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Aqueous Gold Nanoparticle Solutions for Improved Efficiency in Electrogenerated Chemiluminescent Reactions
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    Aqueous Gold Nanoparticle Solutions for Improved Efficiency in Electrogenerated Chemiluminescent Reactions
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    • Pilar Perez-Tejeda*
      Pilar Perez-Tejeda
      Department of Physical Chemistry, Faculty of Chemistry, University of Seville, 41012 Sevilla, Spain
      *(P.P.-T.) E-mail [email protected]; Tel +34954557175; Fax +34954557174.
    • Elia Grueso
      Elia Grueso
      Department of Physical Chemistry, Faculty of Chemistry, University of Seville, 41012 Sevilla, Spain
      More by Elia Grueso
    • Ana Marin-Gordillo
      Ana Marin-Gordillo
      Department of Physical Chemistry, Faculty of Chemistry, University of Seville, 41012 Sevilla, Spain
    • Concepcion Torres-Marquez
      Concepcion Torres-Marquez
      Department of Physical Chemistry, Faculty of Chemistry, University of Seville, 41012 Sevilla, Spain
    • Rosa M. Giráldez-Pérez
      Rosa M. Giráldez-Pérez
      Department of Physical Chemistry, Faculty of Chemistry, University of Seville, 41012 Sevilla, Spain
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    ACS Applied Nano Materials

    Cite this: ACS Appl. Nano Mater. 2018, 1, 9, 5307–5315
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    https://doi.org/10.1021/acsanm.8b01323
    Published August 21, 2018
    Copyright © 2018 American Chemical Society

    Abstract

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    The efficiency of the high-energy electrogenerated chemiluminescence (ECL) tris(2,2′-bipyridine)ruthenium(II)/oxalate reaction was determined in the presence of citrate-coated gold nanoparticle (AuNPs) aqueous solutions. The ECL efficiency (ΦECL) for this reaction is enhanced by the addition of increasing amounts of AuNPs, followed by a sharp decrease when [AuNPs] is higher than 1.6 × 10–8 M. To explain this ΦECL/[AuNPs] trend, photoluminescent (PL) quenching, transmission electronic microscopy (TEM), and energy dispersive X-ray spectroscopy (EDS) measurements were also performed as well as redox potentials for the [Ru(bpy)3]3+/2+ couple. Two facts were noteworthy: First, there is an increase in ΦECL, which accompanies an energy transfer effect by coupling between the Ru(II) complex ECL emission band and the AuNPs surface plasmon resonance (SPR)-induced band. This coupling, which we have called the ECL-SPR effect, enabled the quantifying of a coefficient (KECL-SPR, ECL-SPR effectiveness) for the improved ΦECL of the tris(2,2′-bipyridine)ruthenium(II)/oxalate reaction, which turned out to be about 3.5 times higher than the quenching constant for the [Ru(bpy)3]2+/Au@citrate system. This ECL-SPR effectiveness is the basis for applying the ECL-SPR coupling effect in a given reaction. Specifically, it measures the degree to which an ECL reaction has been improved. Second, a metal nanostructure is generated in the solution due to a sufficiently strong electrostatic binding between the Ru(II) complex and the AuNPs, which is revealed through TEM and EDS measurements and the redox potential trend.

    Copyright © 2018 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsanm.8b01323.

    • Figures S1–S8 and Table S1 (PDF)

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    This article is cited by 10 publications.

    1. Ibtihaj Albalawi, Anna Hogan, Hanan Alatawi, Samia Alsefri, Eric Moore. A novel comparative study for simultaneous determination of Cd (II) and Pb (II) based on ruthenium complex-nanoparticles-nafion modified screen-printed gold electrode. Sensors and Actuators B: Chemical 2023, 380 , 133273. https://doi.org/10.1016/j.snb.2022.133273
    2. Cheng Ma, Zhichen Zhang, Tingting Tan, Jun-Jie Zhu. Recent Progress in Plasmonic based Electrochemiluminescence Biosensors: A Review. Biosensors 2023, 13 (2) , 200. https://doi.org/10.3390/bios13020200
    3. Yitian Huang, Dandan Zhao, Yanjie Chen, Shupei Zhang, Feng Lin, Hong Dai. Ratiometric electrochemiluminescence biosensor for hepatitis C virus E2 protein based on block copolymers-solubilized Ir(ppy)3 with high electrochemiluminescence efficiency. Electrochimica Acta 2022, 429 , 141028. https://doi.org/10.1016/j.electacta.2022.141028
    4. Ibtihaj Albalawi, Anna Hogan, Hanan Alatawi, Samia Alsefri, Eric Moore. A Novel Comparative Study for Simultaneous Determination of CD (II) and Pb (II) Based on Ruthenium Complex-Nanoparticles-Nafion Modified Screen-Printed Gold Electrode. SSRN Electronic Journal 2022, 9 https://doi.org/10.2139/ssrn.4192547
    5. Cuizhong Zhang, Liya Zhou, Jinyun Peng. Blue-light photoelectrochemical aptasensor for kanamycin based on synergistic strategy by Schottky junction and sensitization. Sensors and Actuators B: Chemical 2021, 340 , 129898. https://doi.org/10.1016/j.snb.2021.129898
    6. Yuanjie Sun, Liang Tao, Ying Ma, Shuya Yang, Xiyang Zhang, Boquan Jin, Zhujun Zhang, Kun Yang. Development of an Approach of High Sensitive Chemiluminescent Assay for Cystatin C Using a Nanoparticle Carrier. Frontiers in Chemistry 2020, 8 https://doi.org/10.3389/fchem.2020.00802
    7. Pilar Perez-Tejeda, Alberto Martínez-Delgado, Elia Grueso, Rosa M. Giráldez-Pérez. Measuring nanoparticle-induced resonance energy transfer effect by electrogenerated chemiluminescent reactions. RSC Advances 2020, 10 (7) , 3861-3871. https://doi.org/10.1039/C9RA08857A
    8. Andrew Danis, Janine Mauzeroll. Electrogenerated chemiluminescence (ECL). 2020, 285-314. https://doi.org/10.1016/B978-0-12-821203-5.00005-1
    9. Thomas S. Heiderscheit, Miranda J. Gallagher, Rashad Baiyasi, Sean S. E. Collins, Seyyed Ali Hosseini Jebeli, Leonardo Scarabelli, Alexander Al-Zubeidi, Charlotte Flatebo, Wei-Shun Chang, Christy F. Landes, Stephan Link. Nanoelectrode-emitter spectral overlap amplifies surface enhanced electrogenerated chemiluminescence. The Journal of Chemical Physics 2019, 151 (14) https://doi.org/10.1063/1.5118669
    10. Narsingh R. Nirala, Nofar Pinker, Chaitanyakumar Desitti, Giorgi Shtenberg. Milk haptoglobin detection based on enhanced chemiluminescence of gold nanoparticles. Talanta 2019, 197 , 257-263. https://doi.org/10.1016/j.talanta.2019.01.027

    ACS Applied Nano Materials

    Cite this: ACS Appl. Nano Mater. 2018, 1, 9, 5307–5315
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsanm.8b01323
    Published August 21, 2018
    Copyright © 2018 American Chemical Society

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