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Cu–Pd Dinuclear Complexes with Earth-Abundant Cu Photosensitizer: Synthesis and Photopolymerization

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    Cu–Pd Dinuclear Complexes with Earth-Abundant Cu Photosensitizer: Synthesis and Photopolymerization
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    Organometallics

    Cite this: Organometallics 2020, 39, 13, 2464–2469
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    https://doi.org/10.1021/acs.organomet.0c00261
    Published June 21, 2020
    Copyright © 2020 American Chemical Society
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    Abstract

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    A series of new palladium complexes containing a Cu(I) photosensitizing unit were synthesized in good yields by the reaction of [(bpm)Pd(CH3)(solv.)]+ (bpm = 2,2′-bipyrimidine) complex with Cu(I) precursors. One of the Cu–Pd dinuclear complexes was structurally characterized by single-crystal X-ray diffraction and showed sterically congested Cu center. The Cu–Pd complexes catalyzed styrene polymerization under visible-light irradiation to furnish polystyrenes via a nonradical mechanism.

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.organomet.0c00261.

    • Synthetic and computational procedures, NMR spectral data for 3R1R2; crystal data and structure refinement for 2Me and 3MePh; DFT-optimized structures and MOs of 3MePh, 3MeMe, and 3PhPh (PDF)

    • Cartesian coordinates for 3MePh, 3MeMe, and 3PhPh (XYZ)

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    CCDC 1963713–1963714 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.

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    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

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    This article is cited by 8 publications.

    1. Jérôme Beaudelot, Samuel Oger, Stefano Peruško, Tuan-Anh Phan, Titouan Teunens, Cécile Moucheron, Gwilherm Evano. Photoactive Copper Complexes: Properties and Applications. Chemical Reviews 2022, 122 (22) , 16365-16609. https://doi.org/10.1021/acs.chemrev.2c00033
    2. Valentina Ferraro, Clara R. Adam, Aleksandra Vranic, Stefan Bräse. Recent Advances of Transition Metal Complexes for Photopolymerization and 3D Printing under Visible Light. Advanced Functional Materials 2024, 34 (20) https://doi.org/10.1002/adfm.202302157
    3. Frédéric Dumur. Recent Advances on Quinoxaline-Based Photoinitiators of Polymerization. Catalysts 2023, 13 (4) , 718. https://doi.org/10.3390/catal13040718
    4. Violetta Ionova, Anton Abel, Alexei Averin, Irina Beletskaya. Heterobinuclear Metallocomplexes as Photocatalysts in Organic Synthesis. Catalysts 2023, 13 (4) , 768. https://doi.org/10.3390/catal13040768
    5. Frédéric Dumur. Recent Advances on Furan-Based Visible Light Photoinitiators of Polymerization. Catalysts 2023, 13 (3) , 493. https://doi.org/10.3390/catal13030493
    6. Zoraida Freixa, Piet W. N. M. van Leeuwen, Philippe Kalck. Dinuclear Reactivity of One Metal Exalted by the Second One. 2023, 1-65. https://doi.org/10.1007/3418_2022_80
    7. Akiko Inagaki. Development of Metal Complexes to Utilize Visible-Light Energy into Molecular Transformation. Journal of Synthetic Organic Chemistry, Japan 2022, 80 (5) , 489-497. https://doi.org/10.5059/yukigoseikyokaishi.80.489
    8. Kira Behm, Ruaraidh D. McIntosh. Application of Discrete First‐Row Transition‐Metal Complexes as Photosensitisers. ChemPlusChem 2020, 85 (12) , 2611-2618. https://doi.org/10.1002/cplu.202000610
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    Organometallics

    Cite this: Organometallics 2020, 39, 13, 2464–2469
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.organomet.0c00261
    Published June 21, 2020
    Copyright © 2020 American Chemical Society
    Request reuse permissions

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