Di-(m-m-m)terphenyl-Embedded Decaphyrin and Its Bis-Rh(I) Complex
- Mainak DasMainak DasSchool of Chemical Sciences, National Institute of Science Education and Research (NISER), HBNI, Bhubaneswar 752050, Odisha, IndiaMore by Mainak Das
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- B. AdinarayanaB. AdinarayanaSchool of Chemical Sciences, National Institute of Science Education and Research (NISER), HBNI, Bhubaneswar 752050, Odisha, IndiaMore by B. Adinarayana
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- M. MurugavelM. MurugavelSchool of Chemical Sciences, National Institute of Science Education and Research (NISER), HBNI, Bhubaneswar 752050, Odisha, IndiaMore by M. Murugavel
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- Subhashree NayakSubhashree NayakSchool of Chemical Sciences, National Institute of Science Education and Research (NISER), HBNI, Bhubaneswar 752050, Odisha, IndiaMore by Subhashree Nayak
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- A. Srinivasan*A. Srinivasan*E-mail: [email protected]School of Chemical Sciences, National Institute of Science Education and Research (NISER), HBNI, Bhubaneswar 752050, Odisha, IndiaMore by A. Srinivasan
Abstract
A new rectangular-shaped carbadecaphyrin was successfully synthesized by introducing a terphenylene unit (m-m-m) in the macrocyclic core. The terphenylene moiety offers an open framework with multiple binding pockets to stabilize two Rh(I) ions in the core. The photophysical and structural studies reveal the non-aromatic character of the ligand and its bis-Rh(I) complex.
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