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Conductive Polymer Binder-Enabled SiO–SnxCoyCz Anode for High-Energy Lithium-Ion Batteries

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Applied Energy Materials Group, Energy Storage and Distributed Resources Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States
Argonne National Laboratory, Chicago, Illinois 60439, United States
*Tel.: +1-510-486-7207. Email: [email protected] (G. Liu).
Cite this: ACS Appl. Mater. Interfaces 2016, 8, 21, 13373–13377
Publication Date (Web):May 10, 2016
https://doi.org/10.1021/acsami.6b00312
Copyright © 2016 American Chemical Society

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    Abstract

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    A SiOSnCoC composite anode is assembled using a conductive polymer binder for the application in next-generation high energy density lithium-ion batteries. A specific capacity of 700 mAh/g is achieved at a 1C (900 mA/g) rate. A high active material loading anode with an areal capacity of 3.5 mAh/cm2 is demonstrated by mixing SiOSnCoC with graphite. To compensate for the lithium loss in the first cycle, stabilized lithium metal powder (SLMP) is used for prelithiation; when paired with a commercial cathode, a stable full cell cycling performance with a 86% first cycle efficiency is realized. By achieving these important metrics toward a practical application, this conductive polymer binder/SiOSnCoC anode system presents great promise to enable the next generation of high-energy lithium-ion batteries.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsami.6b00312.

    • Details about Coulombic efficiency of the cell based on this conductive polymer-based high capacity anode (PDF).

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    22. Jianbin Li, Lei Wang, Fangming Liu, Wenjing Liu, Caikun Luo, Yingling Liao, Xuan Li, Meizhen Qu, Qi Wan, Gongchang Peng. In Situ Wrapping SiO with Carbon Nanotubes as Anode Material for High‐Performance Li–Ion Batteries. ChemistrySelect 2019, 4 (10) , 2918-2925. https://doi.org/10.1002/slct.201900337
    23. Fan Song, Xuelin Yang, Shouzheng Zhang, Lu-Lu Zhang, Zhaoyin Wen. High-performance phosphorus-modified SiO/C anode material for lithium ion batteries. Ceramics International 2018, 44 (15) , 18509-18515. https://doi.org/10.1016/j.ceramint.2018.07.071
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    26. Shu Huang, Jianguo Ren, Rong Liu, Min Yue, Youyuan Huang, Guohui Yuan. The progress of novel binder as a non-ignorable part to improve the performance of Si-based anodes for Li-ion batteries. International Journal of Energy Research 2018, 42 (3) , 919-935. https://doi.org/10.1002/er.3826
    27. Dahua Yao, Yu Yang, Yonghong Deng, Chaoyang Wang. Flexible polyimides through one-pot synthesis as water-soluble binders for silicon anodes in lithium ion batteries. Journal of Power Sources 2018, 379 , 26-32. https://doi.org/10.1016/j.jpowsour.2017.12.086
    28. Haijun Huang, Guangshuai Han, Jingying Xie, Quansheng Zhang. The Effect of Commercialized Binders on Silicon Oxide Anode Material for High Capacity Lithium ion Batteries. International Journal of Electrochemical Science 2016, 11 (10) , 8697-8708. https://doi.org/10.20964/2016.10.29

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