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Download Hi-Res ImageDownload to MS-PowerPointCite This:ACS Appl. Mater. Interfaces 2020, 12, 16, 19184-19193
    Research Article

    Capsules of Reactive Ionic Liquids for Selective Capture of Carbon Dioxide at Low Concentrations
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    • Yun-Yang Lee
      Yun-Yang Lee
      Department of Chemical Engineering Biomolecular Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, Ohio 44106, United States
      More by Yun-Yang Lee
    • Katelynn Edgehouse
      Katelynn Edgehouse
      Department of Chemistry, Department of Materials Science and Engineering, Texas A&M University, 3003 TAMU, College Station, Texas 77843, United States
      More by Katelynn Edgehouse
      Orcidhttp://orcid.org/0000-0003-0910-8723
    • Aidan Klemm
      Aidan Klemm
      Department of Chemical Engineering Biomolecular Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, Ohio 44106, United States
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    • Hongchao Mao
      Hongchao Mao
      Department of Chemical Engineering Biomolecular Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, Ohio 44106, United States
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    • Emily Pentzer
      Emily Pentzer
      Department of Chemistry, Department of Materials Science and Engineering, Texas A&M University, 3003 TAMU, College Station, Texas 77843, United States
      More by Emily Pentzer
      Orcidhttp://orcid.org/0000-0001-6187-6135
    • Burcu Gurkan*
      Burcu Gurkan
      Department of Chemical Engineering Biomolecular Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, Ohio 44106, United States
      *Email: [email protected]
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      Orcidhttp://orcid.org/0000-0003-4886-3350
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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2020, 12, 16, 19184–19193
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    https://doi.org/10.1021/acsami.0c01622
    Published April 2, 2020
    Copyright © 2020 American Chemical Society
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    Abstract

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    The task-specific ionic liquid (IL), 1-ethyl-3-methylimidazolium 2-cyanopyrolide ([EMIM][2-CNpyr]), was encapsulated with polyurea (PU) and graphene oxide (GO) sheets via a one-pot Pickering emulsion, and these capsules were used to scrub CO2 (0–5000 ppm) from moist air. Up to 60 wt % of IL was achieved in the synthesized capsules, and we demonstrated comparable gravimetric CO2 capacities to zeolites and enhanced absorption rates compared to those of bulk IL due to the increased gas/liquid surface-to-volume area. The reactive IL capsules show recyclability upon mild temperature increase compared to zeolites that are the conventional absorber materials for CO2 scrubbing. The measured breakthrough curves in a fixed bed under 100% relative humidity establish the utility of reactive IL capsules as moisture-stable scrubber materials to separate CO2 from air, outperforming zeolites owing to their higher selectivity. It is shown that thermal stability, CO2 absorption capacity, and rate of uptake by IL capsules can be further modulated by incorporating low-viscosity and nonreactive ILs to the capsule core. This study demonstrates an alternative and facile approach for CO2 scrubbing, where separation from gas mixtures with extremely low partial pressures of CO2 is required.

    Copyright © 2020 American Chemical Society

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    • NMR, isotherm fit parameters, absorption rates, VFT parameters, composition of synthesized capsules, zeolite absorption–desorption and breakthrough, and CO2 isotherms for ILs (PDF)

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    Cite this: ACS Appl. Mater. Interfaces 2020, 12, 16, 19184–19193
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