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ACS Publications. Most Trusted. Most Cited. Most Read
Engineering Human-Scale Artificial Bone Grafts for Treating Critical-Size Bone Defects
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    Engineering Human-Scale Artificial Bone Grafts for Treating Critical-Size Bone Defects
    Click to copy article linkArticle link copied!

    • Alessandro Cianciosi
      Alessandro Cianciosi
      Department of Chemistry, University of Rome “La Sapienza”, 00185 Rome, Italy
    • Marco Costantini
      Marco Costantini
      Department of Chemistry, University of Rome “La Sapienza”, 00185 Rome, Italy
      Institute of Physical Chemistry, Polish Academy of Sciences, 01-224 Warsaw, Poland
    • Sara Bergamasco
      Sara Bergamasco
      Department of Chemistry, University of Rome “La Sapienza”, 00185 Rome, Italy
    • Stefano Testa
      Stefano Testa
      Department of Biology, Rome University Tor Vergata, 00133 Rome, Italy
    • Ersilia Fornetti
      Ersilia Fornetti
      Department of Biology, Rome University Tor Vergata, 00133 Rome, Italy
    • Jakub Jaroszewicz
      Jakub Jaroszewicz
      Faculty of Materials Science and Engineering, Warsaw University of Technology, 00-661 Warsaw, Poland
    • Jacopo Baldi
      Jacopo Baldi
      IRCCS Regina Elena National Cancer Institute, 00144 Rome, Italy
      More by Jacopo Baldi
    • Alessandro Latini
      Alessandro Latini
      Department of Chemistry, University of Rome “La Sapienza”, 00185 Rome, Italy
    • Emilia Choińska
      Emilia Choińska
      Faculty of Materials Science and Engineering, Warsaw University of Technology, 00-661 Warsaw, Poland
    • Marcin Heljak
      Marcin Heljak
      Faculty of Materials Science and Engineering, Warsaw University of Technology, 00-661 Warsaw, Poland
    • Carmine Zoccali
      Carmine Zoccali
      IRCCS Regina Elena National Cancer Institute, 00144 Rome, Italy
    • Stefano Cannata
      Stefano Cannata
      Department of Biology, Rome University Tor Vergata, 00133 Rome, Italy
    • Wojciech Święszkowski
      Wojciech Święszkowski
      Faculty of Materials Science and Engineering, Warsaw University of Technology, 00-661 Warsaw, Poland
    • Andrés Diaz Lantada
      Andrés Diaz Lantada
      Mechanical Engineering Department, Universidad Politécnica de Madrid, 28006 Madrid, Spain
    • Cesare Gargioli*
      Cesare Gargioli
      Department of Biology, Rome University Tor Vergata, 00133 Rome, Italy
      *E-mail: [email protected] (C.G.).
    • Andrea Barbetta*
      Andrea Barbetta
      Department of Chemistry, University of Rome “La Sapienza”, 00185 Rome, Italy
      *E-mail: [email protected] (A.B.).
    Other Access OptionsSupporting Information (4)

    ACS Applied Bio Materials

    Cite this: ACS Appl. Bio Mater. 2019, 2, 11, 5077–5092
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    https://doi.org/10.1021/acsabm.9b00756
    Published October 22, 2019
    Copyright © 2019 American Chemical Society

    Abstract

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    The manufacturing of artificial bone grafts can potentially circumvent the issues associated with current bone grafting treatments for critical-size bone defects caused by pathological disorders, trauma, or massive tumor ablation. In this study, we report on a potentially patient-specific fabrication process in which replicas of bone defects, in particular zygomatic and mandibular bones and phalanxes of a hand finger, were manufactured by laser stereolithography and used as templates for the creation of PDMS molds. Gas-in-water foams were cast in the molds, rapidly frozen, freeze-dried, and cross-linked. Since bone matrix consists essentially of collagen and hydroxyapatite, biomimetic scaffolds were fabricated using gelatin and hydroxyapatite in a ratio very similar to that found in bone. The obtained composite scaffolds were excellent replicas of the original bone defects models and presented both a superficial and internal porous texture adequate for cellular and blood vessels infiltration. In particular, scaffolds exhibited a porous texture consisting of pores and interconnects with average size of about 300 and 100 μm, respectively, and a porosity of 90%. In vitro culture tests using hMSCs demonstrated scaffold biocompatibility and capacity in inducing differentiation toward osteoblasts progenitors. In vivo cellularized implants showed bone matrix deposition and recruitment of blood vessels. Overall, the technique/materials combination used in this work led to the fabrication of promising mechanically stable, bioactive, and biocompatible composite scaffolds with well-defined architectures potentially valuable in the regeneration of patient-specific bone defects.

    Copyright © 2019 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsabm.9b00756.

    • Scheme of the apparatus used in foaming tests (PDF)

    • Movie S1 showing molded foam zygomatic eye scaffold (MP4)

    • Movie S2 showing molded foam phalanxes scaffolds (AVI)

    • Movie S3 showing molded foam zygomatic eye scaffold (MP4)

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    Cited By

    Click to copy section linkSection link copied!

    This article is cited by 13 publications.

    1. Sumin Moon, Jongmin Q. Kim, Baekmin Q. Kim, Junsu Chae, Siyoung Q. Choi. Processable Composites with Extreme Material Capacities: Toward Designer High Internal Phase Emulsions and Foams. Chemistry of Materials 2020, 32 (11) , 4838-4854. https://doi.org/10.1021/acs.chemmater.9b04952
    2. Xi Zhao, Xinying Li, Xiaofen Xie, Jinfeng Lei, Liming Ge, Lun Yuan, Defu Li, Changdao Mu. Controlling the Pore Structure of Collagen Sponge by Adjusting the Cross-Linking Degree for Construction of Heterogeneous Double-Layer Bone Barrier Membranes. ACS Applied Bio Materials 2020, 3 (4) , 2058-2067. https://doi.org/10.1021/acsabm.9b01175
    3. Shital S. Shendage, Kranti Kachare, Kajal Gaikwad, Shivaji Kashte, Anil Vithal Ghule. Porous calcium silicate bioactive material–alginate composite for bone regeneration. RSC Advances 2024, 14 (35) , 25740-25749. https://doi.org/10.1039/D4RA02763A
    4. Yi Tan, Huan Sun, Yuanchen Lan, Haider Mohammed Khan, Hui Zhang, Linli Zhang, Fengying Zhang, Yujia Cui, Lan Zhang, Dingming Huang, Xinmei Chen, Changchun Zhou, Jianxun Sun, Xuedong Zhou. Study on 3D printed MXene-berberine-integrated scaffold for photo-activated antibacterial activity and bone regeneration. Journal of Materials Chemistry B 2024, 12 (8) , 2158-2179. https://doi.org/10.1039/D3TB02306K
    5. Khanish Gupta, Kusum Meena. Artificial bone scaffolds and bone joints by additive manufacturing: A review. Bioprinting 2023, 31 , e00268. https://doi.org/10.1016/j.bprint.2023.e00268
    6. Hadis Gharacheh, Murat Guvendiren. Three-dimensional bioprinting vascularized bone tissue. MRS Bulletin 2023, 48 (6) , 668-675. https://doi.org/10.1557/s43577-023-00547-y
    7. Krystian Kowiorski, Marcin Heljak, Agata Strojny-Nędza, Bartosz Bucholc, Marcin Chmielewski, Małgorzata Djas, Kamil Kaszyca, Rafał Zybała, Marcin Małek, Wojciech Swieszkowski, Adrian Chlanda. Compositing graphene oxide with carbon fibers enables improved dynamical thermomechanical behavior of papers produced at a large scale. Carbon 2023, 206 , 26-36. https://doi.org/10.1016/j.carbon.2023.02.009
    8. Sumbul Mirza, Reshma Jolly, Iram Zia, Mohd S. Umar, Mohammad Owais, Mohammad Shakir. Fabrication of Biobased Nanocomposites by Chemical Intervention of Nano‐Hydroxyapatite in Aloe Vera Gel‐Guava Seed Matrix for Bone Tissue Engineering. ChemistrySelect 2022, 7 (6) https://doi.org/10.1002/slct.202103051
    9. Martina Viola, Susanna Piluso, Jürgen Groll, Tina Vermonden, Jos Malda, Miguel Castilho. The Importance of Interfaces in Multi‐Material Biofabricated Tissue Structures. Advanced Healthcare Materials 2021, 10 (21) https://doi.org/10.1002/adhm.202101021
    10. Sabine Schulze, Rebecca Rothe, Christin Neuber, Sandra Hauser, Martin Ullrich, Jens Pietzsch, Stefan Rammelt. Men who stare at bone: multimodal monitoring of bone healing. Biological Chemistry 2021, 402 (11) , 1397-1413. https://doi.org/10.1515/hsz-2021-0170
    11. Chun-Ta Yu, Fu-Ming Wang, Yen-Ting Liu, Hooi Yee Ng, Yi-Rong Jhong, Chih-Hung Hung, Yi-Wen Chen. Effect of Bone Morphogenic Protein-2-Loaded Mesoporous Strontium Substitution Calcium Silicate/Recycled Fish Gelatin 3D Cell-Laden Scaffold for Bone Tissue Engineering. Processes 2020, 8 (4) , 493. https://doi.org/10.3390/pr8040493
    12. Víctor Santos-Rosales, Ana Iglesias-Mejuto, Carlos García-González. Solvent-Free Approaches for the Processing of Scaffolds in Regenerative Medicine. Polymers 2020, 12 (3) , 533. https://doi.org/10.3390/polym12030533
    13. Ilham Maimouni, Cesare M. Cejas, Janine Cossy, Patrick Tabeling, Maria Russo. Microfluidics Mediated Production of Foams for Biomedical Applications. Micromachines 2020, 11 (1) , 83. https://doi.org/10.3390/mi11010083

    ACS Applied Bio Materials

    Cite this: ACS Appl. Bio Mater. 2019, 2, 11, 5077–5092
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsabm.9b00756
    Published October 22, 2019
    Copyright © 2019 American Chemical Society

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