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Hierarchical Bimetallic Ni–Co–P Microflowers with Ultrathin Nanosheet Arrays for Efficient Hydrogen Evolution Reaction over All pH Values

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    Research Article

    Hierarchical Bimetallic Ni–Co–P Microflowers with Ultrathin Nanosheet Arrays for Efficient Hydrogen Evolution Reaction over All pH Values
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    • Xupo Liu
      Xupo Liu
      Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, People’s Republic of China
      More by Xupo Liu
    • Shaofeng Deng
      Shaofeng Deng
      Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, People’s Republic of China
      More by Shaofeng Deng
    • Dongdong Xiao
      Dongdong Xiao
      Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, People’s Republic of China
      More by Dongdong Xiao
    • Mingxing Gong
      Mingxing Gong
      Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, People’s Republic of China
      More by Mingxing Gong
    • Jianing Liang
      Jianing Liang
      Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, People’s Republic of China
      More by Jianing Liang
    • Tonghui Zhao
      Tonghui Zhao
      Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, People’s Republic of China
      More by Tonghui Zhao
    • Tao Shen
      Tao Shen
      Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, People’s Republic of China
      More by Tao Shen
    • Deli Wang*
      Deli Wang
      Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, People’s Republic of China
      *E-mail: [email protected]
      More by Deli Wang
      Orcidhttp://orcid.org/0000-0003-2023-6478
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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2019, 11, 45, 42233–42242
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    https://doi.org/10.1021/acsami.9b15194
    Published October 28, 2019
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    Abstract

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    Designing efficient nonprecious catalysts with pH-universal hydrogen evolution reaction (HER) performance is of importance for boosting water splitting. Herein, a self-template strategy based on Ni–Co–glycerates is developed to prepare bimetallic Ni–Co–P microflowers with ultrathin nanosheet arrays. The highly porous core–shell structure gives rise to affluent mass transfer channels and availably prevents the aggregation of nanosheets, while the ultrathin nanosheets are favorable for producing abundant active sites. Besides, the produced CoP/NiCoP heterostructure in the bimetallic Ni–Co–P catalyst has excellent HER performance in a wide pH range. The as-prepared catalyst shows low potentials of 90, 157, and 121 mV to deliver a current density of 10 mA cm–2 in 0.5 M H2SO4, 0.5 M PBS, and 1 M KOH solution, respectively. Meanwhile, negligible overpotential decay is achieved in the polarization curves after a long-term stability determination. This work supplies a promising strategy for developing pH-universal HER electrocatalysts based on solid-state metal alkoxides.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsami.9b15194.

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    Cite this: ACS Appl. Mater. Interfaces 2019, 11, 45, 42233–42242
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