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Selective Electro-Oxidation of Glycerol to Dihydroxyacetone by PtAg Skeletons

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    Research Article

    Selective Electro-Oxidation of Glycerol to Dihydroxyacetone by PtAg Skeletons
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    • Yongfang Zhou
      Yongfang Zhou
      School of Food Science and Engineering, South China University of Technology, Guangzhou 510640, China
      More by Yongfang Zhou
    • Yi Shen*
      Yi Shen
      School of Food Science and Engineering, South China University of Technology, Guangzhou 510640, China
      Overseas Expertise Introduction Center for Discipline Innovation of Food Nutrition and Human Health (111 Center), Guangzhou 510640, China
      *E-mail: [email protected]
      More by Yi Shen
      Orcidhttp://orcid.org/0000-0003-1923-7588
    • Jingyu Xi
      Jingyu Xi
      Institute of Green Chemistry and Energy, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055, China
      More by Jingyu Xi
      Orcidhttp://orcid.org/0000-0002-7618-8500
    • Xuanli Luo
      Xuanli Luo
      Advanced Materials Research Group, Faculty of Engineering, University of Nottingham, Nottingham NG7 2RD, U.K.
      More by Xuanli Luo
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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2019, 11, 32, 28953–28959
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    https://doi.org/10.1021/acsami.9b09431
    Published July 18, 2019
    Copyright © 2019 American Chemical Society
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    Abstract

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    Developing high-performance electrocatalysts for the selective conversion of glycerol into value-added chemicals is of great significance. Herein, three-dimensional nanoporous PtAg skeletons were studied as catalysts for the electro-oxidation of glycerol. The structural features of the PtAg skeletons were revealed by electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and UV–vis spectroscopy. The electrochemical activity of the catalysts was examined by cyclic voltammetry, linear sweeping voltammetry, and chronoamperometry. The resulting PtAg skeletons exhibit a peak current density of 7.57 mA cm–2, which is 15.4-fold higher than that of Pt/C, making the PtAg skeletons one of the best electrocatalysts for glycerol oxidation. High-performance liquid chromatography results show that the PtAg skeletons yield a remarkable dihydroxyacetone selectivity of 82.6%, which has so far been the second largest value reported in the literature. The superior activity and selectivity of the PtAg skeletons are ascribed to the large surface area and abundant Pt(111) facets. Additionally, the effects of glycerol and KOH concentrations and reaction time on product selectivity were investigated.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsami.9b09431.

    • TEM images of Ag seeds and the Pt/C catalyst, i–t curves, representative HPLC curves, and product distribution of the catalysts (PDF)

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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2019, 11, 32, 28953–28959
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsami.9b09431
    Published July 18, 2019
    Copyright © 2019 American Chemical Society
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