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Improved Thermal Dissipation in a MoS2 Field-Effect Transistor by Hybrid High-k Dielectric Layers
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    Functional Nanostructured Materials (including low-D carbon)

    Improved Thermal Dissipation in a MoS2 Field-Effect Transistor by Hybrid High-k Dielectric Layers
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    • Jian Huang
      Jian Huang
      Wuhan National High Magnetic Field Center and School of Materials Science & Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
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    • Yifan Li
      Yifan Li
      State Key Laboratory of Digital Manufacturing Equipment and Technology, School of Mechanical Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
      More by Yifan Li
    • Xiaotong Yu
      Xiaotong Yu
      State Key Laboratory of Digital Manufacturing Equipment and Technology, School of Mechanical Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
      More by Xiaotong Yu
    • Zexin Liu
      Zexin Liu
      School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
      More by Zexin Liu
    • Fanfan Wang
      Fanfan Wang
      Wuhan National High Magnetic Field Center and School of Materials Science & Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
      More by Fanfan Wang
    • Yue Yue
      Yue Yue
      School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
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    • Rong Zhang
      Rong Zhang
      Wuhan National High Magnetic Field Center and School of Materials Science & Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
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    • Ruiwen Dai
      Ruiwen Dai
      School of Physics, Huazhong University of Science and Technology, Wuhan 430074, China
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    • Kai Yang
      Kai Yang
      Wuhan National High Magnetic Field Center and School of Materials Science & Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
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    • Heng Liu
      Heng Liu
      College of Information and Control Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, China
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    • Qingyang Fan
      Qingyang Fan
      College of Information and Control Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, China
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    • Donghui Hong
      Donghui Hong
      College of Aerospace Science and Technology, National University of Defense Technology, Changsha 410073, China
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    • Qiang Chen
      Qiang Chen
      College of Aerospace Science and Technology, National University of Defense Technology, Changsha 410073, China
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    • Zhiqiang Wang
      Zhiqiang Wang
      School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
    • Yuan Gao
      Yuan Gao
      State Key Laboratory of Digital Manufacturing Equipment and Technology, School of Mechanical Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
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    • Guoqing Xin*
      Guoqing Xin
      Wuhan National High Magnetic Field Center and School of Materials Science & Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
      *Email: [email protected]
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    Other Access OptionsSupporting Information (1)

    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2024, 16, 45, 62527–62536
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    https://doi.org/10.1021/acsami.4c12143
    Published November 2, 2024
    Copyright © 2024 American Chemical Society

    Abstract

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    Transition metal dichalcogenides like MoS2 have been considered as crucial channel materials beyond silicon to continuously advance transistor scaling down owing to their two-dimensional structure and exceptional electrical properties. However, the undesirable interface morphology and vibrational phonon frequency mismatch between MoS2 and the dielectric layer induce low thermal boundary conductance, resulting in overheating issues and impeding electrical performance improvement in the MoS2 field-effect transistors. Here, we employed hybrid high-k dielectric layers of Al2O3/HfO2 to simultaneously reduce the interfacial thermal resistance and improve device electrical performance. The enhanced contact, greater vibrational phonon overlapping region, and stronger interfacial bonding force between the top Al2O3 layer and MoS2 promote the heat removal efficiency across the interface to the substrate. Under the same input power density, the temperature profile of the MoS2 transistor on the Al2O3/HfO2 has been largely reduced compared to that of the device on HfO2, with a maximum reduction of 49.5 °C. In addition, the field-effect mobility and current of MoS2 devices on the Al2O3/HfO2 high-k dielectric layers have been significantly improved, attributed to the depressed electron scattering and trap states at the interface. The design of the hybrid high-k dielectric layers provides an efficient solution to simultaneously improve the thermal and electrical performance of the two-dimensional devices.

    Copyright © 2024 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsami.4c12143.

    • Temperature calibration (Figure S1); TDTR sensitivity analysis (Figure S2); TDTR fitting analysis (Figure S3); electrical contact resistance of MoS2 (Figure S4); temperature measurements (Figure S5); TBC comparison with 2D semiconductors (Table 1); contact angles of dielectric layers (Figure S6); STEM of MoS2 (Figure S7); mobility calculation method of MoS2 FET (S7); hysteresis of MoS2 FET with logarithmic scale (Figure S8); electrical performance comparison (Table 2) (PDF)

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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2024, 16, 45, 62527–62536
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsami.4c12143
    Published November 2, 2024
    Copyright © 2024 American Chemical Society

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