziz, Pooi See Lee. Stretchable and Wearable Resistive Switching Random‐Access Memory. Advanced Intelligent Systems 2020, 2 (7) https://doi.org/10.1002/aisy.202000007
    24. Satoshi Katsuhara, Hiroaki Mamiya, Takuya Yamamoto, Kenji Tajima, Takuya Isono, Toshifumi Satoh. Metallopolymer- block -oligosaccharide for sub-10 nm microphase separation. Polymer Chemistry 2020, 11 (17) , 2995-3002. https://doi.org/10.1039/D0PY00271B
    25. Dai-Hua Jiang, Saburo Kobayashi, Chih-Chun Jao, Yoshinobu Mato, Takuya Isono, Yu-Han Fang, Chun-Che Lin, Toshifumi Satoh, Shih-Huang Tung, Chi-Ching Kuo. Light Down-Converter Based on Luminescent Nanofibers from the Blending of Conjugated Rod-Coil Block Copolymers and Perovskite through Electrospinning. Polymers 2020, 12 (1) , 84. https://doi.org/10.3390/polym12010084
    26. Jie Hou, Bin Zhang, Dongqi Li, Yubin Fu, Gang Liu, Yu Chen. Enabling superior stretchable resistive switching memory via polymer-functionalized graphene oxide nanosheets. Journal of Materials Chemistry C 2019, 7 (46) , 14664-14671. https://doi.org/10.1039/C9TC05593B
    27. Yun-Chi Chiang, Saburo Kobayashi, Takuya Isono, Chien-Chung Shih, Tomoki Shingu, Chih-Chien Hung, Hui-Ching Hsieh, Shih-Huang Tung, Toshifumi Satoh, Wen-Chang Chen. Effect of a conjugated/elastic block sequence on the morphology and electronic properties of polythiophene based stretchable block copolymers. Polymer Chemistry 2019, 10 (40) , 5452-5464. https://doi.org/10.1039/C9PY01216H
    28. Chen‐Tsyr Lo, Yu Watanabe, Daiki Murakami, Chien‐Chung Shih, Kazuhiro Nakabayashi, Hideharu Mori, Wen‐Chang Chen. Donor–Acceptor Core–Shell Nanoparticles and Their Application in Non‐Volatile Transistor Memory Devices. Macromolecular Rapid Communications 2019, 40 (12) https://doi.org/10.1002/marc.201900115
    29. Takuya Isono, Nao Kawakami, Kodai Watanabe, Kohei Yoshida, Issei Otsuka, Hiroaki Mamiya, Hajime Ito, Takuya Yamamoto, Kenji Tajima, Redouane Borsali, Toshifumi Satoh. Microphase separation of carbohydrate-based star-block copolymers with sub-10 nm periodicity. Polymer Chemistry 2019, 10 (9) , 1119-1129. https://doi.org/10.1039/C8PY01745J
    30. Ze‐Hua Wu, Wen‐Jing Sun, Hu‐Hu Tian, Ze‐Feng Yu, Rui‐Xue Guo, Xiangfeng Shao, Hao‐Li Zhang. 9,10‐Imide‐Pyrene‐Fused Pyrazaacenes (IPPA) as N‐Type Doping Materials for High‐Performance Nonvolatile Organic Field Effect Transistor Memory Devices. Advanced Electronic Materials 2019, 5 (2) https://doi.org/10.1002/aelm.201800598
    31. Li-Che Hsu, Chien-Chung Shih, Hui-Ching Hsieh, Yun-Chi Chiang, Ping-Han Wu, Chu-Chen Chueh, Wen-Chang Chen. Intrinsically stretchable, solution-processable functional poly(siloxane-imide)s for stretchable resistive memory applications. Polymer Chemistry 2018, 9 (41) , 5145-5154. https://doi.org/10.1039/C8PY01283K

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect