Chlorine-Substituted 9,10-Dihydro-9-aza-10-boraanthracene as a Precursor for Various Boron- and Nitrogen-Containing π-Conjugated CompoundsClick to copy article linkArticle link copied!
- Yutaro IshikawaYutaro IshikawaDepartment of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, JapanMore by Yutaro Ishikawa
- Katsunori Suzuki*Katsunori Suzuki*E-mail: [email protected]Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, JapanMore by Katsunori Suzuki
- Kohei HayashiKohei HayashiDepartment of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, JapanMore by Kohei Hayashi
- Shin-ya NemaShin-ya NemaDepartment of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, JapanMore by Shin-ya Nema
- Makoto Yamashita*Makoto Yamashita*E-mail: [email protected]Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, JapanMore by Makoto Yamashita
Abstract

Chlorine-substituted 9,10-dihydro-9-aza-10-boraanthracene was synthesized. Derivatization of this compound by taking advantage of the transformable B–Cl moiety gave 9,10-dihydro-9-aza-10-boraanthracene derivatives with various aryl substituents. In addition, further functionalization on NH groups by alkylation and Buchwald–Hartwig amination was demonstrated. Photophysical properties of the resulting 9,10-dihydro-9-aza-10-boraanthracene derivatives were also discussed.
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