ACS Publications. Most Trusted. Most Cited. Most Read
Bicontinuous Network Nanostructure with Tunable Thickness Formed on Asymmetric Triblock Terpolymer Thick Films
My Activity

Figure 1Loading Img
    Article

    Bicontinuous Network Nanostructure with Tunable Thickness Formed on Asymmetric Triblock Terpolymer Thick Films
    Click to copy article linkArticle link copied!

    • Karim Aissou*
      Karim Aissou
      Institut Européen des Membranes, Université de Montpellier—CNRS—ENSCM, 300 Avenue du Professeur Emile Jeanbrau, F-34090 Montpellier, France
      *E-mail: [email protected]
      More by Karim Aissou
    • Muhammad Mumtaz
      Muhammad Mumtaz
      Laboratoire de Chimie des Polymères Organiques, Univ. Bordeaux, CNRS, Bordeaux INP, LCPO, UMR 5629, F-33600 Pessac, France
    • Hana Bouzit
      Hana Bouzit
      Institut Européen des Membranes, Université de Montpellier—CNRS—ENSCM, 300 Avenue du Professeur Emile Jeanbrau, F-34090 Montpellier, France
      More by Hana Bouzit
    • Gilles Pécastaings
      Gilles Pécastaings
      Laboratoire de Chimie des Polymères Organiques, Univ. Bordeaux, CNRS, Bordeaux INP, LCPO, UMR 5629, F-33600 Pessac, France
    • Giuseppe Portale
      Giuseppe Portale
      Macromolecular Chemistry & New Polymeric Materials, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG, The Netherlands
    • Guillaume Fleury
      Guillaume Fleury
      Laboratoire de Chimie des Polymères Organiques, Univ. Bordeaux, CNRS, Bordeaux INP, LCPO, UMR 5629, F-33600 Pessac, France
    • Georges Hadziioannou
      Georges Hadziioannou
      Laboratoire de Chimie des Polymères Organiques, Univ. Bordeaux, CNRS, Bordeaux INP, LCPO, UMR 5629, F-33600 Pessac, France
    Other Access OptionsSupporting Information (1)

    Macromolecules

    Cite this: Macromolecules 2019, 52, 12, 4413–4420
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.macromol.9b00572
    Published June 11, 2019
    Copyright © 2019 American Chemical Society

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    Asymmetric poly(1,1-dimethyl silacyclobutane)-block-polystyrene-block-poly(2-vinyl pyridine) (PDMSB-b-PS-b-P2VP) thick films, consisting of a spongelike substructure topped by a nanostructured dense top layer, were produced by combining a fast self-assembly of the triblock terpolymer chains with nonsolvent-induced phase separation (referred as SNIPS). A controlled evolution of the thickness and morphology of the nanostructured top layer was achieved upon solvent vapor annealing (SVA). For instance, the sub-100 nm thick square array morphology generated by SNIPS is transformed into a 1.5 μm thick core–shell perforated lamellar (PL) structure when exposed to a chloroform (CHCl3) vapor for 3 h. A PL phase having highly ordered continuous P2VP nanochannels can be envisioned as an appealing morphology for membrane applications, since such a network structure formed on asymmetric PDMSB-b-PS-b-P2VP thick films obviates the need for alignment. Monoliths entirely composed of the bicontinuous PL structure were also produced by increasing the duration of the SVA treatment (18 h, CHCl3).

    Copyright © 2019 American Chemical Society

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Supporting Information

    Click to copy section linkSection link copied!

    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.macromol.9b00572.

    • SAXS pattern profiles of the DSV-51k, DSV-43k, blended DSV-51k/DSV-43k samples; SEM images of the same region of a DSV-51k/DSV-43k thick film (t ∼ 19 μm); particle size distribution obtained from DLS measurements for the DSV-51k/DSV-43k solution in DOX/THF; AFM topographic views of a DSV-51k/DSV-43k thick film (t ∼ 19 μm) generated by SNIPS and a one then exposed to a CHCl3 vapor during 30 min; schematic representation of a bicontinuous PL structure with HAuCl4-stained P2VP (yellow)/PS (blue) core–shell perforations; SEM image of a solvent-annealed (0.5 h, CHCl3) DSV-51k/DSV-43k thick film; AFM topographic view and the 2D-FFT with its associated profile corresponding to the PL (001) plane of a solvent-annealed (3 h, CHCl3) DSV-51k/DSV-43k thick film; 2D GISAXS pattern of a solvent-annealed (3 h, CHCl3) DSV-51k/DSV-43k thick film (t ∼ 19 μm) generated by SNIPS–SVA; SEM image of the PL (100) pattern; AFM topographic view and the 2D-FFT with its associated profile corresponding to the PL (101) plane of a solvent-annealed (3 h, CHCl3) DSV-51k/DSV-43k thick film (PDF)

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!
    Citation Statements
    Explore this article's citation statements on scite.ai

    This article is cited by 10 publications.

    1. Hanna Hübner, Bart-Jan Niebuur, Thomas Büttner, Marcus Koch, Bernd Stühn, Tobias Kraus, David Scheschkewitz, Markus Gallei. Self-Assembly of Amphiphilic Carbosilane-Based Block Copolymers in Organic Media and Structure Formation in Colloidal Confinement. Macromolecules 2022, 55 (21) , 9442-9451. https://doi.org/10.1021/acs.macromol.2c01853
    2. Sangho Lee, Ashwanth Subramanian, Nikhil Tiwale, Kim Kisslinger, Muhammad Mumtaz, Ling-Ying Shi, Karim Aissou, Chang-Yong Nam, Caroline A. Ross. Resolving Triblock Terpolymer Morphologies by Vapor-Phase Infiltration. Chemistry of Materials 2020, 32 (12) , 5309-5316. https://doi.org/10.1021/acs.chemmater.0c01647
    3. Karim Aissou, Muhammad Mumtaz, Nils Demazy, Gilles Pécastaings, Guillaume Fleury, Georges Hadziioannou. Periodic Bicontinuous Structures Formed on the Top Surface of Asymmetric Triblock Terpolymer Thick Films. ACS Macro Letters 2019, 8 (8) , 923-930. https://doi.org/10.1021/acsmacrolett.9b00403
    4. Karim Aissou, Maximilien Coronas, Daniel Hermida-Merino, Eduardo Solano, Didier Cot, Stéphanie Roualdes, Denis Bouyer, Damien Quemener, . Nanoporous Double-Gyroid Structure from ABC Triblock Terpolymer Thick Films. International Journal of Polymer Science 2023, 2023 , 1-9. https://doi.org/10.1155/2023/9598572
    5. Karim Aissou, Muhammad Mumtaz, Daniel Hermida‐Merino, Eduardo Solano, Didier Cot, Belkacem Tarek Benkhaled, Damien Quémener, Stéphanie Roualdes, Guillaume Fleury, Georges Hadziioannou. Square arrays of vertically aligned nanoporous cylinders from a linear ABC triblock terpolymer. Journal of Polymer Science 2023, 61 (13) , 1259-1269. https://doi.org/10.1002/pol.20230088
    6. Hana Bouzit, Felix Krusch, Daniel Hermida‐Merino, Eduardo Solano, Didier Cot, Jean Pierre Méricq, Stéphanie Roualdes, Mona Semsarilar, Damien Quémener, Karim Aissou. Double s timuli‐responsive perforated lamellar structure formed by linear ABC triblock terpolymer monoliths. Journal of Polymer Science 2023, 61 (11) , 1005-1014. https://doi.org/10.1002/pol.20220264
    7. Hanna Hübner, Bart‐Jan Niebuur, Oliver Janka, Lea Gemmer, Marcus Koch, Tobias Kraus, Guido Kickelbick, Bernd Stühn, Markus Gallei. Crystalline Carbosilane‐Based Block Copolymers: Synthesis by Anionic Polymerization and Morphology Evaluation in the Bulk State. Macromolecular Chemistry and Physics 2023, 224 (3) https://doi.org/10.1002/macp.202200178
    8. Kyle D. Mehringer, Brad J. Davis, Lisa K. Kemp, Guorong Ma, Samuel B. Hunt, Robson F. Storey, Xiaodan Gu, Travis L. Thornell, Dane N. Wedgeworth, Yoan C. Simon, Sarah E. Morgan. Synthesis and Morphology of High‐Molecular‐Weight Polyisobutylene–Polystyrene Block Copolymers Containing Dynamic Covalent Bonds. Macromolecular Rapid Communications 2022, 43 (24) https://doi.org/10.1002/marc.202200487
    9. Karim Aissou, Hana Bouzit, Felix Krusch, Jean Pierre Méricq, Didier Cot, Nathalie Masquelez, Stéphanie Roualdes, Damien Quémener. Asymmetric Solvent‐Annealed Triblock Terpolymer Thick Films Topped by a Hexagonal Perforated Lamellar Nanostructure. Macromolecular Rapid Communications 2022, 43 (2) https://doi.org/10.1002/marc.202100585
    10. Nils Demazy, Cian Cummins, Karim Aissou, Guillaume Fleury. Non‐Native Block Copolymer Thin Film Nanostructures Derived from Iterative Self‐Assembly Processes. Advanced Materials Interfaces 2020, 7 (5) https://doi.org/10.1002/admi.201901747

    Macromolecules

    Cite this: Macromolecules 2019, 52, 12, 4413–4420
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.macromol.9b00572
    Published June 11, 2019
    Copyright © 2019 American Chemical Society

    Article Views

    1174

    Altmetric

    -

    Citations

    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.