Electrolyte-Phobic Surface for the Next-Generation Nanostructured Battery ElectrodesClick to copy article linkArticle link copied!
- Chenxi QianChenxi QianDepartment of Materials Science and Engineering, Stanford University, Stanford, California 94305, United StatesDepartment of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, CanadaMore by Chenxi Qian
- Jie ZhaoJie ZhaoDepartment of Materials Science and Engineering, Stanford University, Stanford, California 94305, United StatesMore by Jie Zhao
- Yongming Sun*Yongming Sun*Email: [email protected]Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan 430074, ChinaMore by Yongming Sun
- Hye Ryoung LeeHye Ryoung LeeDepartment of Materials Science and Engineering, Stanford University, Stanford, California 94305, United StatesMore by Hye Ryoung Lee
- Langli LuoLangli LuoInstitute of Molecular Plus, Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, Tianjin University, Tianjin 300072, ChinaMore by Langli Luo
- Meysam MakaremiMeysam MakaremiDepartment of Materials Science and Engineering, University of Toronto, 184 College St., Toronto, Ontario M5S 3E4, CanadaMore by Meysam Makaremi
- Sankha MukherjeeSankha MukherjeeDepartment of Materials Science and Engineering, University of Toronto, 184 College St., Toronto, Ontario M5S 3E4, CanadaMore by Sankha Mukherjee
- Jiangyan WangJiangyan WangDepartment of Materials Science and Engineering, Stanford University, Stanford, California 94305, United StatesStanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025, United StatesMore by Jiangyan Wang
- Chenxi ZuChenxi ZuDepartment of Materials Science and Engineering, Stanford University, Stanford, California 94305, United StatesMore by Chenxi Zu
- Meikun XiaMeikun XiaDepartment of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, CanadaMore by Meikun Xia
- Chongmin WangChongmin WangEnvironmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington 99352, United StatesMore by Chongmin Wang
- Chandra Veer Singh*Chandra Veer Singh*Email: [email protected]Department of Materials Science and Engineering, University of Toronto, 184 College St., Toronto, Ontario M5S 3E4, CanadaMore by Chandra Veer Singh
- Yi Cui*Yi Cui*Email: [email protected]Department of Materials Science and Engineering, Stanford University, Stanford, California 94305, United StatesStanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025, United StatesMore by Yi Cui
- Geoffrey A. Ozin*Geoffrey A. Ozin*Email: [email protected]Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, CanadaMore by Geoffrey A. Ozin
Abstract

Nanostructured electrodes are among the most important candidates for high-capacity battery chemistry. However, the high surface area they possess causes serious issues. First, it would decrease the Coulombic efficiencies. Second, they have significant intakes of liquid electrolytes, which reduce the energy density and increase the battery cost. Third, solid-electrolyte interphase growth is accelerated, affecting the cycling stability. Therefore, the interphase chemistry regarding electrolyte contact is crucial, which was rarely studied. Here, we present a completely new strategy of limiting effective surface area by introducing an “electrolyte-phobic surface”. Using this method, the electrolyte intake was limited. The initial Coulombic efficiencies were increased up to ∼88%, compared to ∼60% of the control. The electrolyte-phobic layer of Si particles is also compatible with the binder, stabilizing the electrode for long-term cycling. This study advances the understanding of interphase chemistry, and the introduction of the universal concept of electrolyte-phobicity benefits the next-generation battery designs.
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(29)
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