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Non-Hygroscopic, Self-Absorption Free, and Efficient 1D CsCu2I3 Perovskite Single Crystal for Radiation Detection

  • Shuangliang Cheng
    Shuangliang Cheng
    Shanghai Institute of Ceramics, Chinese Academy of Sciences, 585 He-shuo Road, Shanghai 201899, P. R. China
    University of Shanghai for Science and Technology, 516 Jun-gong Road, Shanghai 200093, P. R. China
    More by Shuangliang Cheng
  • , 
  • Alena Beitlerova
    Alena Beitlerova
    Institute of Physics of the Czech Academy of Sciences, Cukrovarnicka 10/112, Prague 16200, Czech Republic
    More by Alena Beitlerova
  • , 
  • Romana Kucerkova
    Romana Kucerkova
    Institute of Physics of the Czech Academy of Sciences, Cukrovarnicka 10/112, Prague 16200, Czech Republic
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  • , 
  • Eva Mihokova
    Eva Mihokova
    Institute of Physics of the Czech Academy of Sciences, Cukrovarnicka 10/112, Prague 16200, Czech Republic
    More by Eva Mihokova
  • , 
  • Martin Nikl
    Martin Nikl
    Institute of Physics of the Czech Academy of Sciences, Cukrovarnicka 10/112, Prague 16200, Czech Republic
    More by Martin Nikl
    Orcidhttp://orcid.org/0000-0002-2378-208X
  • , 
  • Zhengyang Zhou
    Zhengyang Zhou
    Shanghai Institute of Ceramics, Chinese Academy of Sciences, 585 He-shuo Road, Shanghai 201899, P. R. China
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  • , 
  • Guohao Ren
    Guohao Ren
    Shanghai Institute of Ceramics, Chinese Academy of Sciences, 585 He-shuo Road, Shanghai 201899, P. R. China
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  • , and 
  • Yuntao Wu*
    Yuntao Wu
    Shanghai Institute of Ceramics, Chinese Academy of Sciences, 585 He-shuo Road, Shanghai 201899, P. R. China
    *Email: [email protected], [email protected]
    More by Yuntao Wu
    Orcidhttp://orcid.org/0000-0002-9708-0304
Cite this: ACS Appl. Mater. Interfaces 2021, 13, 10, 12198–12202
Publication Date (Web):March 3, 2021
https://doi.org/10.1021/acsami.0c22505
Copyright © 2021 American Chemical Society
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    Abstract

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    A novel all-inorganic CsCu2I3 single-crystalline perovskite as a nonhygroscopic and efficient X-ray and γ-ray scintillator is described herein. It is featured by a one-dimensional (1D) perovskite structure with an orthorhombic system and a space group of Cmcm. The CsCu2I3 crystal emits yellow light peaking at 570 nm originated from strongly localized 1D exciton emission. It appears self-absorption free because of the large Stokes shift of 1.54 eV. The photophysics process of the self-trapped exciton was studied using temperature dependent photoluminescene spectra and decay kinetics measurements. The CsCu2I3 crystal exhibits an extremely low afterglow level of 0.008% at 10 ms under X-ray excitation. Under 137Cs γ-ray irradiation, its light yield is 16 000 photons/MeV with an energy resolution of 7.8% at 662 keV.

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsami.0c22505.

    • Experimental description of crystal growth, single crystal X-ray diffraction, DTA, hygroscopicity test, and optical and scintillation measurements; single-crystal X-ray diffraction image, refinement results, and activation energy of thermal quenching fitting curve (PDF)

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