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Ultralow-Noise Organic Transistors Based on Polymeric Gate Dielectrics with Self-Assembled Modifiers

  • Masaya Kondo
    Masaya Kondo
    The Institute of Scientific and Industrial Research, Osaka University, 8-1, Mihogaoka, Ibaraki, Osaka 567-0047, Japan
    Graduate School of Engineering, Osaka University, 2-1, Yamada-oka, Suita, Osaka 565-0871, Japan
    Advanced Photonics and Biosensing Open Innovation Laboratory, National Institute of Advanced Industrial Science and Technology, Photonics Center P3 Bldg. 2-1, Yamadaoka, Suita, Osaka 565-0871, Japan
    More by Masaya Kondo
  • Takafumi Uemura*
    Takafumi Uemura
    The Institute of Scientific and Industrial Research, Osaka University, 8-1, Mihogaoka, Ibaraki, Osaka 567-0047, Japan
    Advanced Photonics and Biosensing Open Innovation Laboratory, National Institute of Advanced Industrial Science and Technology, Photonics Center P3 Bldg. 2-1, Yamadaoka, Suita, Osaka 565-0871, Japan
    *E-mail: [email protected] (T.U.).
  • Fumitaka Ishiwari
    Fumitaka Ishiwari
    Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
  • Takashi Kajitani
    Takashi Kajitani
    Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
  • Yoshiaki Shoji
    Yoshiaki Shoji
    Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
  • Masato Morita
    Masato Morita
    Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
  • Naoko Namba
    Naoko Namba
    Advanced Photonics and Biosensing Open Innovation Laboratory, National Institute of Advanced Industrial Science and Technology, Photonics Center P3 Bldg. 2-1, Yamadaoka, Suita, Osaka 565-0871, Japan
    More by Naoko Namba
  • Yumi Inoue
    Yumi Inoue
    The Institute of Scientific and Industrial Research, Osaka University, 8-1, Mihogaoka, Ibaraki, Osaka 567-0047, Japan
    More by Yumi Inoue
  • Yuki Noda
    Yuki Noda
    The Institute of Scientific and Industrial Research, Osaka University, 8-1, Mihogaoka, Ibaraki, Osaka 567-0047, Japan
    More by Yuki Noda
  • Teppei Araki
    Teppei Araki
    The Institute of Scientific and Industrial Research, Osaka University, 8-1, Mihogaoka, Ibaraki, Osaka 567-0047, Japan
    Graduate School of Engineering, Osaka University, 2-1, Yamada-oka, Suita, Osaka 565-0871, Japan
    Advanced Photonics and Biosensing Open Innovation Laboratory, National Institute of Advanced Industrial Science and Technology, Photonics Center P3 Bldg. 2-1, Yamadaoka, Suita, Osaka 565-0871, Japan
    More by Teppei Araki
  • Takanori Fukushima*
    Takanori Fukushima
    Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
    *E-mail: [email protected] (T.F.).
  • , and 
  • Tsuyoshi Sekitani*
    Tsuyoshi Sekitani
    The Institute of Scientific and Industrial Research, Osaka University, 8-1, Mihogaoka, Ibaraki, Osaka 567-0047, Japan
    Graduate School of Engineering, Osaka University, 2-1, Yamada-oka, Suita, Osaka 565-0871, Japan
    Advanced Photonics and Biosensing Open Innovation Laboratory, National Institute of Advanced Industrial Science and Technology, Photonics Center P3 Bldg. 2-1, Yamadaoka, Suita, Osaka 565-0871, Japan
    *E-mail: [email protected] (T.S.).
Cite this: ACS Appl. Mater. Interfaces 2019, 11, 44, 41561–41569
Publication Date (Web):October 9, 2019
https://doi.org/10.1021/acsami.9b13056
Copyright © 2019 American Chemical Society

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    Supporting Info (1)»

    Abstract

    Abstract Image

    In this study, ultralow 1/f noise organic thin-film transistors (OTFTs) based on parylene gate dielectrics modified with triptycene (Trip) modifiers were fabricated. The fabricated OTFTs showed the lowest 1/f noise level among those of previously reported OTFTs. It is well known that 1/f noise causes degradation of signal integrity in analog and digital circuits. However, conventional OTFTs still possess high 1/f noise levels, and the factors that strongly affect 1/f noise are still ambiguous. In this work, the effect of gate dielectric surface on 1/f noise was investigated. First, by comparing OTFTs composed of various channel lengths, we revealed that contact resistance did not affect 1/f noise. Second, we compared parylene OTFTs with and without a self-assembled Trip modifier layer in terms of 1/f noise and trap density of states (Trap DOS). The experiments revealed that a specific Trip modifier layer suppresses the shallow Trap DOS in the OTFTs, leading to a low 1/f noise. Moreover, the 1/f noise level and Trap DOS of various kinds of OTFTs were comprehensively compared, which highlighted that the 1/f noise of OTFTs strongly depends on the gate dielectric surface. Finally, detailed analysis of the gate dielectric interface led us to conclude that the disorder of gate dielectrics and the crystalline quality of semiconductor films are related to shallow Trap DOS, which correlates with 1/f noise.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsami.9b13056.

    • XRD measurements for characterization of TripOMeF, contact angle and surface energy measurements, mobility characterization, azimuthal-angle dependency of the diffraction peak intensity, contact-resistance characterization, normalized 1/f noise levels, gate-voltage-dependence of 1/f noise, normalized 1/f noise levels with a parameter of |ID| and |gm/ID|2, temperature-dependent characteristics, comprehensive Trap DOS comparison (PDF)

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    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 7 publications.

    1. Wei Huang, Xinge Yu, Li Zeng, Binghao Wang, Atsuro Takai, Gabriele Di Carlo, Michael J. Bedzyk, Tobin J. Marks, Antonio Facchetti. Ultraviolet Light-Densified Oxide-Organic Self-Assembled Dielectrics: Processing Thin-Film Transistors at Room Temperature. ACS Applied Materials & Interfaces 2021, 13 (2) , 3445-3453. https://doi.org/10.1021/acsami.0c20345
    2. G. Giusi, M. Rapisarda, M. Scagliotti, L. Mariucci, G. Scandurra, C. Ciofi. Low Frequency Noise in DNTT/Cytop™ Based Organic Thin Film Transistors. IEEE Electron Device Letters 2023, 44 (10) , 1720-1723. https://doi.org/10.1109/LED.2023.3307591
    3. Esther Karner‐Petritz, Andreas Petritz, Takafumi Uemura, Naoko Namba, Teppei Araki, Tsuyoshi Sekitani, Barbara Stadlober. Ultraflexible Organic Active Matrix Sensor Sheet for Tactile and Biosignal Monitoring. Advanced Electronic Materials 2023, 9 (9) https://doi.org/10.1002/aelm.202201333
    4. Tomoharu Kimura, Takafumi Uemura, Yayoi Shibafuji, Takeshi Suyama, Hiroyuki Ueno, Tsuyoshi Sekitani. Biosignal Amplifiers Based on Low‐Noise Organic Transistors with Printed Electrodes. Advanced Electronic Materials 2023, 9 (9) https://doi.org/10.1002/aelm.202201279
    5. Tsuyoshi Sekitani. 57‐4: Invited Paper: Imperceptible Electronics for Digital Transformation. SID Symposium Digest of Technical Papers 2021, 52 (1) , 810-813. https://doi.org/10.1002/sdtp.14807
    6. Takafumi UEMURA, Masaya KONDO, Masahiro SUGIYAMA, Naoko NAMBA, Yumi INOUE, Mihoko AKIYAMA, Shusuke YOSHIMOTO, Yuki NODA, Teppei ARAKI, Tsuyoshi SEKITANI. Development of a Sheet-type Magnetic Sensor System Using Flexible Organic Thin-film Transistors. Vacuum and Surface Science 2021, 64 (1) , 22-27. https://doi.org/10.1380/vss.64.22
    7. Teppei Araki, Lukas M Bongartz, Taro Kaiju, Ashuya Takemoto, Shuichi Tsuruta, Takafumi Uemura, Tsuyoshi Sekitani. Flexible neural interfaces for brain implants—the pursuit of thinness and high density. Flexible and Printed Electronics 2020, 5 (4) , 043002. https://doi.org/10.1088/2058-8585/abc3ca

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