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Ultrahigh Rate Performance of a Robust Lithium Nickel Manganese Cobalt Oxide Cathode with Preferentially Orientated Li-Diffusing Channels

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Download Hi-Res ImageDownload to MS-PowerPointCite This:ACS Appl. Mater. Interfaces 2019, 11, 44, 41178-41187
    Research Article

    Ultrahigh Rate Performance of a Robust Lithium Nickel Manganese Cobalt Oxide Cathode with Preferentially Orientated Li-Diffusing Channels
    Click to copy article linkArticle link copied!

    • Dong Ren
      Dong Ren
      Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, United States
      More by Dong Ren
    • Elliot Padgett
      Elliot Padgett
      School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14853, United States
      More by Elliot Padgett
      Orcidhttp://orcid.org/0000-0001-9034-2335
    • Yao Yang
      Yao Yang
      Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, United States
      More by Yao Yang
      Orcidhttp://orcid.org/0000-0003-0321-3792
    • Luxi Shen
      Luxi Shen
      Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, United States
      More by Luxi Shen
    • Yun Shen
      Yun Shen
      Lionano, Inc., 19 Presidential Way, Suite 103, Woburn, Massachusetts 01801, United States
      More by Yun Shen
    • Barnaby D. A. Levin
      Barnaby D. A. Levin
      School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14853, United States
      More by Barnaby D. A. Levin
    • Yingchao Yu
      Yingchao Yu
      Lionano, Inc., 19 Presidential Way, Suite 103, Woburn, Massachusetts 01801, United States
      More by Yingchao Yu
    • Francis J. DiSalvo
      Francis J. DiSalvo
      Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, United States
      More by Francis J. DiSalvo
    • David A. Muller
      David A. Muller
      School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14853, United States
      More by David A. Muller
      Orcidhttp://orcid.org/0000-0003-4129-0473
    • Héctor D. Abruña*
      Héctor D. Abruña
      Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, United States
      *E-mail: [email protected]
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      Orcidhttp://orcid.org/0000-0002-3948-356X
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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2019, 11, 44, 41178–41187
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsami.9b05602
    Published October 10, 2019
    Copyright © 2019 American Chemical Society
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    Abstract

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    Lithium nickel manganese cobalt oxide (NMC) materials, with low cost and high energy density, are considered to be among the most promising cathode materials for Li-ion batteries (LIBs). However, several issues have hindered their further deployment, particularly for high-powered applications, including limited rate capability, capacity loss during cycling (especially at high temperatures and high voltages), and difficulty in reproducibly preparing the desired particle morphology. In this work, we have developed a robust LiNi0.33Mn0.33Co0.33O2 cathode material (NMC-111) capable of high-rate performance for LIBs. Our high power NMC-111 (HP-NMC) cathode materials showed significantly enhanced electrochemical performance, relative to a commercial NMC-111 (c-NMC), with discharge capacities of 138 and 131 mAh/g at high current rates of 20 and 30 C, respectively. The material also exhibited enhanced cycling stability under both room temperature and at 50 °C. We ascribe the high performance of our material to a unique crystalline microstructure observed by electron microscopy characterization, which showed preferential orientation of the Li-diffusing channels radially outward. This HP-NMC material achieved one of the highest performance metrics among NMC materials reported to date, especially for high-powered electric vehicles.

    Copyright © 2019 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsami.9b05602.

    • Experimental methods, Figures S1–S3, and Tables S1–S5 (PDF)

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    Cited By

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    This article is cited by 21 publications.

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    2. Tianyang Chen, Harish Banda, Jiande Wang, Julius J. Oppenheim, Alessandro Franceschi, Mircea Dincǎ. A Layered Organic Cathode for High-Energy, Fast-Charging, and Long-Lasting Li-Ion Batteries. ACS Central Science 2024, 10 (3) , 569-578. https://doi.org/10.1021/acscentsci.3c01478
    3. Isaac Martens, Victor Vanpeene, Nikita Vostrov, Steven Leake, Edoardo Zatterin, Jeremie Auvergniot, Jakub Drnec, Marie-Ingrid Richard, Julie Villanova, Tobias Schulli. Imaging Voids and Defects Inside Li-Ion Cathode LiNi0.6Mn0.2Co0.2O2 Single Crystals. ACS Applied Materials & Interfaces 2023, 15 (51) , 59319-59328. https://doi.org/10.1021/acsami.3c10509
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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2019, 11, 44, 41178–41187
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsami.9b05602
    Published October 10, 2019
    Copyright © 2019 American Chemical Society
    Request reuse permissions

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