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Time Dependence of Fluoride Uptake in Hydroxyapatite
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    Time Dependence of Fluoride Uptake in Hydroxyapatite
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    Experimental Physics, Faculty of Natural Sciences and Technology, Saarland University, 66123 Saarbrücken, Germany
    Functional Materials, Faculty of Natural Sciences and Technology, Saarland University, 66123 Saarbrücken, Germany
    § Clinic of Operative Dentistry, Periodontology and Preventive Dentistry, Faculty of Medicine-Clinical Medicine, Saarland University Hospital, 66421 Homburg, Germany
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    ACS Biomaterials Science & Engineering

    Cite this: ACS Biomater. Sci. Eng. 2017, 3, 8, 1822–1826
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    https://doi.org/10.1021/acsbiomaterials.6b00782
    Published June 2, 2017
    Copyright © 2017 American Chemical Society

    Abstract

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    Fluoridation of enamel is believed to provide an effective tool to protect teeth from caries, but there is still little information on the time scale of fluoride uptake. In this study, highly compressed pellets of hydroxyapatite are used as first-order model systems to approximate the mineral component of natural enamel for investigations on the time-dependence of fluoride uptake. We found that both the overall amount of fluoride as well as the mean thickness of the fluoridated surface layer cannot be extended to any values just by increasing the application time of a fluoride containing agent. Instead, both parameters start to become constant on a time scale of about 3 min. The present results as obtained on a synthetic model “tooth” show that the time scale to provide the maximum amount of fluoride possible is of the same order of magnitude as that in usual daily practice in dental care when applying toothpastes or mouth rinses.

    Copyright © 2017 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsbiomaterials.6b00782.

    • XPS data of sintered HAp samples; particle size distribution of HAp powder; chemical composition of HAp powder and sintered sample; XRD analysis of HAp powder and sintered sample; and microhardness of HAp pellets compared to enamel (PDF)

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    Cited By

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    This article is cited by 14 publications.

    1. Johannes Mischo, Thomas Faidt, Ryan B. McMillan, Johanna Dudek, Gubesh Gunaratnam, Pardis Bayenat, Anne Holtsch, Christian Spengler, Frank Müller, Hendrik Hähl, Markus Bischoff, Matthias Hannig, Karin Jacobs. Hydroxyapatite Pellets as Versatile Model Surfaces for Systematic Adhesion Studies on Enamel: A Force Spectroscopy Case Study. ACS Biomaterials Science & Engineering 2022, 8 (4) , 1476-1485. https://doi.org/10.1021/acsbiomaterials.1c00925
    2. Yansong Wang, Xiao Li, Minfang Chen, Yun Zhao, Chen You, Yankun Li, Guorui Chen. In Vitro and in Vivo Degradation Behavior and Biocompatibility Evaluation of Microarc Oxidation-Fluoridated Hydroxyapatite-Coated Mg–Zn–Zr–Sr Alloy for Bone Application. ACS Biomaterials Science & Engineering 2019, 5 (6) , 2858-2876. https://doi.org/10.1021/acsbiomaterials.9b00564
    3. Thomas Faidt, Andreas Friedrichs, Samuel Grandthyll, Christian Spengler, Karin Jacobs, Frank Müller. Effect of Fluoride Treatment on the Acid Resistance of Hydroxyapatite. Langmuir 2018, 34 (50) , 15253-15258. https://doi.org/10.1021/acs.langmuir.8b03412
    4. Satoshi Hayakawa, Yu Okada, Tomohiko Yoshioka. Comparative study of the effects of fluoride treatment with cyclic variations in pH on the structures of stoichiometric, calcium-deficient, and carbonated hydroxyapatites. Journal of the Ceramic Society of Japan 2025, https://doi.org/10.2109/jcersj2.24094
    5. Joachim Enax, Pascal Fandrich, Erik Schulze zur Wiesche, Matthias Epple. The Remineralization of Enamel from Saliva: A Chemical Perspective. Dentistry Journal 2024, 12 (11) , 339. https://doi.org/10.3390/dj12110339
    6. Christine Müller-Renno, Christiane Ziegler. The Contribution of Scanning Force Microscopy on Dental Research: A Narrative Review. Materials 2024, 17 (9) , 2100. https://doi.org/10.3390/ma17092100
    7. Andreas Kiesow, Maria Morawietz, Jennifer Gruner, Stephan Gierth, Lutz Berthold, Eva Schneiderman, Samuel St. John. High-Resolution Characterization of Enamel Remineralization Using Time-of-Flight Secondary Ion Mass Spectrometry and Electron Microscopy. Caries Research 2024, 58 (4) , 407-420. https://doi.org/10.1159/000535979
    8. Jana Storsberg, Kateryna Loza, Matthias Epple. Incorporation of Fluoride into Human Teeth after Immersion in Fluoride-Containing Solutions. Dentistry Journal 2022, 10 (8) , 153. https://doi.org/10.3390/dj10080153
    9. Matthias Epple, Joachim Enax, Frederic Meyer. Prevention of Caries and Dental Erosion by Fluorides—A Critical Discussion Based on Physico-Chemical Data and Principles. Dentistry Journal 2022, 10 (1) , 6. https://doi.org/10.3390/dj10010006
    10. Hui Shi, Ziqi Zhou, Wuda Li, Yuan Fan, Zhihua Li, Junchao Wei. Hydroxyapatite Based Materials for Bone Tissue Engineering: A Brief and Comprehensive Introduction. Crystals 2021, 11 (2) , 149. https://doi.org/10.3390/cryst11020149
    11. Xiao-Jiao Guo, Xiao-Yu Yuan, Si-Rui Zhao, Jin-Ku Liu, Xi-Zi Xue, Ya-Nan Xue. Improving anticorrosion performance of hydroxyapatite via controlling exposed crystal surface and applications. Journal of Alloys and Compounds 2020, 845 , 156290. https://doi.org/10.1016/j.jallcom.2020.156290
    12. Faisal Madi, Sharanbir K. Sidhu, John W. Nicholson. The effect of temperature and ionic solutes on the fluoride release and recharge of glass-ionomer cements. Dental Materials 2020, 36 (1) , e9-e14. https://doi.org/10.1016/j.dental.2019.11.018
    13. Jasmin Kirsch, Matthias Hannig, Pia Winkel, Sabine Basche, Birgit Leis, Norbert Pütz, Anna Kensche, Christian Hannig. Influence of pure fluorides and stannous ions on the initial bacterial colonization in situ. Scientific Reports 2019, 9 (1) https://doi.org/10.1038/s41598-019-55083-0
    14. D. Sivaraj, K. Vijayalakshmi. Substantial effect of magnesium incorporation on hydroxyapatite/carbon nanotubes coatings on metallic implant surfaces for better anticorrosive protection and antibacterial ability. Journal of Analytical and Applied Pyrolysis 2018, 135 , 15-21. https://doi.org/10.1016/j.jaap.2018.09.027

    ACS Biomaterials Science & Engineering

    Cite this: ACS Biomater. Sci. Eng. 2017, 3, 8, 1822–1826
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsbiomaterials.6b00782
    Published June 2, 2017
    Copyright © 2017 American Chemical Society

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