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Laponite-Based Surfaces with Holistic Self-Cleaning Functionality by Combining Antistatics and Omniphobicity

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    Research Article

    Laponite-Based Surfaces with Holistic Self-Cleaning Functionality by Combining Antistatics and Omniphobicity
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    † IK4-CIDETEC, Parque Tecnológico de San Sebastián, Paseo Miramón, 196, 20014 Donostia - San Sebastián, Spain
    ‡ CIC nanoGUNE, Tolosa Hiribidea, 76, 20018 Donostia - San Sebastián, Spain
    § Ikerbasque, Basque Foundation for Science, Maria Díaz de Haro 3, 48013 Bilbao, Spain
    *E-mail: [email protected]
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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2017, 9, 44, 39078–39085
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    https://doi.org/10.1021/acsami.7b13535
    Published October 17, 2017
    Copyright © 2017 American Chemical Society
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    Abstract

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    In the present work, perfluoroalkylated laponite nanoparticles with a high degree of functionalization (60 wt %) have been prepared and a methodology to prepare transparent, antistatic, and omniphobic laponite-based films with holistic self-cleaning properties against liquids, solids and liquid–solid mixtures has been developed. The intrinsic electrical and ionic conductivities observed in unmodified laponite coatings are combined with perfluoroalkyl-modified laponite clays. As a result, films with improved self-cleaning functionality based on dust-repellency and omniphobic liquid-repellence (sheet resistance in the range of 107 Ω/□ and contact angles of 106° (H2O) and 93° (oil)) were obtained. These unique films, being capable to repel dust and liquids, were applied to a variety of substrates (i.e., glass and plastics) and tested against solids and liquids of different nature with excellent performance. Bending tests of these holistic self-cleaning films deposited over flexible substrates showed better mechanical performance than unmodified laponite films.

    Copyright © 2017 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsami.7b13535.

    • Additional information regarding Infrared Spectra of laponite JS and perfluorinated-modified laponite JS, Thermogravimetry Analysis of laponite JS and perfluorinated-modified laponite JS, FE-SEM, Spectrophotometric data of fabricated films, measured data of surface free energy, dynamic and hysteresis contact angles is included (PDF)

    • Video file (SI Movie S1) showing the self-cleaning performance of multifunctional coatings against tinted PAO 6 oil (MPG)

    • Video file (SI Movie S2) showing the self-cleaning performance of multifunctional coatings against mineral oil-carbon black mixtures (MPG)

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    Cited By

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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2017, 9, 44, 39078–39085
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsami.7b13535
    Published October 17, 2017
    Copyright © 2017 American Chemical Society
    Request reuse permissions

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