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Ferroelectric Hafnia-Based M3D FeTFTs Annealed at Extremely Low Temperatures and TCAM Cells for Computing-in-Memory Applications
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    Functional Inorganic Materials and Devices

    Ferroelectric Hafnia-Based M3D FeTFTs Annealed at Extremely Low Temperatures and TCAM Cells for Computing-in-Memory Applications
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    • Hongrae Joh
      Hongrae Joh
      The School of Electrical Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea
      More by Hongrae Joh
    • Sooji Nam
      Sooji Nam
      The Reality Device Research Division, Electronics and Telecommunications Research Institute, Daejeon 34129, Republic of Korea
      More by Sooji Nam
    • Minhyun Jung
      Minhyun Jung
      The School of Electrical Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea
      More by Minhyun Jung
    • Hunbeom Shin
      Hunbeom Shin
      The School of Electrical Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea
      More by Hunbeom Shin
    • Sung Haeng Cho
      Sung Haeng Cho
      The Reality Device Research Division, Electronics and Telecommunications Research Institute, Daejeon 34129, Republic of Korea
    • Sanghun Jeon*
      Sanghun Jeon
      The School of Electrical Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea
      *Email: [email protected]
      More by Sanghun Jeon
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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2023, 15, 44, 51339–51349
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    https://doi.org/10.1021/acsami.3c10597
    Published October 24, 2023
    Copyright © 2023 American Chemical Society

    Abstract

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    In order to overcome the bottleneck between the central processor unit and memory as well as the issue of energy consumption, computing-in-memory (CIM) is becoming more popular as an alternative to the traditional von Neumann structure. However, as artificial intelligence advances, the networks require CIM devices to store billions of parameters in order to handle huge data traffic demands. Monolithic three-dimensional (M3D) stacked ferroelectric thin-film transistors (FeTFTs) are one of the promising techniques for realizing high-density CIM devices that can store billions of parameters. In particular, oxide channel-based FeTFTs are well suited for these applications due to low-temperature processes, nonvolatility, and 3D integration capability. Nevertheless, the M3D-integrated CIM devices including hafnia ferroelectric films need the high-temperature annealing process to crystallize the ferroelectric layer, making M3D integration difficult. When the FeTFTs are fabricated with an M3D structure, the high-temperature process causes thermal issues in the underlying devices. Here, we present the focused microwave annealed (FMA) oxide FeTFTs with M3D integration at a low temperature of 250 °C. We confirmed that the FeTFTs with metal–ferroelectric-metal–insulator–semiconductor structure exhibited a large memory window of 3.2 V, good endurance over 106 cycles, and a long retention time of 105 s. To understand the different electrical characteristics of FeTFTs in the top and bottom layers, we experimentally analyzed the density of the state of the oxide channel and ferroelectric properties of the ferroelectric gate insulator by using multifrequency capacitance–voltage measurement and nucleation-limited-switching model analysis, respectively. With our approach, we demonstrate for the first time a vertical stacked FeTFTs-based ternary-content-addressable memory (TCAM) cell for CIM application. We believe that the proposed M3D-stacked TCAM cells composed of FeTFTs can be used in high-density memory, energy-efficient memory, and CIM technology.

    Copyright © 2023 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsami.3c10597.

    • NLS model; multifrequency capacitance–voltage measurement method; relationship between hysteresis window, Vth, and MW (Figure S1); ΔP/PSW versus log tp & NLS model fitting lines and the Lorentzian distribution at different voltages of first, second, and third layers of M3D MFM capacitors (Figure S2); CV curves with various frequency from 20 kHz to 1 MHz and the normalized CV curves of first, second, and third layers of M3D TFTs (Figure S3); process flow schematics of FeTFT (Figure S4); energy-dispersive spectrometer (EDS) mapping of MFM capacitor (Figure S5); EDS mapping of oxide TFT (Figure S6); and fitting parameters for ΔP/PSW versus log tp of first-, second-, and third-layer M3D MFM capacitors with the NLS model (Table S1) (PDF)

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    Cited By

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    This article is cited by 3 publications.

    1. Minjong Lee, Dushyant M. Narayan, Jin-Hyun Kim, Dan N. Le, Soham Shirodkar, Seongbin Park, Jongmug Kang, Seungbin Lee, Youngbae Ahn, Seung Wook Ryu, Si Joon Kim, Jiyoung Kim. Hafnium Oxide-Based Ferroelectric Devices for In-Memory Computing: Resistive and Capacitive Approaches. ACS Applied Electronic Materials 2024, 6 (8) , 5391-5401. https://doi.org/10.1021/acsaelm.4c01071
    2. Heonbang Lee, Md Mobaidul Islam, Jinbaek Bae, Myeonggi Jeong, Samiran Roy, Taebin Lim, Md Hasnat Rabbi, Jin Jang. A Coplanar Crystalline InGaO Thin Film Transistor with SiO 2 Gate Insulator on ZrO 2 Ferroelectric Layer: A New Ferroelectric TFT Structure. Advanced Materials Technologies 2024, 25 https://doi.org/10.1002/admt.202401075
    3. Hongrae Joh, Sangho Lee, Jinho Ahn, Sanghun Jeon. Dual-port ferroelectric NAND flash memory for large memory window, QLC programmable and disturbance-free operations. Journal of Materials Chemistry C 2024, 12 (38) , 15435-15443. https://doi.org/10.1039/D4TC02210F

    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2023, 15, 44, 51339–51349
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsami.3c10597
    Published October 24, 2023
    Copyright © 2023 American Chemical Society

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