Full-Color Tunable Fluorescent and Chemiluminescent Supramolecular Nanoparticles for Anti-counterfeiting Inks
- Minzan ZuoMinzan ZuoKey Laboratory of Mesoscopic Chemistry of MOE and Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, ChinaMore by Minzan Zuo,
- Weirui QianWeirui QianKey Laboratory of Mesoscopic Chemistry of MOE and Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, ChinaMore by Weirui Qian,
- Tinghan LiTinghan LiKey Laboratory of Mesoscopic Chemistry of MOE and Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, ChinaMore by Tinghan Li,
- Xiao-Yu Hu*Xiao-Yu Hu*E-mail: [email protected] (X.-Y.H.).Key Laboratory of Mesoscopic Chemistry of MOE and Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, ChinaApplied Chemistry Department, School of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing, 211100, ChinaMore by Xiao-Yu Hu,
- Juli Jiang*Juli Jiang*E-mail: [email protected] (J.J.).Key Laboratory of Mesoscopic Chemistry of MOE and Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, ChinaMore by Juli Jiang, and
- Leyong Wang*Leyong Wang*E-mail: [email protected] (L.W.).Key Laboratory of Mesoscopic Chemistry of MOE and Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, ChinaSchool of Petrochemical Engineering, Changzhou University, Changzhou, 213164, ChinaMore by Leyong Wang
Abstract

A drive for anti-counterfeiting technology has attracted considerable interests in developing nanomaterials with a wide range of colors and tunable optical properties in solid state. Herein, with a series of conjugated polymers and based on the host–guest driven self-assembly strategy, a color-tunable supramolecular nanoparticle-based system is reported, in which full-color as well as white fluorescence can be achieved. Moreover, this fluorescent platform exhibits reversible photoswitching between quenching and emission by noncovalently introducing a photoresponsive energy acceptor. In addition, an efficient chemiluminescence system with high intensity can also be obtained in a similar manner by introducing a H2O2-responsive energy donor. Significantly, chemiluminescence is advantageous over fluorescence since there is no need for external light irradiation. More importantly, these acceptor/donor-loaded supramolecular nanoparticles exhibit fluorescence/chemiluminescence modulation ability in both solution and solid state. Therefore, this supramolecular system can be employed as fluorescent security inks for anti-counterfeiting strategies and provide a proof-of-principle application.
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