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Nonradiative Energy Transfer and Selective Charge Transfer in a WS2/(PEA)2PbI4 Heterostructure

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    Surfaces, Interfaces, and Applications

    Nonradiative Energy Transfer and Selective Charge Transfer in a WS2/(PEA)2PbI4 Heterostructure
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    • Miriam Karpińska
      Miriam Karpińska
      Laboratoire National des Champs Magnétiques Intenses, UPR 3228, CNRS-UGA-UPS-INSA, 38042 Grenoble and 31400 Toulouse, France
      Institute of Physics, Polish Academy of Sciences, 02-668 Warsaw, Poland
      More by Miriam Karpińska
    • Minpeng Liang
      Minpeng Liang
      Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands
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    • Roman Kempt
      Roman Kempt
      Technische Universität Dresden, Bergstr. 66c, 01062 Dresden, Germany
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    • Kati Finzel
      Kati Finzel
      Technische Universität Dresden, Bergstr. 66c, 01062 Dresden, Germany
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      Orcidhttps://orcid.org/0000-0002-0862-2782
    • Machteld Kamminga
      Machteld Kamminga
      Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands
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    • Mateusz Dyksik
      Mateusz Dyksik
      Laboratoire National des Champs Magnétiques Intenses, UPR 3228, CNRS-UGA-UPS-INSA, 38042 Grenoble and 31400 Toulouse, France
      Department of Experimental Physics, Faculty of Fundamental Problems of Technology, Wroclaw University of Science and Technology, 50-370 Wroclaw, Poland
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      Orcidhttps://orcid.org/0000-0003-4945-8795
    • Nan Zhang
      Nan Zhang
      Laboratoire National des Champs Magnétiques Intenses, UPR 3228, CNRS-UGA-UPS-INSA, 38042 Grenoble and 31400 Toulouse, France
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      Orcidhttps://orcid.org/0000-0003-4269-6811
    • Catherine Knodlseder
      Catherine Knodlseder
      Laboratoire National des Champs Magnétiques Intenses, UPR 3228, CNRS-UGA-UPS-INSA, 38042 Grenoble and 31400 Toulouse, France
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    • Duncan K. Maude
      Duncan K. Maude
      Laboratoire National des Champs Magnétiques Intenses, UPR 3228, CNRS-UGA-UPS-INSA, 38042 Grenoble and 31400 Toulouse, France
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    • Michał Baranowski
      Michał Baranowski
      Department of Experimental Physics, Faculty of Fundamental Problems of Technology, Wroclaw University of Science and Technology, 50-370 Wroclaw, Poland
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      Orcidhttps://orcid.org/0000-0002-5974-0850
    • Łukasz Kłopotowski
      Łukasz Kłopotowski
      Institute of Physics, Polish Academy of Sciences, 02-668 Warsaw, Poland
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      Orcidhttps://orcid.org/0000-0001-8327-2156
    • Jianting Ye
      Jianting Ye
      Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands
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    • Agnieszka Kuc*
      Agnieszka Kuc
      Helmholtz-Zentrum Dresden-Rossendorf, Bautzner Landstrasse 400, 01328 Dresden, Germany
      *Email: [email protected]
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      Orcidhttps://orcid.org/0000-0002-9458-4136
    • Paulina Plochocka*
      Paulina Plochocka
      Laboratoire National des Champs Magnétiques Intenses, UPR 3228, CNRS-UGA-UPS-INSA, 38042 Grenoble and 31400 Toulouse, France
      Department of Experimental Physics, Faculty of Fundamental Problems of Technology, Wroclaw University of Science and Technology, 50-370 Wroclaw, Poland
      *Email: [email protected]
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      Orcidhttps://orcid.org/0000-0002-4019-6138
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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2021, 13, 28, 33677–33684
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    https://doi.org/10.1021/acsami.1c08377
    Published July 6, 2021
    Copyright © 2021 American Chemical Society
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    Abstract

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    van der Waals heterostructures are currently the focus of intense investigation; this is essentially due to the unprecedented flexibility offered by the total relaxation of lattice matching requirements and their new and exotic properties compared to the individual layers. Here, we investigate the hybrid transition-metal dichalcogenide/2D perovskite heterostructure WS2/(PEA)2PbI4 (where PEA stands for phenylethylammonium). We present the first density functional theory (DFT) calculations of a heterostructure ensemble, which reveal a novel band alignment, where direct electron transfer is blocked by the organic spacer of the 2D perovskite. In contrast, the valence band forms a cascade from WS2 through the PEA to the PbI4 layer allowing hole transfer. These predictions are supported by optical spectroscopy studies, which provide compelling evidence for both charge transfer and nonradiative transfer of the excitation (energy transfer) between the layers. Our results show that TMD/2D perovskite (where TMD stands for transition-metal dichalcogenides) heterostructures provide a flexible and convenient way to engineer the band alignment.

    Copyright © 2021 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsami.1c08377.

    • PL spectra taken of bare WS2 flake and the PEPI/WS2 heterostructure with excitation 488 nm, spatial PL intensity map of bound exciton peak of PEPI, trion-to-exciton PL intensity ratio, and optical images of heterostructure just after stacking procedure (PDF)

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    This article is cited by 15 publications.

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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2021, 13, 28, 33677–33684
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsami.1c08377
    Published July 6, 2021
    Copyright © 2021 American Chemical Society
    Request reuse permissions

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