Iron-Catalyzed C–H Arylphosphorylation of QuinoxalinesClick to copy article linkArticle link copied!
- Maoyi DaiMaoyi DaiGuangxi Colleges and Universities Key Laboratory of Applied Chemistry Technology and Resource Development, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, P. R. ChinaMore by Maoyi Dai
- Meilan XuMeilan XuGuangxi Colleges and Universities Key Laboratory of Applied Chemistry Technology and Resource Development, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, P. R. ChinaMore by Meilan Xu
- Xiaoting GuXiaoting GuGuangxi Colleges and Universities Key Laboratory of Applied Chemistry Technology and Resource Development, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, P. R. ChinaMore by Xiaoting Gu
- Pengyan ZhangPengyan ZhangGuangxi Colleges and Universities Key Laboratory of Applied Chemistry Technology and Resource Development, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, P. R. ChinaMore by Pengyan Zhang
- Yukun XieYukun XieGuangxi Colleges and Universities Key Laboratory of Applied Chemistry Technology and Resource Development, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, P. R. ChinaMore by Yukun Xie
- Jin ZhugeJin ZhugeGuangxi Colleges and Universities Key Laboratory of Applied Chemistry Technology and Resource Development, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, P. R. ChinaMore by Jin Zhuge
- Xinting LiangXinting LiangGuangxi Colleges and Universities Key Laboratory of Applied Chemistry Technology and Resource Development, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, P. R. ChinaMore by Xinting Liang
- Runmin LiaoRunmin LiaoGuangxi Colleges and Universities Key Laboratory of Applied Chemistry Technology and Resource Development, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, P. R. ChinaMore by Runmin Liao
- Zongwu WeiZongwu WeiSchool of Resources, Environment and Materials, Guangxi University, Nanning, Guangxi 530004, P. R. ChinaMore by Zongwu Wei
- Zhuan ZhangZhuan ZhangGuangxi Colleges and Universities Key Laboratory of Applied Chemistry Technology and Resource Development, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, P. R. ChinaMore by Zhuan Zhang
- Taoyuan Liang*Taoyuan Liang*Email: [email protected]Guangxi Colleges and Universities Key Laboratory of Applied Chemistry Technology and Resource Development, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, P. R. ChinaMore by Taoyuan Liang
Abstract
A one-pot strategy for iron-catalyzed C2,3–H arylphosphorylation of electron-deficient quinoxalines with phosphines and aryl compounds is reported. The proposed method features the use of non-noble metal catalysts, the capacity of utilizing multiple aryl compounds as substrates, the simultaneous formation of C–P and C–C bonds in one pot, the simplicity of its operation, the mildness of the reaction conditions, and its compatibility with a wide range of substrates. Moreover, it offers a practical route for direct access to 2-aryl-3-phosphino N-heteroarenes, a class of potential cyclometalated C^N and N^P bidentate ligands that are difficult to prepare with existing C(sp2)–H functionalization methods.
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