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Uniaxially Oriented Electrically Conductive Metal–Organic Framework Nanosheets Assembled at Air/Liquid Interfaces

  • Takashi Ohata
    Takashi Ohata
    Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Nakaku, Sakai, Osaka 599-8570, Japan
  • Akihiro Nomoto
    Akihiro Nomoto
    Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8570, Japan
  • Takeshi Watanabe
    Takeshi Watanabe
    Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan
  • Ichiro Hirosawa
    Ichiro Hirosawa
    Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan
  • Tatsuyuki Makita
    Tatsuyuki Makita
    Material Innovation Research Center (MIRC) and Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan
  • Jun Takeya
    Jun Takeya
    Material Innovation Research Center (MIRC) and Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan
    More by Jun Takeya
  • , and 
  • Rie Makiura*
    Rie Makiura
    Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Nakaku, Sakai, Osaka 599-8570, Japan
    *Email: [email protected]
    More by Rie Makiura
Cite this: ACS Appl. Mater. Interfaces 2021, 13, 45, 54570–54578
Publication Date (Web):October 27, 2021
https://doi.org/10.1021/acsami.1c16180
Copyright © 2021 American Chemical Society

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    Abstract

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    Although most metal–organic frameworks (MOFs)─highly porous crystalline metal complex networks with structural and functional varieties─are electrically insulating, high electrical conduction has been recently demonstrated in MOFs while retaining permanent porosity. Usability of electronically active MOFs effectively emerges when they are created in a thin-film state as required in major potential applications such as chemiresistive sensors, supercapacitors, and electrode catalysts. Thin-film morphology including crystallinity, thickness, density, roughness, and orientation sensitively influences device performance. Fine control of such morphological parameters still remains as a main issue to be addressed. Here, we report a bottom-up procedure of assembling a conductive MOF nanosheet composed of 2,3,6,7,10,11-hexaiminotriphenylene molecules and nickel ions (HITP-Ni-NS). Creation of HITP-Ni-NS is achieved by applying air/liquid (A/L) interfacial bottom-up synthesis. HITP-Ni-NS has a multilayered structure with 14 nm thickness and is endowed with high crystallinity and uniaxial orientation, demonstrated by synchrotron X-ray crystallography. Facile transferability of HITP-Ni-NS assembled at air/liquid interfaces to any desired substrate enables us to measure its electrical conductivity, recorded as 0.6 S cm–1─highest among those of triphenylene-based MOF nanosheets with a thickness lower than 100 nm.

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsami.1c16180.

    • Experimental details; BAM, AFM, SEM, and TEM images, XPS spectra, structural models, and optical microscopy image for HITP-Ni-NS; and π–A isotherm, BAM, AFM, and SEM images, UV–vis and IR absorption spectra, XPS spectra, and electrical conductivity for HATP-water-NS (PDF)

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    Cited By

    This article is cited by 13 publications.

    1. Kazuaki Tachimoto, Takashi Ohata, Kanokwan Jumtee Takeno, Akihiro Nomoto, Takeshi Watanabe, Ichiro Hirosawa, Rie Makiura. Assembling Triphenylene-Based Metal–Organic Framework Nanosheets at the Air/Liquid Interface: Modification by Tuning the Spread Solution Concentration. Langmuir 2023, 39 (26) , 8952-8962. https://doi.org/10.1021/acs.langmuir.2c02685
    2. Víctor Rubio-Giménez, Giel Arnauts, Mingchao Wang, Eduardo Sergio Oliveros Mata, Xing Huang, Tianshu Lan, Max L. Tietze, Dmitry E. Kravchenko, Jorid Smets, Nathalie Wauteraerts, Azat Khadiev, Dmitri V. Novikov, Denys Makarov, Renhao Dong, Rob Ameloot. Chemical Vapor Deposition and High-Resolution Patterning of a Highly Conductive Two-Dimensional Coordination Polymer Film. Journal of the American Chemical Society 2023, 145 (1) , 152-159. https://doi.org/10.1021/jacs.2c09007
    3. Islam E. Khalil, Javier Fonseca, Michael R. Reithofer, Tanja Eder, Jia Min Chin. Tackling orientation of metal-organic frameworks (MOFs): The quest to enhance MOF performance. Coordination Chemistry Reviews 2023, 481 , 215043. https://doi.org/10.1016/j.ccr.2023.215043
    4. Takashi Ohata, Kazuaki Tachimoto, Kanokwan Jumtee Takeno, Akihiro Nomoto, Takeshi Watanabe, Ichiro Hirosawa, Rie Makiura. Influence of the Solvent on the Assembly of Ni 3 (hexaiminotriphenylene) 2 Metal–Organic Framework Nanosheets at the Air/Liquid Interface. Bulletin of the Chemical Society of Japan 2023, 96 (3) , 274-282. https://doi.org/10.1246/bcsj.20220283
    5. Anamika Ghosh, Sana Fathima Thanutty Kallungal, Sundara Ramaprabhu. 2D Metal-Organic Frameworks: Properties, Synthesis, and Applications in Electrochemical and Optical Biosensors. Biosensors 2023, 13 (1) , 123. https://doi.org/10.3390/bios13010123
    6. Xuan Sun, Yuanli Li, Hui Su, Xiuxiu Zhang, Yanzhi Xu, Wanlin Zhou, Meihuan Liu, Weiren Cheng, Qinghua Liu. Dissecting π-conjugated covalent-coupling over conductive MOFs toward efficient two-electron oxygen reduction. Applied Catalysis B: Environmental 2022, 317 , 121706. https://doi.org/10.1016/j.apcatb.2022.121706
    7. Hiroaki Maeda, Kenji Takada, Naoya Fukui, Sayoko Nagashima, Hiroshi Nishihara. Conductive coordination nanosheets: Sailing to electronics, energy storage, and catalysis. Coordination Chemistry Reviews 2022, 470 , 214693. https://doi.org/10.1016/j.ccr.2022.214693
    8. Hang Wang, Pengfei Zhao, Xingmao Zhang, Su Zhang, Xiaolong Lu, Zhipeng Qiu, Kang Ren, Zheng Xu, Ruxin Yao, Tong Wei, Zhuangjun Fan. Holey graphene oxide-templated construction of nano nickel-based metal—organic framework for highly efficient asymmetric supercapacitor. Nano Research 2022, 15 (10) , 9047-9056. https://doi.org/10.1007/s12274-022-4902-5
    9. Rie Makiura. Creation of metal–organic framework nanosheets by the Langmuir-Blodgett technique. Coordination Chemistry Reviews 2022, 469 , 214650. https://doi.org/10.1016/j.ccr.2022.214650
    10. Katsuhiko Ariga. Materials nanoarchitectonics in a two-dimensional world within a nanoscale distance from the liquid phase. Nanoscale 2022, 14 (30) , 10610-10629. https://doi.org/10.1039/D2NR02513B
    11. Junya Adachi, Masaya Naito, Sho Sugiura, Ngoc Ha-Thu Le, Shoma Nishimura, Shufang Huang, Shuichi Suzuki, Soichiro Kawamorita, Naruyoshi Komiya, Jonathan P. Hill, Katsuhiko Ariga, Takeshi Naota, Taizo Mori. Coordination Amphiphile: Design of Planar-Coordinated Platinum Complexes for Monolayer Formation at an Air-Water Interface Based on Ligand Characteristics and Molecular Topology. Bulletin of the Chemical Society of Japan 2022, 95 (6) , 889-897. https://doi.org/10.1246/bcsj.20220086
    12. Linan Cao, Min Wei. Recent Progress of Electric Conductive Metal-Organic Frameworks Thin Film. Acta Chimica Sinica 2022, 80 (7) , 1042. https://doi.org/10.6023/A22010024
    13. AshokKumar Meiyazhagan. Ultrathin metal–organic framework nanosheets and devices. Oxford Open Materials Science 2020, 1 (1) https://doi.org/10.1093/oxfmat/itab019

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