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Reversible Insertion in AFeF3 (A = K+, NH4+) Cubic Iron Fluoride Perovskites

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    Research Article

    Reversible Insertion in AFeF3 (A = K+, NH4+) Cubic Iron Fluoride Perovskites
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    • Andréa Martin
      Andréa Martin
      Institut für Chemie and IRIS Adlershof, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, D-12489 Berlin, Germany
      More by Andréa Martin
    • Enrique S. Santiago
      Enrique S. Santiago
      Institut für Chemie and IRIS Adlershof, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, D-12489 Berlin, Germany
      More by Enrique S. Santiago
    • Erhard Kemnitz
      Erhard Kemnitz
      Institut für Chemie and IRIS Adlershof, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, D-12489 Berlin, Germany
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      Orcidhttp://orcid.org/0000-0002-5300-3905
    • Nicola Pinna*
      Nicola Pinna
      Institut für Chemie and IRIS Adlershof, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, D-12489 Berlin, Germany
      *E-mail: [email protected]
      More by Nicola Pinna
      Orcidhttp://orcid.org/0000-0003-1273-803X
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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2019, 11, 36, 33132–33139
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    https://doi.org/10.1021/acsami.9b10659
    Published August 20, 2019
    Copyright © 2019 American Chemical Society
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    Abstract

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    The search for new cathode materials is primordial for alkali-ion battery systems, which are facing a constantly growing demand for high energy density storage devices. In quest of more performing active compounds on the positive side, anhydrous iron(III) fluoride demonstrated to be a good compromise in terms of high capacity, operating voltage, and low cost. However, its reaction toward lithium leads to complicated insertion/conversion reactions, which hinder its performances in Li-ion cells. Cycling this material against larger ions such as sodium and potassium is hard or simply impossible due to the size of the channels of the FeF3 framework impeding ions diffusion. Herein, we propose a strategy based on the use of cubic perovskite AFeF3 (A = K+, NH4+) as starting materials, allowing the straightforward insertion (after a first disinsertion of the alkali and/or NH4+ ion) of lithium within the structure and enabling the cycling toward larger alkali ions such as sodium and potassium. For example, a cubic KFeF3 perovskite, produced by a facile synthesis method, shows superior rate capability toward lithium retaining a capacity of up to 132 mA·h·g–1 at 5 C or of 120 mA·h·g–1 at 5 C toward sodium and enabling cycling toward potassium. Moreover, cubic NH4FeF3 perovskite is discussed for the first time as the suitable cathode material for alkali-ion batteries.

    Copyright © 2019 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsami.9b10659.

    • Diffraction patterns of the different Pnma and Pm3̅m phases, TEM images of KFeF3 after ball-milling process with carbon black, capacity retentions and galvanostatic plots of the first discharge depending on the used cutoff potential, capacity retentions and galvanostat plots of KFeF3 cycled toward lithium at high C-rates, capacity retentions, and galvanostatic plots of the different metal fluoride phases cycled toward potassium, ex situ diffraction patterns of KFeF3 cycled toward sodium at different states of charge/discharge of the second cycle and corresponding typical plots, and ex situ diffraction patterns of the KFeF3 cycled toward potassium at different states of charge/discharge of the first and corresponding typical plots (PDF)

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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2019, 11, 36, 33132–33139
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsami.9b10659
    Published August 20, 2019
    Copyright © 2019 American Chemical Society
    Request reuse permissions

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