ACS Publications. Most Trusted. Most Cited. Most Read
Dimensionality Controlled Octahedral Symmetry-Mismatch and Functionalities in Epitaxial LaCoO3/SrTiO3 Heterostructures

OR SEARCH CITATIONS

My Activity
Publications

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:Nano Lett. 2015, 15, 7, 4677-4684
    Letter

    Dimensionality Controlled Octahedral Symmetry-Mismatch and Functionalities in Epitaxial LaCoO3/SrTiO3 Heterostructures
    Click to copy article linkArticle link copied!

    View Author Information
    † School of Materials, The University of Manchester, Manchester, M13 9PL, United Kingdom
    ‡ ‡Center for Nanophase Materials Sciences and §Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States
    ∥ □ ∥School of Physical Electronics, and □Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, China
    ⊥ Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford University, Menlo Park, California 94025, United States
    ∇ #Chemical Science and Engineering Division and ∇Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, United States
    ○ School of Materials Science and Engineering, University of New South Wales, Sydney, 2052, NSW Australia
    ◆ Laboratoire CRISMAT, CNRS UMR 6508, ENSICAEN, Normandie Université, 6 Bd Maréchal Juin, F-14050 Caen Cedex 4, France
    Department of Physics, Lanzhou City University, Lanzhou 730070, China
    *E-mail: [email protected]
    Other Access OptionsSupporting Information (1)

    Nano Letters

    Cite this: Nano Lett. 2015, 15, 7, 4677–4684
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.nanolett.5b01471
    Published June 23, 2015
    Copyright © 2015 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    Epitaxial strain provides a powerful approach to manipulate physical properties of materials through rigid compression or extension of their chemical bonds via lattice-mismatch. Although symmetry-mismatch can lead to new physics by stabilizing novel interfacial structures, challenges in obtaining atomic-level structural information as well as lack of a suitable approach to separate it from the parasitical lattice-mismatch have limited the development of this field. Here, we present unambiguous experimental evidence that the symmetry-mismatch can be strongly controlled by dimensionality and significantly impact the collective electronic and magnetic functionalities in ultrathin perovskite LaCoO3/SrTiO3 heterojunctions. State-of-art diffraction and microscopy reveal that symmetry breaking dramatically modifies the interfacial structure of CoO6 octahedral building-blocks, resulting in expanded octahedron volume, reduced covalent screening, and stronger electron correlations. Such phenomena fundamentally alter the electronic and magnetic behaviors of LaCoO3 thin-films. We conclude that for epitaxial systems, correlation strength can be tuned by changing orbital hybridization, thus affecting the Coulomb repulsion, U, instead of by changing the band structure as the common paradigm in bulks. These results clarify the origin of magnetic ordering for epitaxial LaCoO3 and provide a route to manipulate electron correlation and magnetic functionality by orbital engineering at oxide heterojunctions.

    Copyright © 2015 American Chemical Society

    Subjects

    what are subjects

    Keywords

    what are keywords

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Supporting Information

    Click to copy section linkSection link copied!

    Additional information regarding experimental/theoretical details as well as structural and property characterizations. The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.nanolett.5b01471.

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!
    Citation Statements
    Explore this article's citation statements on scite.ai
    powered by  Scite

    This article is cited by 81 publications.

    1. Ziang Meng, Yacong Qi, Peixin Qin, Xiaorong Zhou, Xiaoning Wang, Hongyu Chen, Li Liu, Guojian Zhao, Zhiyuan Duan, Jinghua Liu, Qinghua Zhang, Peizhe Tang, Zhiqi Liu. Largely Enhanced Oxygen Evolution Performance in a Ferromagnetic Ruddlesden–Popper Phase Cobaltate. Nano Letters 2025, 25 (12) , 4887-4894. https://doi.org/10.1021/acs.nanolett.5c00061
    2. Shenli Zhang, Giulia Galli. Metallic Interface between Two Insulating Phases of La1–xSrxCoO3−δ. Chemistry of Materials 2024, 36 (4) , 2096-2105. https://doi.org/10.1021/acs.chemmater.3c03231
    3. Mohammad Moein Seyfouri, Dawei Zhang, César Menéndez, Daniel Sando, Qi Zhang, Claudio Cazorla, Jan Seidel, Danyang Wang. Engineering Photoresponse in Epitaxial BiFe0.5Cr0.5O3 Thin Films through Structural Distortion. The Journal of Physical Chemistry C 2022, 126 (33) , 14329-14338. https://doi.org/10.1021/acs.jpcc.2c04297
    4. Sangmoon Yoon, Xiang Gao, Jong Mok Ok, Zhaoliang Liao, Myung-Geun Han, Yimei Zhu, Panchapakesan Ganesh, Matthew F. Chisholm, Woo Seok Choi, Ho Nyung Lee. Strain-Induced Atomic-Scale Building Blocks for Ferromagnetism in Epitaxial LaCoO3. Nano Letters 2021, 21 (9) , 4006-4012. https://doi.org/10.1021/acs.nanolett.1c00756
    5. Binbin Chen, Nicolas Gauquelin, Robert J. Green, Jin Hong Lee, Cinthia Piamonteze, Matjaž Spreitzer, Daen Jannis, Johan Verbeeck, Manuel Bibes, Mark Huijben, Guus Rijnders, Gertjan Koster. Spatially Controlled Octahedral Rotations and Metal–Insulator Transitions in Nickelate Superlattices. Nano Letters 2021, 21 (3) , 1295-1302. https://doi.org/10.1021/acs.nanolett.0c03850
    6. Dong Li, Dan Li, He Zhang, Anqi Yang, Chunjun Liang. High-Performance Photovoltaic Materials Based on the Superlattice Structures of Organic–Inorganic Halide Perovskite and Superhalogen Hybrid Perovskite. The Journal of Physical Chemistry Letters 2020, 11 (13) , 5282-5294. https://doi.org/10.1021/acs.jpclett.0c01161
    7. Bangmin Zhang, Lijun Wu, Wei-Guo Yin, Cheng-Jun Sun, Ping Yang, T. Venkatesan, Jingsheng Chen, Yimei Zhu, and Gan Moog Chow . Interfacial Coupling-Induced Ferromagnetic Insulator Phase in Manganite Film. Nano Letters 2016, 16 (7) , 4174-4180. https://doi.org/10.1021/acs.nanolett.6b01056
    8. Beatriz Rivas-Murias, Irene Lucas, Pilar Jiménez-Cavero, César Magén, Luis Morellón, and Francisco Rivadulla . Independent Control of the Magnetization in Ferromagnetic La2/3Sr1/3MnO3/SrTiO3/LaCoO3 Heterostructures Achieved by Epitaxial Lattice Mismatch. Nano Letters 2016, 16 (3) , 1736-1740. https://doi.org/10.1021/acs.nanolett.5b04657
    9. Jingxuan He, Xiaoqiang Wu, Sean Li, Liang Qiao, Xiaotao Zu. Crystalline Structural Engineering of an Electrical Insulator Into A Highly‐Active Electrocatalyst for Oxygen Evolution. Small 2025, 21 (12) https://doi.org/10.1002/smll.202410595
    10. Jiaqi He, Sang Xiong, Huijian Li. Synergistic lubrication effect of graphene oxide and MoS2 nanoparticles in water-based fluid: Experiment and humid-environmental MD simulation study. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2025, 707 , 135900. https://doi.org/10.1016/j.colsurfa.2024.135900
    11. Xiaoyu Hu, Wen He, Dongbo Wang, Lei Chen, Xiangqian Fan, Duoduo Ling, Yanghao Bi, Wei Wu, Shuai Ren, Ping Rong, Yinze Zhang, Yajie Han, Jinzhong Wang. Recent progress in two-dimensional Bi 2 O 2 Se and its heterostructures. Nanoscale 2025, 17 (2) , 661-686. https://doi.org/10.1039/D4NR03769C
    12. Yan Li, Hua Zhou, Yang Liu, I‐Cheng Tung, Xi Yan, Friederike Wrobel, Huan‐Hua Wang, Ulrich Welp, Hawoong Hong, John W. Freeland, Dillon D. Fong. On the Emergence of Ferromagnetism in LaCoO 3 Ultrathin Films. Advanced Functional Materials 2024, 34 (41) https://doi.org/10.1002/adfm.202406037
    13. Junhua Liu, Liang Si, Qinghua Zhang, Xiao Wang, Jessica Freese, Grant Harris, Mei Wu, Xinxin Zhang, Ting Lin, Ronny Sutarto, Javier Herrero‐Martín, Charles Guillemard, Manuel Valvidares, Lin Li, Xiaofei Gao, Yaoyao Ji, Zhixiong Deng, Yuhao Hong, Long Wei, Yulin Gan, Lingfei Wang, Guanglei Cheng, Peng Gao, Lin Gu, Jiandi Zhang, Zhiwei Hu, Liu Hao Tjeng, Robert J. Green, Kai Chen, Zhaoliang Liao. Realization of Fully High‐Spin State and Strong Ferromagnetism in LaCoO 3 Monolayer. Advanced Functional Materials 2024, 34 (34) https://doi.org/10.1002/adfm.202401859
    14. Yongqiang Wu, Yang Hong, Jingchao Zhang. Mechanical properties of hexagonal and trigonal molybdenum ditelluride by molecular dynamics simulation. Applied Physics A 2024, 130 (8) https://doi.org/10.1007/s00339-024-07739-6
    15. Menglu Li, Sa Zhang, Chenhan Liu, Xiaotao Zu, Liang Qiao, Haiyan Xiao. Supertetragonal BaZrS3: A promising perovskite sulphide with giant ferroelectricity and low band gap. Science China Physics, Mechanics & Astronomy 2024, 67 (8) https://doi.org/10.1007/s11433-024-2394-1
    16. Genhao 根豪 Liang 梁, Hui 慧 Cao 曹, Long 龙 Cheng 成, Junkun 君坤 Zha 查, Mingrui 明睿 Bao 保, Fei 飞 Ye 叶, Hua 华 Zhou 周, Aidi 爱迪 Zhao 赵, Xiaofang 晓芳 Zhai 翟. Simultaneous control of ferromagnetism and ferroelasticity by oxygen octahedral backbone stretching. Chinese Physics B 2024, 33 (9) , 097101. https://doi.org/10.1088/1674-1056/ad553c
    17. Amanda Liu, Xuan Luo. Three component superlattice enhanced stability for photovoltaic applications: a first principles study. Materials Advances 2024, 5 (15) , 6052-6062. https://doi.org/10.1039/D4MA00172A
    18. Shan Feng, Hangbo Qi, Wenguang Hu, Xiaotao Zu, Haiyan Xiao. A theoretical prediction of thermoelectrical properties for novel two-dimensional monolayer ZrSn 2 N 4. Journal of Materials Chemistry A 2024, 12 (22) , 13474-13487. https://doi.org/10.1039/D4TA00532E
    19. Bernat Mundet, Marios Hadjimichael, Jennifer Fowlie, Lukas Korosec, Lucia Varbaro, Claribel Domínguez, Jean-Marc Triscone, Duncan T. L. Alexander. Mapping orthorhombic domains with geometrical phase analysis in rare-earth nickelate heterostructures. APL Materials 2024, 12 (3) https://doi.org/10.1063/5.0180998
    20. Dong Li, Hongguang Wang, Kaifeng Li, Bonan Zhu, Kai Jiang, Dirk Backes, Larissa S. I. Veiga, Jueli Shi, Pinku Roy, Ming Xiao, Aiping Chen, Quanxi Jia, Tien-Lin Lee, Sarnjeet S. Dhesi, David O. Scanlon, Judith L. MacManus-Driscoll, Peter A. van Aken, Kelvin H. L. Zhang, Weiwei Li. Emergent and robust ferromagnetic-insulating state in highly strained ferroelastic LaCoO3 thin films. Nature Communications 2023, 14 (1) https://doi.org/10.1038/s41467-023-39369-6
    21. Ting-Wei Chen, Shiqi Liu, Ying Zhang, Fang Tang, Jing-Shi Ying, Shuang-Shuang Li, Lei Chen, Fu-Sheng Luo, Shu-Juan Zhang, Yong Fang, Shanming Ke, Weiyao Zhao, Ren-Kui Zheng. Magnetotransport, spin reorientation, and anomalous ferrimagnetic-to-antiferromagnetic phase transition in epitaxial Mn2Sb alloy thin films. Acta Materialia 2023, 259 , 119257. https://doi.org/10.1016/j.actamat.2023.119257
    22. T. Joshi, D. P. Belanger, Y. T. Tan, W. Wen, D. Lederman. Geometric influence on the net magnetic moment in LaCoO3 thin films. Journal of Materials Research 2023, 38 (8) , 2274-2286. https://doi.org/10.1557/s43578-023-00957-3
    23. Judith L. MacManus-Driscoll, Rui Wu, Weiwei Li. Interface-related phenomena in epitaxial complex oxide ferroics across different thin film platforms: opportunities and challenges. Materials Horizons 2023, 10 (4) , 1060-1086. https://doi.org/10.1039/D2MH01527G
    24. Jeong Rae Kim, Byungmin Sohn, Hyeong Jun Lee, Sangmin Lee, Eun Kyo Ko, Sungsoo Hahn, Sangjae Lee, Younsik Kim, Donghan Kim, Hong Joon Kim, Youngdo Kim, Jaeseok Son, Charles H. Ahn, Frederick J. Walker, Ara Go, Miyoung Kim, Choong H. Kim, Changyoung Kim, Tae Won Noh. Heteroepitaxial Control of Fermi Liquid, Hund Metal, and Mott Insulator Phases in Single‐Atomic‐Layer Ruthenates. Advanced Materials 2023, 45 , 2208833. https://doi.org/10.1002/adma.202208833
    25. Sheng-Ru Chen, Shan Lin, Hai-Tao Hong, Ting Cui, Qiao Jin, Can Wang, Kui-Juan Jin, Er-Jia Guo, , , , . Strong spin-lattice entanglement in cobaltites. Acta Physica Sinica 2023, 72 (9) , 097502. https://doi.org/10.7498/aps.72.20230206
    26. Xiang Ding, Menglu Li, Pei Chen, Yan Zhao, Mei Zhao, Huaqian Leng, Yong Wang, Sharafat Ali, Fazal Raziq, Xiaoqiang Wu, Haiyan Xiao, Xiaotao Zu, Qingyuan Wang, Ajayan Vinu, Jiabao Yi, Liang Qiao. Bi2O2Se: A rising star for semiconductor devices. Matter 2022, 5 (12) , 4274-4314. https://doi.org/10.1016/j.matt.2022.11.005
    27. Vipul Chaturvedi, Supriya Ghosh, Dominique Gautreau, William M. Postiglione, John E. Dewey, Patrick Quarterman, Purnima P. Balakrishnan, Brian J. Kirby, Hua Zhou, Huikai Cheng, Amanda Huon, Timothy Charlton, Michael R. Fitzsimmons, Caroline Korostynski, Andrew Jacobson, Lucca Figari, Javier Garcia Barriocanal, Turan Birol, K. Andre Mkhoyan, Chris Leighton. Room-temperature valence transition in a strain-tuned perovskite oxide. Nature Communications 2022, 13 (1) https://doi.org/10.1038/s41467-022-35024-8
    28. Shengru Chen, Qinghua Zhang, Xujing Li, Jiali Zhao, Shan Lin, Qiao Jin, Haitao Hong, Amanda Huon, Timothy Charlton, Qian Li, Wensheng Yan, Jiaou Wang, Chen Ge, Can Wang, Baotian Wang, Michael R. Fitzsimmons, Haizhong Guo, Lin Gu, Wen Yin, Kui-juan Jin, Er Jia Guo. Atomically engineered cobaltite layers for robust ferromagnetism. Science Advances 2022, 8 (43) https://doi.org/10.1126/sciadv.abq3981
    29. Yan Hong, Marc-André Rose, Zhaoting Zhang, Ming Li, Lisa Heymann, Suqin He, Felix Gunkel. Modulating Spin Polarization and Spin-Orbit Interaction by Submonolayer Engineering at La Al O 3 / Sr Ti O 3 Interfaces. Physical Review Applied 2022, 18 (3) https://doi.org/10.1103/PhysRevApplied.18.034012
    30. Xu-jing Li, Bao-Tian Wang, Wen Yin. Octahedral rotation induced spin state and metal–insulator transition in LaCoO 3 films. Journal of Magnetism and Magnetic Materials 2022, 555 , 169318. https://doi.org/10.1016/j.jmmm.2022.169318
    31. Xu Niu, Bin-Bin Chen, Ni Zhong, Ping-Hua Xiang, Chun-Gang Duan. Topological Hall effect in SrRuO 3 thin films and heterostructures. Journal of Physics: Condensed Matter 2022, 34 (24) , 244001. https://doi.org/10.1088/1361-648X/ac60d0
    32. Cao Huy Phuong, Vu Van Hung. Study of the thermodynamic properties of SrTiO3 perovskite by the statistical moment method with improved interatomic potential. Materials Today Communications 2022, 31 , 103439. https://doi.org/10.1016/j.mtcomm.2022.103439
    33. Arun Kumar Jaiswal, Di Wang, Vanessa Wollersen, Rudolf Schneider, Matthieu Le Tacon, Dirk Fuchs. Direct Observation of Strong Anomalous Hall Effect and Proximity‐Induced Ferromagnetic State in SrIrO 3. Advanced Materials 2022, 34 (14) https://doi.org/10.1002/adma.202109163
    34. Hao Liu, Jiyu Fan, Jun Zhao, Fengjiao Qian, Yan Zhu, Chunlan Ma, Azizur Rahman, Lei Zhang, Hao Yang. Critical Behavior of the (111)‐Oriented LaCoO 3 /SrTiO 3 Thin Film. physica status solidi (b) 2022, 259 (1) https://doi.org/10.1002/pssb.202100424
    35. Yapeng Zheng, Zhi Fang, Minghui Shang, Qian Sun, Jinju Zheng, Zuobao Yang, Xinmei Hou, Weiyou Yang. Stabilizing orthorhombic CsSnI 3 perovskites with optimized electronic properties by surface ligands with inter-molecular hydrogen bond. Journal of Materials Chemistry A 2021, 9 (43) , 24641-24649. https://doi.org/10.1039/D1TA07207B
    36. Xiang Ding, Baishun Yang, Huaqian Leng, Jae Hyuch Jang, Junrui Zhao, Chao Zhang, Sa Zhang, Guixin Cao, Ji Zhang, Rohan Mishra, Jiabao Yi, Dongchen Qi, Zheng Gai, Xiaotao Zu, Sean Li, Bing Huang, Albina Borisevich, Liang Qiao. Crystal Symmetry Engineering in Epitaxial Perovskite Superlattices. Advanced Functional Materials 2021, 31 (47) https://doi.org/10.1002/adfm.202106466
    37. Ji Zhang, Jack Yang, Grace L. Causer, Junjie Shi, Frank Klose, Jing-Kai Huang, Allen Tseng, Danyang Wang, Xiaotao Zu, Liang Qiao, Anh Pham, Sean Li. Realization of exchange bias control with manipulation of interfacial frustration in magnetic complex oxide heterostructures. Physical Review B 2021, 104 (17) https://doi.org/10.1103/PhysRevB.104.174444
    38. Yannan Zhou, Pengfei Yan, Suoying Zhang, Chao Ma, Tianpei Ge, Xiaoli Zheng, Li Zhang, Jingyun Jiang, Yonglong Shen, Jun Chen, Qun Xu. Conversion of non-van der Waals VO2 solid to 2D ferromagnet by CO2-induced phase engineering. Nano Today 2021, 40 , 101272. https://doi.org/10.1016/j.nantod.2021.101272
    39. Sisi Li, Qinghua Zhang, Shan Lin, Xiahan Sang, Ryan F. Need, Manuel A. Roldan, Wenjun Cui, Zhiyi Hu, Qiao Jin, Shuang Chen, Jiali Zhao, Jia‐Ou Wang, Jiesu Wang, Meng He, Chen Ge, Can Wang, Hui‐Bin Lu, Zhenping Wu, Haizhong Guo, Xin Tong, Tao Zhu, Brian Kirby, Lin Gu, Kui‐juan Jin, Er‐Jia Guo. Strong Ferromagnetism Achieved via Breathing Lattices in Atomically Thin Cobaltites. Advanced Materials 2021, 33 (4) https://doi.org/10.1002/adma.202001324
    40. Wenrui Zhang, Shaobo Cheng, Christopher M. Rouleau, Kyle P. Kelley, Jong Keum, Eli Stavitski, Yimei Zhu, Matthew F. Chisholm, Zheng Gai, Gyula Eres. Unusual electrical conductivity driven by localized stoichiometry modification at vertical epitaxial interfaces. Materials Horizons 2020, 7 (12) , 3217-3225. https://doi.org/10.1039/D0MH01324B
    41. Guowei Zhou, Xiaojiao Wang, Huihui Ji, Jun Zhang, Penghua Kang, Zhiqin Li, Xiaohong Xu. The strain induced magnetic and anisotropic variations of LaCoO3 thin films. Journal of Magnetism and Magnetic Materials 2020, 515 , 167303. https://doi.org/10.1016/j.jmmm.2020.167303
    42. Weiwei Li, Jueli Shi, Kelvin H. L. Zhang, Judith L. MacManus-Driscoll. Defects in complex oxide thin films for electronics and energy applications: challenges and opportunities. Materials Horizons 2020, 7 (11) , 2832-2859. https://doi.org/10.1039/D0MH00899K
    43. Ran Shi, Zhaosheng Zhang, Wei-Hai Fang, Run Long. Charge localization control of electron–hole recombination in multilayer two-dimensional Dion–Jacobson hybrid perovskites. Journal of Materials Chemistry A 2020, 8 (18) , 9168-9176. https://doi.org/10.1039/D0TA01944E
    44. Benjamin Geisler, Rossitza Pentcheva. Competition of defect ordering and site disproportionation in strained LaCoO 3 on SrTiO 3 (001). Physical Review B 2020, 101 (16) https://doi.org/10.1103/PhysRevB.101.165108
    45. Mei Zhao, Jianwei Su, Yang Zhao, Peng Luo, Fakun Wang, Wei Han, Yuan Li, Xiaotao Zu, Liang Qiao, Tianyou Zhai. Sodium‐Mediated Epitaxial Growth of 2D Ultrathin Sb 2 Se 3 Flakes for Broadband Photodetection. Advanced Functional Materials 2020, 30 (13) https://doi.org/10.1002/adfm.201909849
    46. Ning Wang, Menglu Li, Haiyan Xiao, Xiaotao Zu, Liang Qiao. Layered La Cu O Se : A Promising Anisotropic Thermoelectric Material. Physical Review Applied 2020, 13 (2) https://doi.org/10.1103/PhysRevApplied.13.024038
    47. Xiaoqiang Wu, Jingxuan He, Meng Zhang, Zhongran Liu, Sa Zhang, Yang Zhao, Tian Li, Fapei Zhang, Zheng Peng, Ningyan Cheng, Jiaye Zhang, Xiaojian Wen, Yanwu Xie, He Tian, Liang Cao, Lei Bi, Yi Du, Hongliang Zhang, Jun Cheng, Xuguang An, Yimin Lei, Huahai Shen, Jiantuo Gan, Xiaotao Zu, Sean Li, Liang Qiao. Binary Pd/amorphous-SrRuO3 hybrid film for high stability and fast activity recovery ethanol oxidation electrocatalysis. Nano Energy 2020, 67 , 104247. https://doi.org/10.1016/j.nanoen.2019.104247
    48. Xiaoning Wang, Zexin Feng, Peixin Qin, Han Yan, Xiaorong Zhou, Huixin Guo, Zhaoguogang Leng, Weiqi Chen, Qiannan Jia, Zexiang Hu, Haojiang Wu, Xin Zhang, Chengbao Jiang, Zhiqi Liu. Integration of the noncollinear antiferromagnetic metal Mn3Sn onto ferroelectric oxides for electric-field control. Acta Materialia 2019, 181 , 537-543. https://doi.org/10.1016/j.actamat.2019.10.020
    49. Jonathan Hwang, Zhenxing Feng, Nenian Charles, Xiao Renshaw Wang, Dongkyu Lee, Kelsey A. Stoerzinger, Sokseiha Muy, Reshma R. Rao, Dongwook Lee, Ryan Jacobs, Dane Morgan, Yang Shao-Horn. Tuning perovskite oxides by strain: Electronic structure, properties, and functions in (electro)catalysis and ferroelectricity. Materials Today 2019, 31 , 100-118. https://doi.org/10.1016/j.mattod.2019.03.014
    50. Kayahan Saritas, Jaron T. Krogel, Satoshi Okamoto, Ho Nyung Lee, Fernando A. Reboredo. Structural, electronic, and magnetic properties of bulk and epitaxial LaCoO 3 through diffusion Monte Carlo. Physical Review Materials 2019, 3 (12) https://doi.org/10.1103/PhysRevMaterials.3.124414
    51. Saül Vélez, Vitaly N. Golovach, Juan M. Gomez-Perez, Andrey Chuvilin, Cong Tinh Bui, F. Rivadulla, Luis E. Hueso, F. Sebastian Bergeret, Fèlix Casanova. Spin Hall magnetoresistance in a low-dimensional Heisenberg ferromagnet. Physical Review B 2019, 100 (18) https://doi.org/10.1103/PhysRevB.100.180401
    52. Sisi Li, Jiesu Wang, Qinghua Zhang, Manuel A. Roldan, Lin Shan, Qiao Jin, Shuang Chen, Zhenping Wu, Can Wang, Chen Ge, Meng He, Haizhong Guo, Lin Gu, Kui-juan Jin, Er-Jia Guo. Maximization of ferromagnetism in LaCo O 3 films by competing symmetry. Physical Review Materials 2019, 3 (11) https://doi.org/10.1103/PhysRevMaterials.3.114409
    53. Youdi Gu, Yi-Wen Wei, Kun Xu, Hongrui Zhang, Fei Wang, Fan Li, Muhammad Shahrukh Saleem, Cui-Zu Chang, Jirong Sun, Cheng Song, Ji Feng, Xiaoyan Zhong, Wei Liu, Zhidong Zhang, Jing Zhu, Feng Pan. Interfacial oxygen-octahedral-tilting-driven electrically tunable topological Hall effect in ultrathin SrRuO 3 films. Journal of Physics D: Applied Physics 2019, 52 (40) , 404001. https://doi.org/10.1088/1361-6463/ab2fe8
    54. Ru-Pan Wang, Jaap Geessinck, Hebatalla Elnaggar, Yorick A. Birkhölzer, Keisuke Tomiyasu, Jun Okamoto, Boyang Liu, Chao-Hung Du, Di-Jing Huang, Gertjan Koster, Frank M. F. de Groot. Low-energy orbital excitations in strained LaCoO 3 films. Physical Review B 2019, 100 (16) https://doi.org/10.1103/PhysRevB.100.165148
    55. Yongqi Dong, Zhiyuan Ma, Zhenlin Luo, Hua Zhou, Dillon D. Fong, Wenbin Wu, Chen Gao. Interfacial Octahedral Manipulation Imparts Hysteresis‐Free Metal to Insulator Transition in Ultrathin Nickelate Heterostructure. Advanced Materials Interfaces 2019, 6 (17) https://doi.org/10.1002/admi.201900644
    56. Lijing Wei, Changliang Li, Xiaobo Li, Jianxin Guo, Dayong Ge, Li Guan, Baoting Liu. Origin of lowered bandgap in Bi 2 FeCrO 6 with alternate stacking of B -site cations by first-principles investigations. Materials Research Express 2019, 6 (9) , 096112. https://doi.org/10.1088/2053-1591/ab32b9
    57. Binbin Wang, Bryan D. Esser, Nuria Bagués, Jiaqiang Yan, David W. McComb. Nanoscale Quantification of Jahn-Teller Distortion in LaMnO 3. Microscopy and Microanalysis 2019, 25 (S2) , 80-81. https://doi.org/10.1017/S1431927619001132
    58. Axiel Yaël Birenbaum, Valentino R. Cooper, Albina Borisevich. Tracing Oxygen Transport Pathways with In-Situ STEM and Theory. Microscopy and Microanalysis 2019, 25 (S2) , 1428-1429. https://doi.org/10.1017/S1431927619007876
    59. Claudio U. Hail, Ann‐Katrin U. Michel, Dimos Poulikakos, Hadi Eghlidi. Optical Metasurfaces: Evolving from Passive to Adaptive. Advanced Optical Materials 2019, 7 (14) https://doi.org/10.1002/adom.201801786
    60. Qiyuan Feng, Dechao Meng, Haibiao Zhou, Genhao Liang, Zhangzhang Cui, Haoliang Huang, Jianlin Wang, Jinghua Guo, Chao Ma, Xiaofang Zhai, Qingyou Lu, Yalin Lu. Direct imaging revealing halved ferromagnetism in tensile-strained LaCo O 3 thin films. Physical Review Materials 2019, 3 (7) https://doi.org/10.1103/PhysRevMaterials.3.074406
    61. Xue Rui, Robert F. Klie. Atomic-resolution in-situ cooling study of oxygen vacancy ordering in La0.5Sr0.5CoO3−δ thin films. Applied Physics Letters 2019, 114 (23) https://doi.org/10.1063/1.5098886
    62. Yooun Heo, Daisuke Kan, Masato Anada, Yusuke Wakabayashi, Hiroo Tajiri, Yuichi Shimakawa. Correlations between oxygen octahedral distortions and magnetic and transport properties in strained La 0.5 Sr 0.5 Co O 3 thin films. Physical Review B 2019, 99 (17) https://doi.org/10.1103/PhysRevB.99.174420
    63. Chao Ma, Nan Lin, Zuyong Wang, Shiming Zhou, Hongchun Yu, Jiangbo Lu, Hongwen Huang. Origin of spin-state crossover and electronic reconstruction at the surface of a LaCo O 3 nanoparticle. Physical Review B 2019, 99 (11) https://doi.org/10.1103/PhysRevB.99.115401
    64. Taehwan Moon, Hyun Jae Lee, Keum Do Kim, Young Hwan Lee, Seung Dam Hyun, Hyeon Woo Park, Yong Bin Lee, Baek Su Kim, Cheol Seong Hwang. Diode Property and Positive Temperature Coefficient of Resistance of Pt/Al 2 O 3 /Nb:SrTiO 3. Advanced Electronic Materials 2018, 4 (12) https://doi.org/10.1002/aelm.201800388
    65. M. Sukumar, L. John Kennedy, J. Judith Vijaya, B. Al-Najar, M. Bououdina. Co 2+ substituted La 2 CuO 4 /LaCoO 3 perovskite nanocomposites: synthesis, properties and heterogeneous catalytic performance. New Journal of Chemistry 2018, 42 (22) , 18128-18142. https://doi.org/10.1039/C8NJ04133D
    66. Han Hsu, Sheng-Chieh Huang. Simultaneous metal–half-metal and spin transition in SrCoO 3 under compression. Physical Review Materials 2018, 2 (11) https://doi.org/10.1103/PhysRevMaterials.2.111401
    67. S. Thota, K. Roychowdhury, V. Thakare, S. C. Ganguli, Z. H. Chen, E. J. Guo, S. Das. Structural and magnetic properties of La0.7Sr0.3MnO3/LaCoO3 heterostructures. Applied Physics Letters 2018, 113 (12) https://doi.org/10.1063/1.5045359
    68. Bangmin Zhang, Lijun Wu, Jincheng Zheng, Ping Yang, Xiaojiang Yu, Jun Ding, Steve M. Heald, Richard A Rosenberg, Thirumalai Venky Venkatesan, Jingsheng Chen, Cheng-Jun Sun, Yimei Zhu, Gan Moog Chow. Control of magnetic anisotropy by orbital hybridization with charge transfer in (La0.67Sr0.33MnO3)n/(SrTiO3)n superlattice. NPG Asia Materials 2018, 10 (9) , 931-942. https://doi.org/10.1038/s41427-018-0084-8
    69. G. E. Sterbinsky, R. Nanguneri, J. X. Ma, J. Shi, E. Karapetrova, J. C. Woicik, H. Park, J.-W. Kim, P. J. Ryan. Ferromagnetism and Charge Order from a Frozen Electron Configuration in Strained Epitaxial LaCoO 3 . Physical Review Letters 2018, 120 (19) https://doi.org/10.1103/PhysRevLett.120.197201
    70. L. Qiao, S. Zhang, H. Y. Xiao, D. J. Singh, K. H. L. Zhang, Z. J. Liu, X. T. Zu, S. Li. Orbital controlled band gap engineering of tetragonal BiFeO 3 for optoelectronic applications. Journal of Materials Chemistry C 2018, 6 (5) , 1239-1247. https://doi.org/10.1039/C7TC04160H
    71. Han Gyeol Lee, Rokyeon Kim, Jinkwon Kim, Minu Kim, Tae Heon Kim, Shinbuhm Lee, Tae Won Noh. Anisotropic suppression of octahedral breathing distortion with the fully strained BaBiO3/BaCeO3 heterointerface. APL Materials 2018, 6 (1) https://doi.org/10.1063/1.5010825
    72. Seyoung Cook, Tassie K. Andersen, Hawoong Hong, Richard A. Rosenberg, Laurence D. Marks, Dillon D. Fong. Engineering the oxygen coordination in digital superlattices. APL Materials 2017, 5 (12) , 126101. https://doi.org/10.1063/1.5007663
    73. Felip Sandiumenge. Strain landscapes and self-organization of free surfaces in complex oxide epitaxy. Journal of Materials Research 2017, 32 (21) , 3958-3976. https://doi.org/10.1557/jmr.2017.317
    74. Hui Cao, Yang Liu, Genhao Liang, Aidi Zhao, Xiaofang Zhai. Unraveling interfacial strain and interfacial lattice reconstruction mechanism of ultrathin LaMnO3+δ layers in LaMnO3+δ/SrTiO3 superlattices. Journal of Applied Physics 2017, 122 (8) https://doi.org/10.1063/1.4998958
    75. Q. Q. Lan, X. J. Zhang, X. Shen, H. W. Yang, H. R. Zhang, X. X. Guan, W. Wang, Y. Yao, Y. G. Wang, Y. Peng, B. G. Liu, J. R. Sun, R. C. Yu. Tuning the magnetism of epitaxial cobalt oxide thin films by electron beam irradiation. Physical Review Materials 2017, 1 (2) https://doi.org/10.1103/PhysRevMaterials.1.024403
    76. Daichi Oka, Tomoteru Fukumura. Crystal engineering for novel functionalities with oxide thin film epitaxy. CrystEngComm 2017, 19 (16) , 2144-2162. https://doi.org/10.1039/C7CE00322F
    77. Anh Pham, Sean Li. Engineering the strongly correlated properties of bulk Ruddlesden–Popper transition metal oxides via self-doping. Physical Chemistry Chemical Physics 2017, 19 (18) , 11373-11379. https://doi.org/10.1039/C7CP01700F
    78. H. Y. Qi, M. K. Kinyanjui, X. D. Chen, J. Biskupek, D. Geiger, E. Benckiser, H.-U. Habermeier, B. Keimer, U. Kaiser. Control of octahedral rotations via octahedral connectivity in an epitaxially strained [1 u.c.//4 u.c.] LaNiO3/LaGaO3 superlattice. Journal of Materials Science 2016, 51 (17) , 8168-8176. https://doi.org/10.1007/s10853-016-0092-4
    79. J M Vila-Fungueiriño, Cong Tinh Bui, B Rivas-Murias, E Winkler, J Milano, J Santiso, F Rivadulla. Thermodynamic conditions during growth determine the magnetic anisotropy in epitaxial thin-films of La 0.7 Sr 0.3 MnO 3. Journal of Physics D: Applied Physics 2016, 49 (31) , 315001. https://doi.org/10.1088/0022-3727/49/31/315001
    80. Qing-Hua Zhang, Dong-Dong Xiao, Lin Gu. Aberration-corrected scanning transmission electron microscopy for complex transition metal oxides. Chinese Physics B 2016, 25 (6) , 066803. https://doi.org/10.1088/1674-1056/25/6/066803
    81. Ryan B. Comes, Steven R. Spurgeon, Steve M. Heald, Despoina M. Kepaptsoglou, Lewys Jones, Phuong Vu Ong, Mark E. Bowden, Quentin M. Ramasse, Peter V. Sushko, Scott A. Chambers. Interface‐Induced Polarization in SrTiO 3 ‐LaCrO 3 Superlattices. Advanced Materials Interfaces 2016, 3 (10) https://doi.org/10.1002/admi.201500779
    Download PDF
    Go to Nano Letters
    Get e-Alerts
    Get e-Alerts

    Nano Letters

    Cite this: Nano Lett. 2015, 15, 7, 4677–4684
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.nanolett.5b01471
    Published June 23, 2015
    Copyright © 2015 American Chemical Society
    Request reuse permissions

    Article Views

    3141

    Altmetric

    -

    Citations

    81
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.