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Uniaxially Oriented Electrically Conductive Metal–Organic Framework Nanosheets Assembled at Air/Liquid Interfaces

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    Surfaces, Interfaces, and Applications

    Uniaxially Oriented Electrically Conductive Metal–Organic Framework Nanosheets Assembled at Air/Liquid Interfaces
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    • Takashi Ohata
      Takashi Ohata
      Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Nakaku, Sakai, Osaka 599-8570, Japan
      More by Takashi Ohata
    • Akihiro Nomoto
      Akihiro Nomoto
      Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8570, Japan
      More by Akihiro Nomoto
    • Takeshi Watanabe
      Takeshi Watanabe
      Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan
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    • Ichiro Hirosawa
      Ichiro Hirosawa
      Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan
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    • Tatsuyuki Makita
      Tatsuyuki Makita
      Material Innovation Research Center (MIRC) and Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan
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    • Jun Takeya
      Jun Takeya
      Material Innovation Research Center (MIRC) and Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan
      More by Jun Takeya
    • Rie Makiura*
      Rie Makiura
      Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Nakaku, Sakai, Osaka 599-8570, Japan
      *Email: [email protected]
      More by Rie Makiura
      Orcidhttps://orcid.org/0000-0003-2589-0698
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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2021, 13, 45, 54570–54578
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    https://doi.org/10.1021/acsami.1c16180
    Published October 27, 2021
    Copyright © 2021 American Chemical Society
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    Abstract

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    Although most metal–organic frameworks (MOFs)─highly porous crystalline metal complex networks with structural and functional varieties─are electrically insulating, high electrical conduction has been recently demonstrated in MOFs while retaining permanent porosity. Usability of electronically active MOFs effectively emerges when they are created in a thin-film state as required in major potential applications such as chemiresistive sensors, supercapacitors, and electrode catalysts. Thin-film morphology including crystallinity, thickness, density, roughness, and orientation sensitively influences device performance. Fine control of such morphological parameters still remains as a main issue to be addressed. Here, we report a bottom-up procedure of assembling a conductive MOF nanosheet composed of 2,3,6,7,10,11-hexaiminotriphenylene molecules and nickel ions (HITP-Ni-NS). Creation of HITP-Ni-NS is achieved by applying air/liquid (A/L) interfacial bottom-up synthesis. HITP-Ni-NS has a multilayered structure with 14 nm thickness and is endowed with high crystallinity and uniaxial orientation, demonstrated by synchrotron X-ray crystallography. Facile transferability of HITP-Ni-NS assembled at air/liquid interfaces to any desired substrate enables us to measure its electrical conductivity, recorded as 0.6 S cm–1─highest among those of triphenylene-based MOF nanosheets with a thickness lower than 100 nm.

    Copyright © 2021 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsami.1c16180.

    • Experimental details; BAM, AFM, SEM, and TEM images, XPS spectra, structural models, and optical microscopy image for HITP-Ni-NS; and π–A isotherm, BAM, AFM, and SEM images, UV–vis and IR absorption spectra, XPS spectra, and electrical conductivity for HATP-water-NS (PDF)

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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2021, 13, 45, 54570–54578
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsami.1c16180
    Published October 27, 2021
    Copyright © 2021 American Chemical Society
    Request reuse permissions

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