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Tuning the Reflection Bandwidth of Polarization Volume Gratings by Guest Material Penetration
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    Tuning the Reflection Bandwidth of Polarization Volume Gratings by Guest Material Penetration
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    ACS Applied Optical Materials

    Cite this: ACS Appl. Opt. Mater. 2024, 2, 7, 1314–1320
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    https://doi.org/10.1021/acsaom.3c00117
    Published May 27, 2023
    Copyright © 2023 American Chemical Society

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    Polarization volume gratings (PVGs) based on polymerized cholesteric liquid crystal (CLC) films can potentially be applied as optical combiners in augmented reality (AR) smart glasses. The reflection bandwidth of PVGs is determined by the helical pitch and birefringence of the CLC, which must be tuned to match the desired color for reflection, but tuning the material properties is challenging as the materials must also be polymerizable. Here, we report a postprocessing method based on guest material penetration for the tuning of the reflection bandwidth of CLC polymer films. Solution coating of a high-birefringence guest liquid crystal on a CLC film modifies the birefringence as well as elongates the helical pitch. Penetration of a high-birefringence 5CT liquid crystal was found to cause a birefringence increase of the CLC film by approximately 18%.

    Copyright © 2023 American Chemical Society

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    This article is cited by 2 publications.

    1. Yoshimichi Shimomura, Yuuto Iida, Eiji Tsurumaki, Gen-ichi Konishi. Innovative molecular design of bridged biphenyls for calamitic nematic liquid crystals with extensive π-conjugated mesogens. Materials Chemistry Frontiers 2025, 9 (7) , 1127-1138. https://doi.org/10.1039/D4QM01116C
    2. Frederik Van Acker, Bo-Han Lin, Chun-Ta Wang, Kristiaan Neyts, Jeroen Beeckman. Defect Modes Generated in a Stack of Spin-Coated Chiral Liquid Crystal Layers. Crystals 2024, 14 (3) , 231. https://doi.org/10.3390/cryst14030231

    ACS Applied Optical Materials

    Cite this: ACS Appl. Opt. Mater. 2024, 2, 7, 1314–1320
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsaom.3c00117
    Published May 27, 2023
    Copyright © 2023 American Chemical Society

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