Tracking Compression Changes in an Aqueous Electrolyte for Real-Time H2 and O2 Gas Evolution Quantification during Total Water Splitting Using BARDS
- Aaron Kang
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- Alanood AlkhraijeAlanood AlkhraijeSchool of Chemistry, University College Cork, Cork T12 YN60, IrelandMore by Alanood Alkhraije
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- Seán McSweeney
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- Anas AlfarsiAnas AlfarsiSchool of Chemistry, University College Cork, Cork T12 YN60, IrelandAnalytical and Biological Chemistry Research Facility (ABCRF), University College Cork, Cork T12 YN60, IrelandMore by Anas Alfarsi
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- Rizwan AhmedRizwan AhmedSchool of Chemistry, University College Cork, Cork T12 YN60, IrelandAnalytical and Biological Chemistry Research Facility (ABCRF), University College Cork, Cork T12 YN60, IrelandMore by Rizwan Ahmed
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- Jacob Krüse
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- Colm O’DwyerColm O’DwyerSchool of Chemistry, University College Cork, Cork T12 YN60, IrelandTyndall National Institute, Lee Maltings, Cork T12 R5CP, IrelandEnvironmental Research Institute, Lee Road, Cork T23 XE10, IrelandAMBER@CRANN, Trinity College Dublin, Dublin 2 D02 PD91, IrelandMore by Colm O’Dwyer
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- Dara Fitzpatrick*Dara Fitzpatrick*E-mail [email protected]School of Chemistry, University College Cork, Cork T12 YN60, IrelandAnalytical and Biological Chemistry Research Facility (ABCRF), University College Cork, Cork T12 YN60, IrelandEnvironmental Research Institute, Lee Road, Cork T23 XE10, IrelandMore by Dara Fitzpatrick
Abstract

Hydrogen fuel cell technology has the potential for integration with renewable energy sources to produce electricity without the need for fossil fuels. Efforts are being made in producing cheap and effective electrodes from new materials to make hydrogen production more efficient. Gas evolution, in all cases, requires an accurate analysis of electrochemical behavior of electrodes to quantify efficiency, improvement, or stability. Knowing the exact gas volume by any method in real time during electrochemical water splitting is urgently needed. Taking inspiration from the existing technique broadband acoustic resonance dissolution spectroscopy (BARDS), we demonstrate an original approach to continuously track the electrochemical water splitting via the gas volume evolution from hydrogen evolution reactions (HER) and oxygen evolution reactions (OER) processes. The technique may be used to unravel the true features of new electrode materials that evolve hydrogen and correlate material electrochemistry to the true gas volume evolved in real time.
Cited By
This article is cited by 1 publications.
- Huanzhu Lv, Xiang Long Huang, Xiaoqi Zhu, Bin Wang. Metal-related electrocatalysts for Li–CO 2 batteries: an overview of the fundamentals to explore future-oriented strategies. Journal of Materials Chemistry A 2022, 10 (48) , 25406-25430. https://doi.org/10.1039/D2TA05756E