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Differences in the Interfacial Mechanical Properties of Thiophosphate and Argyrodite Solid Electrolytes and Their Composites

Cite this: ACS Appl. Mater. Interfaces 2022, 14, 39, 44292–44302
Publication Date (Web):September 21, 2022
https://doi.org/10.1021/acsami.2c10589
Copyright © 2022 American Chemical Society

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    Abstract

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    Interfacial mechanics are a significant contributor to the performance and degradation of solid-state batteries. Spatially resolved measurements of interfacial properties are extremely important to effectively model and understand the electrochemical behavior. Herein, we report the interfacial properties of thiophosphate (Li3PS4)- and argyrodite (Li6PS5Cl)-type solid electrolytes. Using atomic force microscopy, we showcase the differences in the surface morphology as well as adhesion of these materials. We also investigate solvent-less processing of hybrid electrolytes using UV-assisted curing. Physical, chemical, and structural characterizations of the materials highlight the differences in the surface morphology, chemical makeup, and distribution of the inorganic phases between the argyrodite and thiophosphate solid electrolytes.

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    • Additional SEM images, FTIR and XRD spectra, as well as additional surface morphology maps for the materials investigated (PDF)

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    Cited By

    This article is cited by 1 publications.

    1. Weiheng Chen, Xiaoping Chen, Wenhua Chen, Zhongqing Jiang. In Situ Atomic Force Microscopy and X‐ray Computed Tomography Characterization of All‐Solid‐State Lithium Batteries: Both Local and Overall. Energy Technology 2023, 169 , 2201372. https://doi.org/10.1002/ente.202201372