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Understanding and Controlling Photothermal Responses in MXenes

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Download Hi-Res ImageDownload to MS-PowerPointCite This:Nano Lett. 2023, 23, 7, 2677-2686
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    Understanding and Controlling Photothermal Responses in MXenes
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    • Burak Guzelturk*
      Burak Guzelturk
      X-ray Science Division, Argonne National Laboratory, Lemont, Illinois 60439, United States
      *Email for B.G.: [email protected]
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      Orcidhttps://orcid.org/0000-0003-1977-6485
    • Vladislav Kamysbayev
      Vladislav Kamysbayev
      Department of Chemistry, James Franck Institute, and Pritzker School of Molecular Engineering, University of Chicago, Chicago, Illinois 60637, United States
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    • Di Wang
      Di Wang
      Department of Chemistry, James Franck Institute, and Pritzker School of Molecular Engineering, University of Chicago, Chicago, Illinois 60637, United States
      More by Di Wang
    • Huicheng Hu
      Huicheng Hu
      Department of Chemistry, James Franck Institute, and Pritzker School of Molecular Engineering, University of Chicago, Chicago, Illinois 60637, United States
      More by Huicheng Hu
    • Ruiyu Li
      Ruiyu Li
      Department of Chemistry, James Franck Institute, and Pritzker School of Molecular Engineering, University of Chicago, Chicago, Illinois 60637, United States
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    • Sarah B. King
      Sarah B. King
      Department of Chemistry, James Franck Institute, and Pritzker School of Molecular Engineering, University of Chicago, Chicago, Illinois 60637, United States
      More by Sarah B. King
      Orcidhttps://orcid.org/0000-0003-0274-9894
    • Alexander H. Reid
      Alexander H. Reid
      SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States
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      Orcidhttps://orcid.org/0000-0002-7587-295X
    • Ming-Fu Lin
      Ming-Fu Lin
      SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States
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      Orcidhttps://orcid.org/0000-0001-8086-2484
    • Xijie Wang
      Xijie Wang
      SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States
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    • Donald A. Walko
      Donald A. Walko
      X-ray Science Division, Argonne National Laboratory, Lemont, Illinois 60439, United States
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    • Xiaoyi Zhang
      Xiaoyi Zhang
      X-ray Science Division, Argonne National Laboratory, Lemont, Illinois 60439, United States
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      Orcidhttps://orcid.org/0000-0001-9732-1449
    • Aaron Lindenberg
      Aaron Lindenberg
      Department of Materials Science and Engineering, Stanford University, Stanford, California 94305, United States
      Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, Menlo Park, California 94025, United States
      More by Aaron Lindenberg
      Orcidhttps://orcid.org/0000-0003-3233-7161
    • Dmitri V. Talapin*
      Dmitri V. Talapin
      Department of Chemistry, James Franck Institute, and Pritzker School of Molecular Engineering, University of Chicago, Chicago, Illinois 60637, United States
      Center for Nanoscale Materials, Argonne National Laboratory, Lemont, Illinois 60439, United States
      *Email for D.V.T.:[email protected]
      More by Dmitri V. Talapin
      Orcidhttps://orcid.org/0000-0002-6414-8587
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    Nano Letters

    Cite this: Nano Lett. 2023, 23, 7, 2677–2686
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.nanolett.2c05001
    Published March 14, 2023
    Copyright © 2023 UChicago Argonne, LLC, Operator of Argonne National Laboratory. Published by American Chemical Society
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    Abstract

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    MXenes have the potential for efficient light-to-heat conversion in photothermal applications. To effectively utilize MXenes in such applications, it is important to understand the underlying nonequilibrium processes, including electron–phonon and phonon–phonon couplings. Here, we use transient electron and X-ray diffraction to investigate the heating and cooling of photoexcited MXenes at femtosecond to nanosecond time scales. Our results show extremely strong electron–phonon coupling in Ti3C2-based MXenes, resulting in lattice heating within a few hundred femtoseconds. We also systematically study heat dissipation in MXenes with varying film thicknesses, chemical surface terminations, flake sizes, and annealing conditions. We find that the thermal boundary conductance (TBC) governs the thermal relaxation in films thinner than the optical penetration depth. We achieve a 2-fold enhancement of the TBC, reaching 20 MW m–2 K–1, by controlling the flake size or chemical surface termination, which is promising for engineering heat dissipation in photothermal and thermoelectric applications of the MXenes.

    Copyright © 2023 UChicago Argonne, LLC, Operator of Argonne National Laboratory. Published by American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.nanolett.2c05001.

    • Experimental details for MXene synthesis, sample preparation and characterization, ultrafast electron diffraction, pump–probe X-ray diffraction, and two-temperature model (PDF)

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    Cited By

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    This article is cited by 6 publications.

    1. Yubin Huang, Jean Spiece, Tetiana Parker, Asaph Lee, Yury Gogotsi, Pascal Gehring. Violation of the Wiedemann–Franz Law and Ultralow Thermal Conductivity of Ti3C2Tx MXene. ACS Nano 2024, 18 (47) , 32491-32497. https://doi.org/10.1021/acsnano.4c08189
    2. Sean L. Murray, Sahand Serajian, Syed Ibrahim Gnani Peer Mohamed, Shiseido Robinson, Rajavel Krishnamoorthy, Suprem R. Das, Mona Bavarian, Siamak Nejati, Ufuk Kilic, Mathias Schubert, Mohammad Ghashami. Ultrabroadband Optical Properties of 2D Titanium Carbide MXene. ACS Applied Materials & Interfaces 2024, Article ASAP.
    3. Dujearic-Stephane Kouao, Katarzyna Grochowska, Vitezslav Stranak, Petr Sezemsky, Justyna Gumieniak, Agnieszka Kramek, Jakub Karczewski, Emerson Coy, Jan Hanus, Ondrej Kylian, Mirosław Sawczak, Katarzyna Siuzdak. Laser-Treated MXene as an Electrochemical Agent to Boost Properties of Semitransparent Photoelectrode Based on Titania Nanotubes. ACS Nano 2024, 18 (14) , 10165-10183. https://doi.org/10.1021/acsnano.4c00092
    4. Xing He, Ding-Shyue Yang. Nanoscale Energy Transport Dynamics across Nonbonded Solid–Molecule Interfaces and in Molecular Thin Films. The Journal of Physical Chemistry Letters 2023, 14 (50) , 11457-11464. https://doi.org/10.1021/acs.jpclett.3c02673
    5. Jie Zhao, Qi Zhang, Laizhi Sui, Guangming Niu, Yutong Zhang, Guorong Wu, Shengrui Yu, Kaijun Yuan, Xueming Yang. Evidence of Surface-Mediated Carrier-Phonon Scattering in MXene. ACS Nano 2023, 17 (23) , 23714-23722. https://doi.org/10.1021/acsnano.3c07431
    6. Haoguan Gui, Xiaonan Zhao, Shixiang Zuo, Wenjie Liu, Chunyu Wang, Pei Xu, Yunsheng Ding, Chao Yao. Carbonized Syndiotactic Polystyrene/Carbon Nanotube/MXene Hybrid Aerogels with Egg-Box Structure: A Platform for Electromagnetic Interference Shielding and Solar Thermal Energy Management. ACS Applied Materials & Interfaces 2023, 15 (33) , 39740-39751. https://doi.org/10.1021/acsami.3c08176
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    Nano Letters

    Cite this: Nano Lett. 2023, 23, 7, 2677–2686
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.nanolett.2c05001
    Published March 14, 2023
    Copyright © 2023 UChicago Argonne, LLC, Operator of Argonne National Laboratory. Published by American Chemical Society
    Request reuse permissions

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