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Bimodal Mesoporous CMK-5 Carbon: Selective Pore Filling with Sulfur and SnO2 for Lithium Battery Electrodes

  • Christian Weinberger
    Christian Weinberger
    Department of Chemistry, University of Paderborn, Warburger Str. 100, D-33098 Paderborn, Germany
  • Sai Ren
    Sai Ren
    Department of Chemistry, University of Paderborn, Warburger Str. 100, D-33098 Paderborn, Germany
    More by Sai Ren
  • Marc Hartmann
    Marc Hartmann
    Department of Chemistry, University of Paderborn, Warburger Str. 100, D-33098 Paderborn, Germany
  • Thorsten Wagner
    Thorsten Wagner
    Department of Chemistry, University of Paderborn, Warburger Str. 100, D-33098 Paderborn, Germany
  • Didem. Ş. Karaman
    Didem. Ş. Karaman
    Pharmaceutical Sciences Laboratory, Faculty of Science and Engineering, Åbo Akademi University, 20520 Turku, Finland
  • Jessica M. Rosenholm
    Jessica M. Rosenholm
    Pharmaceutical Sciences Laboratory, Faculty of Science and Engineering, Åbo Akademi University, 20520 Turku, Finland
  • , and 
  • Michael Tiemann*
    Michael Tiemann
    Department of Chemistry, University of Paderborn, Warburger Str. 100, D-33098 Paderborn, Germany
    *E-mail: [email protected]
Cite this: ACS Appl. Nano Mater. 2018, 1, 1, 455–462
Publication Date (Web):December 19, 2017
https://doi.org/10.1021/acsanm.7b00307
Copyright © 2017 American Chemical Society

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    Abstract

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    Ordered mesoporous CMK-5 carbon exhibits two distinct pore systems that can be modified individually. This work demonstrates how one of the pore systems can be selectively filled with elemental sulfur, while the other pore system remains empty. The resulting sulfur–carbon composite material with high residual porosity can be used as the cathode material in lithium–sulfur battery cells. We present a systematic investigation of the loading of CMK-5 carbon with variable relative amounts of sulfur and compare the results to the preparation of SnO2 (as well as TiO2, Mn2O3/Mn3O4, NiO) nanoparticle-loaded CMK-5 carbon.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsanm.7b00307.

    • Explanation of the determination of SnO2 and sulfur content, EDX analysis, thermogravimetric analysis, wide-angle X-ray diffraction measurements, measurement of the Coulombic efficiency and specific capacity, charge–discharge profiles, and porosity data (PDF)

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