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Tracking Compression Changes in an Aqueous Electrolyte for Real-Time H2 and O2 Gas Evolution Quantification during Total Water Splitting Using BARDS

  • Aaron Kang
    Aaron Kang
    School of Chemistry, University College Cork, Cork T12 YN60, Ireland
    More by Aaron Kang
  • Alanood Alkhraije
    Alanood Alkhraije
    School of Chemistry, University College Cork, Cork T12 YN60, Ireland
  • Seán McSweeney
    Seán McSweeney
    BARDS Acoustic Science Laboratories, Cork T12 YN60, Ireland
  • Anas Alfarsi
    Anas Alfarsi
    School of Chemistry, University College Cork, Cork T12 YN60, Ireland
    Analytical and Biological Chemistry Research Facility (ABCRF), University College Cork, Cork T12 YN60, Ireland
    More by Anas Alfarsi
  • Rizwan Ahmed
    Rizwan Ahmed
    School of Chemistry, University College Cork, Cork T12 YN60, Ireland
    Analytical and Biological Chemistry Research Facility (ABCRF), University College Cork, Cork T12 YN60, Ireland
    More by Rizwan Ahmed
  • Jacob Krüse
    Jacob Krüse
    Kinetox, Kruiskruidlaan 11, 9413 BB Beilen, The Netherlands
    More by Jacob Krüse
  • Colm O’Dwyer
    Colm O’Dwyer
    School of Chemistry, University College Cork, Cork T12 YN60, Ireland
    Tyndall National Institute, Lee Maltings, Cork T12 R5CP, Ireland
    Environmental Research Institute, Lee Road, Cork T23 XE10, Ireland
    AMBER@CRANN, Trinity College Dublin, Dublin 2 D02 PD91, Ireland
  • , and 
  • Dara Fitzpatrick*
    Dara Fitzpatrick
    School of Chemistry, University College Cork, Cork T12 YN60, Ireland
    Analytical and Biological Chemistry Research Facility (ABCRF), University College Cork, Cork T12 YN60, Ireland
    Environmental Research Institute, Lee Road, Cork T23 XE10, Ireland
    *E-mail [email protected]
Cite this: ACS Appl. Energy Mater. 2020, 3, 2, 2000–2009
Publication Date (Web):January 17, 2020
https://doi.org/10.1021/acsaem.9b02436
Copyright © 2020 American Chemical Society

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    Abstract

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    Hydrogen fuel cell technology has the potential for integration with renewable energy sources to produce electricity without the need for fossil fuels. Efforts are being made in producing cheap and effective electrodes from new materials to make hydrogen production more efficient. Gas evolution, in all cases, requires an accurate analysis of electrochemical behavior of electrodes to quantify efficiency, improvement, or stability. Knowing the exact gas volume by any method in real time during electrochemical water splitting is urgently needed. Taking inspiration from the existing technique broadband acoustic resonance dissolution spectroscopy (BARDS), we demonstrate an original approach to continuously track the electrochemical water splitting via the gas volume evolution from hydrogen evolution reactions (HER) and oxygen evolution reactions (OER) processes. The technique may be used to unravel the true features of new electrode materials that evolve hydrogen and correlate material electrochemistry to the true gas volume evolved in real time.

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsaem.9b02436.

    • Details of sulfuric acid electrolyte concentrations, gas elimination curves for each cycle as a function of H2SO4 concentration, and applied voltage; background theory for estimated gas volumes and associated calculations; additional simulations of water oxidation processes during BARDS together with details on the calculation of the kel and kprod parameters (PDF)

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    Cited By

    This article is cited by 1 publications.

    1. Huanzhu Lv, Xiang Long Huang, Xiaoqi Zhu, Bin Wang. Metal-related electrocatalysts for Li–CO 2 batteries: an overview of the fundamentals to explore future-oriented strategies. Journal of Materials Chemistry A 2022, 10 (48) , 25406-25430. https://doi.org/10.1039/D2TA05756E

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