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Revisiting Cr3+-Doped Bi2Ga4O9 Spectroscopy: Crystal Field Effect and Optical Thermometric Behavior of Near-Infrared-Emitting Singly-Activated Phosphors

Cite this: ACS Appl. Mater. Interfaces 2018, 10, 48, 41512–41524
Publication Date (Web):October 31, 2018
Copyright © 2018 American Chemical Society

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    The increasing interest in the development of ratiometric optical thermal sensors has led to a wide variety of new systems with promising properties. Among them, singly-doped ratiometric thermometers were recently demonstrated to be particularly reliable. With the aim to discuss the development of an ideal optical thermal sensor, a combined experimental and theoretical insight into the spectroscopy of the Bi2Ga4O9:Cr3+ system is reported showing the importance of an insightful analysis in a wide temperature range. Low-temperature photoluminescence analysis (from 10 K) and the temperature dependence of the lifetime investigation, together with the crystal field analysis and the modeling of the thermal quenching process, allow the estimation of key parameters such as the Debye temperature (cutoff frequency), the Huang–Rhys parameter, and the energy barrier between 2Eg and 4T2g. Additionally, by considering the reliable class of singly-doped ratiometric thermometers based on a couple of excited states obeying the Boltzmann law, the important role played by the absolute sensitivity was discussed and the great potential of Cr3+ singly-activated systems was demonstrated. The results may provide new guidelines for the design of reliable optical thermometers with outstanding and robust performances.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsami.8b15607.

    • Additional details on the CF calculation; experimental details such as XRPD patterns, PLE spectrum deconvolution analysis, and PL spectrum collected at 10 K; and supporting data summarizing the Judd–Ofelt parameters, the radiative rate ratio, and the estimated D parameters for a series of Er3+-, Nd3+-, and Cr3+-activated phosphors (PDF)

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    54. S.J. Gai, C. Zhou, L. Peng, M.H. Wu, P.X. Gao, L.J. Su, M.S. Molokeev, Z. Zhou, M. Xia. A novel Cr3+-doped stannate far red phosphor for plant lighting: structure evolution, broad-narrow spectrum tuning and application prospect. Materials Today Chemistry 2022, 26 , 101107.
    55. K. Elzbieciak-Piecka, L. Marciniak. Optical heating and luminescence thermometry combined in a Cr3+-doped YAl3(BO3)4. Scientific Reports 2022, 12 (1)
    56. Fangyi Zhao, Zhen Song, Quanlin Liu. Advances in Chromium‐Activated Phosphors for Near‐Infrared Light Sources. Laser & Photonics Reviews 2022, 16 (11)
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    58. L. Marciniak, K. Kniec, K. Elżbieciak-Piecka, K. Trejgis, J. Stefanska, M. Dramićanin. Luminescence thermometry with transition metal ions. A review. Coordination Chemistry Reviews 2022, 469 , 214671.
    59. Qingyi Lv, Xiaoxi Ma, Yujuan Dong, Ying Li, Bohuai Shao, Chuqi Wang, Shuo Yang, Chuang Wang. Ratiometric optical thermometer with high-sensitive temperature sensing based on tunable luminescence of Ce3+-Eu2+ in KSr4B3O9 phosphors. Advanced Powder Technology 2022, 33 (10) , 103769.
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    61. Shala Bi, Zutao Fan, Hyo Jin Seo. Energy transfer and temperature sensing properties of Dy3+-doped Gd10V2O20 phosphors. Materials Research Bulletin 2022, 153 , 111898.
    62. Wen Zhang, Hongda Xu, Shan Wang, Hairui Fang, Tianyi Li, Yumei Zhang, Dongfei Li, Xiangdong Meng, Changmin Hou, Long Yuan. Chromaticity coordinate vector principle for charge-transfer-type thermochromic material design: case of Fe/Cr-(co)doped α-Al 2 O 3 host. Journal of Materials Chemistry C 2022, 10 (31) , 11354-11370.
    63. Shiliang Kang, Wenlong Wang, Jianrong Qiu, Zhongmin Yang, Guoping Dong. Intense continuous‐wave laser and mode‐locked pulse operation from Yb 3+ ‐doped oxyfluoride glass–ceramic fibers. Journal of the American Ceramic Society 2022, 105 (8) , 5203-5212.
    64. Kai Sun, Xiaomeng Yin, Zhenqing Li, Hui Lin, Ruijin Hong, Dawei Zhang, Zhijun Zhang, Guanhaojie Zheng, Yuchong Ding. Far-red emitting MgAl 2 O 4 :Cr 3+ ceramic phosphors with luminescence thermal stability for plant lighting LEDs. Optical Materials Express 2022, 12 (8) , 2942.
    65. Alexey Ryadun, Mariana I. Rakhmanova, Vyacheslav A. Trifonov, Anatoly A. Pavluk. Energy transfer in Tb 3+ - Yb 3+ doubly doped CsGd(MoO 4 ) 2 single crystals for contactless thermometry, solid-state lighting and solar cells. Materials Technology 2022, 37 (9) , 1001-1007.
    66. Abbi L. Mullins, Aleksandar Ćirić, Ivana Zeković, J. A. Gareth Williams, Miroslav D. Dramićanin, Ivana Radosavljević Evans. Dual-emission luminescence thermometry using LaGaO 3 :Cr 3+ , Nd 3+ phosphors. Journal of Materials Chemistry C 2022, 10 (28) , 10396-10403.
    67. Lulu Lou, Shuang Zhao, Shuwen Yuan, Daoyun Zhu, Fugen Wu, Zhongfei Mu. Efficient broadband near-infrared emission induced by Nb 5+ substitution for Ta 5+ in GaTa 1− y Nb y O 4 :Cr 3+ phosphor. Inorganic Chemistry Frontiers 2022, 9 (14) , 3522-3531.
    68. Q. Zhang, J. X. Deng, R. D. Li, J. X. Luo, L. Kong, J. H. Meng, H. L. Gao, Q. Q. Yang, G. S. Wang, X. L. Wang, J. Y. Wang. Study on the structure and properties of gallium bismuth oxide alloy thin films prepared by sol-gel method. Journal of Sol-Gel Science and Technology 2022, 103 (1) , 280-289.
    69. Mantas Norkus, Ramūnas Skaudžius. Enhanced NIR region emission of chromium by changing the chromium concentration in yttrium aluminum garnet (YAG) host matrix. Journal of Alloys and Compounds 2022, 908 , 164601.
    70. Shuai He, Liangliang Zhang, Jingnan Zhang, Zhendong Hao, Hao Wu, Huajun Wu, Yongshi Luo, Guohui Pan, Feng Liu, Jiahua Zhang. Cr3+ and Nd3+ co-activated garnet phosphor for NIR super broadband pc-LED application. Materials Research Bulletin 2022, 151 , 111797.
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    72. W.M. Piotrowski, Z. Ristic, M.D. Dramićanin, Ł. Marciniak. Modification of the thermometric performance of the lifetime-based luminescent thermometer exploiting Ti3+ emission in SrTiO3 and CaTiO3 by doping with lanthanide ions. Journal of Alloys and Compounds 2022, 906 , 164398.
    73. Abbi L. Mullins, Aleksandar Ćirić, Zoran Ristić, J.A. Gareth Williams, Ivana Radosavljević Evans, Miroslav D. Dramićanin. Double-deconvolution method for the separation of thermalised emissions from chromium-doped lanthanum gallate and its potential in luminescence-based thermometry. Journal of Luminescence 2022, 246 , 118847.
    74. Lukasz Marciniak, Wojciech Michal Piotrowski, Marek Drozd, Vasyl Kinzhybalo, Artur Bednarkiewicz, Miroslav Dramicanin. Phase Transition‐Driven Highly Sensitive, NIR–NIR Band‐Shape Luminescent Thermometer Based on LiYO 2 :Nd 3+. Advanced Optical Materials 2022, 10 (9)
    75. Langping Dong, Jingshan Hou, Baiqi Shao, Shuang Zhao, Yongzheng Fang. Cr3+/Yb3+/Nd3+-doped Ba2LaGa11O20 broadband NIR phosphors for NIR pc-LED and c-Si solar cells. Optical Materials 2022, 127 , 112290.
    76. Shunsuke Kozuka, Jumpei Ueda, Setsuhisa Tanabe. Multimodal deep red luminescent ratiometric thermometer of LaAlO3 doped with Mn4+. Physica B: Condensed Matter 2022, 633 , 413492.
    77. Cheng Zhou, Lu Peng, Zihui Kong, Meihan Wu, Maxim S. Molokeev, Zhi Zhou, Jing Wang, Mao Xia. A high thermal stability Cr 3+ -doped gallate far red phosphor for plant lighting: structure, luminescence enhancement and application prospect. Journal of Materials Chemistry C 2022, 10 (15) , 5829-5839.
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    80. Meiling Shi, Leqi Yao, Shijie Yu, Yan Dong, Qiyue Shao. Enhancing the temperature sensitivity of Cr 3+ emissions by modification of the host's composition for fluorescence thermometry applications. Dalton Transactions 2022, 51 (2) , 587-593.
    81. Manuel Alonso‐Orts, Daniel Carrasco, José M. San Juan, María Luisa Nó, Alicia de Andrés, Emilio Nogales, Bianchi Méndez. Wide Dynamic Range Thermometer Based on Luminescent Optical Cavities in Ga 2 O 3 :Cr Nanowires. Small 2022, 18 (1)
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    85. Aleksandar Ćirić, Jovana Periša, Mina Medić, Sanja Kuzman, Zoran Ristić, Željka Antić, Miroslav D. Dramićanin. Sensitive temperature reading from intensity ratio of Cr3+ and defects’ emissions in MgTiO3:Cr3+. Ceramics International 2021, 47 (22) , 31915-31919.
    86. X. H. Chen, E. H. Song, Y. Y. Zhou, F. Q. He, J. Q. Yang, Q. Y. Zhang. Distorted octahedral site occupation-induced high-efficiency broadband near-infrared emission in LiScGe 2 O 6 :Cr 3+ phosphor. Journal of Materials Chemistry C 2021, 9 (39) , 13640-13646.
    87. K. Elzbieciak-Piecka, M. Suta, L. Marciniak. Structurally induced tuning of the relative sensitivity of LaScO3:Cr3+ luminescent thermometers by co-doping lanthanide ions. Chemical Engineering Journal 2021, 421 , 129757.
    88. Paulina Bolek, Justyna Zeler, Carlos D.S. Brites, Joanna Trojan-Piegza, Luís D. Carlos, Eugeniusz Zych. Ga-modified YAG:Pr3+ dual-mode tunable luminescence thermometers. Chemical Engineering Journal 2021, 421 , 129764.
    89. Aleksandar Ćirić, Zoran Ristić, Jovana Periša, Željka Antić, Miroslav D. Dramićanin. MgAl2O4:Cr3+ luminescence thermometry probe in the physiological temperatures range. Ceramics International 2021, 47 (19) , 27151-27156.
    90. Jovana Periša, Zoran Ristić, Vesna Đorđević, Milica Sekulić, Tatjana Dramićanin, Željka Antić, Miroslav D. Dramićanin. Multiparametric luminescence thermometry from Dy3+, Cr3+ double activated YAG. Journal of Luminescence 2021, 238 , 118306.
    91. Mohit Kumar, A.S. Rao. Influence of Tb3+ ions concentration and temperature on lithium bismuth alumino borosilicate glasses for green photonic device applications. Optical Materials 2021, 120 , 111439.
    92. Zoran Ristić, Vesna Đorđević, Mina Medić, Sanja Kuzman, Mikhail G. Brik, Željka Antić, Miroslav D. Dramićanin. Temperature dependence of the Cr3+-DOPED Mg2TiO4 near-infrared emission. Optical Materials 2021, 120 , 111468.
    93. Zhibin Yang, Zhijun Wang, Mingjie Zheng, Xuejiao Wang, Jia Cui, Yao Yao, Lingwei Cao, Mengya Zhang, Hao Suo, Panlai Li. Excitation selective thermal characteristics of Mg28Ge7.55−xGaxO32F15.04: Mn4+ and application in single/dual-mode optical thermometry. Materials Today Communications 2021, 28 , 102660.
    94. Tianyao Liu, Hao Cai, Ning Mao, Zhen Song, Quanlin Liu. Efficient near‐infrared pyroxene phosphor LiInGe 2 O 6 :Cr 3+ for NIR spectroscopy application. Journal of the American Ceramic Society 2021, 104 (9) , 4577-4584.
    95. Shenghui Zheng, Junpeng Shi, Xiaodan Wang, Xiaoyan Fu, Hongyong Fan, Hongwu Zhang. Flexible thermosensitive films based on shallow-trap persistent luminescence for high-resolution texture imaging of fingerprints even through latex gloves. Journal of Materials Chemistry C 2021, 9 (30) , 9619-9626.
    96. K. Kniec, W. Piotrowski, K. Ledwa, M. Suta, L. D. Carlos, L. Marciniak. From quencher to potent activator – Multimodal luminescence thermometry with Fe 3+ in the oxides MAl 4 O 7 (M = Ca, Sr, Ba). Journal of Materials Chemistry C 2021, 9 (19) , 6268-6276.
    97. Michele Back, Jumpei Ueda, Hiroshi Nambu, Masami Fujita, Akira Yamamoto, Hisao Yoshida, Hiromitsu Tanaka, Mikhail G. Brik, Setsuhisa Tanabe. Boltzmann Thermometry in Cr 3+ ‐Doped Ga 2 O 3 Polymorphs: The Structure Matters!. Advanced Optical Materials 2021, 9 (9)
    98. Ning Mao, Shengqiang Liu, Zhen Song, Yi Yu, Quanlin Liu. A broadband near-infrared phosphor Ca3Y2Ge3O12:Cr3+ with garnet structure. Journal of Alloys and Compounds 2021, 863 , 158699.
    99. Zoran Ristić, Vesna Đorđević, Mina Medić, Sanja Kuzman, Milica Sekulić, Željka Antić, Miroslav D Dramićanin. Triple-temperature readout in luminescence thermometry with Cr 3+ -doped Mg 2 SiO 4 operating from cryogenic to physiologically relevant temperatures. Measurement Science and Technology 2021, 32 (5) , 054004.
    100. Li Jinlei, Guo Jiaqing, Li Hao, Qu Junle, Song Jun. Simultaneous realization of persistent luminescence and CT dual-mode imaging by x-ray recharged Bi2Ga4O9:Cr nanoprobes in depth-independent tumors. Chemical Engineering Journal 2021, 406 , 126008.
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