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    Ionic Conductivity Enhancement of Polymer Electrolytes with Ceramic Nanowire Fillers
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    † Department of Materials Science and Engineering, Stanford University, Stanford, California 94305, United States
    ‡ Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025, United States
    *E-mail: [email protected]
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    Nano Letters

    Cite this: Nano Lett. 2015, 15, 4, 2740–2745
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    https://doi.org/10.1021/acs.nanolett.5b00600
    Published March 17, 2015
    Copyright © 2015 American Chemical Society
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    Abstract

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    Solid-state electrolytes provide substantial improvements to safety and electrochemical stability in lithium-ion batteries when compared with conventional liquid electrolytes, which makes them a promising alternative technology for next-generation high-energy batteries. Currently, the low mobility of lithium ions in solid electrolytes limits their practical application. The ongoing research over the past few decades on dispersing of ceramic nanoparticles into polymer matrix has been proved effective to enhance ionic conductivity although it is challenging to form the efficiency networks of ionic conduction with nanoparticles. In this work, we first report that ceramic nanowire fillers can facilitate formation of such ionic conduction networks in polymer-based solid electrolyte to enhance its ionic conductivity by three orders of magnitude. Polyacrylonitrile-LiClO4 incorporated with 15 wt % Li0.33La0.557TiO3 nanowire composite electrolyte exhibits an unprecedented ionic conductivity of 2.4 × 10–4 S cm–1 at room temperature, which is attributed to the fast ion transport on the surfaces of ceramic nanowires acting as conductive network in the polymer matrix. In addition, the ceramic-nanowire filled composite polymer electrolyte shows an enlarged electrochemical stability window in comparison to the one without fillers. The discovery in the present work paves the way for the design of solid ion electrolytes with superior performance.

    Copyright © 2015 American Chemical Society

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    Supporting Information

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    Detailed description of the experimental procedures, DTA/TG and XRD characterization of LLTO nanowires, TG curves of solid electrolytes, SEM images of LLTO nanopowder and composite electrolyte filled with LLTO nanoparticles, and supplementary electrochemical data. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cite this: Nano Lett. 2015, 15, 4, 2740–2745
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    https://doi.org/10.1021/acs.nanolett.5b00600
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