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Na3V2(PO4)3─A Highly Promising Anode and Cathode Material for Sodium-Ion Batteries

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    Na3V2(PO4)3─A Highly Promising Anode and Cathode Material for Sodium-Ion Batteries
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    • Tolga Akçay
      Tolga Akçay
      Institute for Applied Materials (IAM), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
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      Orcidhttps://orcid.org/0000-0002-1460-9541
    • Marcel Häringer
      Marcel Häringer
      Institute for Applied Materials (IAM), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
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    • Kristina Pfeifer
      Kristina Pfeifer
      Institute for Applied Materials (IAM), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
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    • Jens Anhalt
      Jens Anhalt
      Institute for Applied Materials (IAM), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
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    • Joachim R. Binder
      Joachim R. Binder
      Institute for Applied Materials (IAM), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
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      Orcidhttps://orcid.org/0000-0003-2237-1411
    • Sonia Dsoke
      Sonia Dsoke
      Institute for Applied Materials (IAM), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
      Helmholtz-Institute Ulm for Electrochemical Energy Storage (HIU), P.O. Box 3640, 76021 Karlsruhe, Germany
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      Orcidhttps://orcid.org/0000-0001-9295-2110
    • Dominik Kramer*
      Dominik Kramer
      Institute for Applied Materials (IAM), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
      *Email: [email protected]
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    • Reiner Mönig
      Reiner Mönig
      Institute for Applied Materials (IAM), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
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    ACS Applied Energy Materials

    Cite this: ACS Appl. Energy Mater. 2021, 4, 11, 12688–12695
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    https://doi.org/10.1021/acsaem.1c02413
    Published October 29, 2021
    Copyright © 2021 The Authors. Published by American Chemical Society
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    Abstract

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    Sodium-ion batteries may develop into a cost-efficient alternative to lithium-ion batteries. Na3V2(PO4)3/C (NVP/C) is known to be a suitable electrode material for such batteries that can be used as an anode or cathode. Here, NVP/C-based electrodes were investigated in different cell configurations. The electrodes were cycled against the anode materials hard carbon, Sb/C, SnSb/C, and sodium metal. Furthermore, NVP versus NVP was investigated. When NVP/C is cycled against the other anode materials, the cells exhibit relatively poor reliability, but in NVP–NVP cells, a high cycling stability was observed and more than 1500 cycles with a capacity retention of 80% were achieved. This work demonstrates that common problems of Na and Na-ion cells result from the anode materials used and that NVP/C itself is very reliable both as an anode and cathode material.

    Copyright © 2021 The Authors. Published by American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsaem.1c02413.

    • Characterization of as-synthesized NVP/C (SEM image and XRD pattern); additional electrochemical data of NVP/C; and equation for proper cell balancing in full cells (PDF)

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    Cited By

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    This article is cited by 12 publications.

    1. Akshita Sharma, Tejveer Singh Anand, Rajashri Urkude, Amit Gupta, Ashok Kumar Ganguli. Na3V2(PO4)3/C in Symmetric Cells: Evaluating Anode and Cathode Performance. The Journal of Physical Chemistry C 2024, 128 (46) , 19499-19509. https://doi.org/10.1021/acs.jpcc.4c05183
    2. Kriti Choudhary, Sunkyu Park, François Fauth, François Rabuel, Charles Delacourt, Vincent Seznec, Jean-Noël Chotard. Effect of Temperature on Intermediate Phases of Na3V2(PO4)3 during Cycling by Operando X-ray Diffraction. ACS Applied Materials & Interfaces 2024, 16 (43) , 58609-58616. https://doi.org/10.1021/acsami.4c11920
    3. Sudharshan Vasudevan, Sushmita Dwivedi, Karthick Babu Morekonda Ganesh Babu, Palani Balaya. Investigation of Solid Polymer Electrolytes for NASICON-Type Solid-State Symmetric Sodium-Ion Battery. ACS Applied Materials & Interfaces 2024, 16 (38) , 50736-50746. https://doi.org/10.1021/acsami.4c10189
    4. Nikhil Chandran Mukkattu Kuniyil, Ranjan Robin, Rajesh Kumar Kumarasamy, S. T. Nishanthi, Marappan Sathish. Tailoring of High-Valent Sn-Doped Porous Na3V2(PO4)3/C Nanoarchitechtonics: An Ultra High-Rate Cathode for Sodium-Ion Batteries. ACS Applied Materials & Interfaces 2024, 16 (22) , 28599-28612. https://doi.org/10.1021/acsami.4c04244
    5. Bidhan Pandit, Morten Johansen, Cynthia Susana Martínez-Cisneros, Johanna M. Naranjo-Balseca, Belen Levenfeld, Dorthe Bomholdt Ravnsbæk, Alejandro Varez. Na3V2(PO4)3 Cathode for Room-Temperature Solid-State Sodium-Ion Batteries: Advanced In Situ Synchrotron X-ray Studies to Understand Intermediate Phase Evolution. Chemistry of Materials 2024, 36 (5) , 2314-2324. https://doi.org/10.1021/acs.chemmater.3c02585
    6. Eldho Edison, Annapaola Parrilli, Elena Tervoort, Henrik Eliasson, Markus Niederberger. Oriented Porous NASICON 3D Framework via Freeze-Casting for Sodium-Metal Batteries. ACS Applied Materials & Interfaces 2023, 15 (27) , 32313-32319. https://doi.org/10.1021/acsami.3c03583
    7. Zixiang Guo, Yuzhe Zhang, Shiyu Liu, Xiaonian Xue, Peiming Song, Xue Qin, Yulong Xie. Decorating Lithium Titanium-Phosphate Carbon Layers with Mo2C as Efficient Li-Ion Storage Electrode. ACS Applied Energy Materials 2023, 6 (7) , 3724-3734. https://doi.org/10.1021/acsaem.2c03845
    8. Yao Liu, Xiangyong Wu, Abdul Moeez, Zhi Peng, Yongyao Xia, Dongyuan Zhao, Jun Liu, Wei Li. Na‐Rich Na 3 V 2 (PO 4 ) 3 Cathodes for Long Cycling Rechargeable Sodium Full Cells. Advanced Energy Materials 2023, 13 (3) , 2203283. https://doi.org/10.1002/aenm.202203283
    9. Ping Hu, Ting Zhu, Congcong Cai, Bo Mai, Chen Yang, Jianmin Ma, Liang Zhou, Hong Jin Fan, Liqiang Mai. Sodium Ion Storage in Na 4 MnV(PO 4 ) 3 @C Free‐Standing Electrode. Advanced Functional Materials 2022, 32 (52) , 2208051. https://doi.org/10.1002/adfm.202208051
    10. Manuel Baumann, Marcel Häringer, Marius Schmidt, Luca Schneider, Jens F. Peters, Werner Bauer, Joachim R. Binder, Marcel Weil. Prospective Sustainability Screening of Sodium‐Ion Battery Cathode Materials. Advanced Energy Materials 2022, 12 (46) , 2202636. https://doi.org/10.1002/aenm.202202636
    11. Ijaz Ul Mohsin, Luca Schneider, Marcel Häringer, Carlos Ziebert, Magnus Rohde, Werner Bauer, Helmut Ehrenberg, Hans Jürgen Seifert. Heat generation and degradation mechanisms studied on Na3V2(PO4)3/C positive electrode material in full pouch / coin cell assembly. Journal of Power Sources 2022, 545 , 231901. https://doi.org/10.1016/j.jpowsour.2022.231901
    12. Archana Kanwade, Sheetal Gupta, Akash Kankane, Abhishek Srivastava, Subhash Chand Yadav, Parasharam M. Shirage. Phosphate-based cathode materials to boost the electrochemical performance of sodium-ion batteries. Sustainable Energy & Fuels 2022, 6 (13) , 3114-3147. https://doi.org/10.1039/D2SE00475E
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    ACS Applied Energy Materials

    Cite this: ACS Appl. Energy Mater. 2021, 4, 11, 12688–12695
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsaem.1c02413
    Published October 29, 2021
    Copyright © 2021 The Authors. Published by American Chemical Society
    Request reuse permissions

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