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    Enhanced Catalysis Based on the Surface Environment of the Silica-Supported Metal Complex
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    • Ken Motokura*
      Ken Motokura
      Department of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
      Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8502, Japan
      *Email: [email protected]
      More by Ken Motokura
      Orcidhttps://orcid.org/0000-0002-0066-5139
    • Siming Ding
      Siming Ding
      Department of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
      Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8502, Japan
      More by Siming Ding
    • Kei Usui
      Kei Usui
      Department of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
      Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8502, Japan
      More by Kei Usui
    • Yuanyuan Kong
      Yuanyuan Kong
      Department of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
      Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8502, Japan
      More by Yuanyuan Kong
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    ACS Catalysis

    Cite this: ACS Catal. 2021, 11, 19, 11985–12018
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    https://doi.org/10.1021/acscatal.1c03426
    Published September 13, 2021
    Copyright © 2021 American Chemical Society
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    Abstract

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    Silica-supported metal complex catalysts have been developed and used for organic transformations. The surface environment around the supported metal complex enhances the catalysis based on a unique surface effect. The design of the linker ligand structure induces the formation of a highly reactive, coordinatively unsaturated metal complex on the silica surface because of the isolated environment. In contrast to the site-isolation effect, the accumulated metal complexes and cocatalysts on the same surface facilitate the acceleration of the catalytic reaction by concerted catalysis. The immobilization of multiactive sites also promotes the tandem catalysis and development of complex products from simple molecules through successive reactions. Surface silanol species originating from the silica support also participate in the catalysis. The control of the immobilization density/location of metal complex/coimmobilized functionality/surface silanol is a key factor for the achievement of site-isolation/concerted catalysis. The direct interaction between the metal complex and coimmobilized functionality facilitates the formation of unique reactive species. The confinement effect of the pore structure of the support enhances the accumulation of active species in mesopores, which boosts the reaction rate, and slightly changes the ligand conformation, which increases the enantioselectivity. The direct support electronic effect is also one of the key factors affecting the surface organometallic chemistry (SOMC) and photooxidation of linker metal complexes. These acceleration effects were detected in both supported homogeneous catalysis and SOMC. Not only the local structure of the metal complex and its ligand but also the surface environment play the most important roles in enhancing the catalysis. In this Review, representative examples of silica-supported metal complexes whose catalysis is significantly enhanced by their surface long-range environment are summarized. The contributions of recent developments of spectroscopic techniques, including DNP-enhanced solid-state NMR and XAFS, which support the evaluation of such long-range interactions, are also discussed. The surface design of the silica-supported metal complex facilitates highly active, selective, and durable catalysis.

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    14. Yi Shen, Yu Mu, Dunwei Wang, Chong Liu, Paula L. Diaconescu. Tuning Electrode Reactivity through Organometallic Complexes. ACS Applied Materials & Interfaces 2023, 15 (24) , 28851-28878. https://doi.org/10.1021/acsami.3c01726
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    17. Till Wissel, Lorenz Rösler, Martin Brodrecht, Mark V. Höfler, Kevin Herr, Marcos de Oliveira, Vytautas Klimavicius, Martin Ebert, Hergen Breitzke, Markus Hoffmann, Gerd Buntkowsky, Torsten Gutmann. Novel Heterogeneous Pd Catalysts for Cross‐Coupling Reactions in Biocompatible Media: Structural Insights from Solid‐State NMR Techniques. ChemCatChem 2025, 17 (5) https://doi.org/10.1002/cctc.202401511
    18. Antony E. Fernandes, Alain M. Jonas. Design of Multicatalytic Systems Through Self-Assembly. Catalysts 2025, 15 (3) , 265. https://doi.org/10.3390/catal15030265
    19. Zinnia Arora, Meriem Rais, Vasile I. Pârvulescu, Karine Philippot, Jérôme Durand, Maryse Gouygou. Non‐Covalent Immobilization of Chiral Rhodium Catalysts on Carbon Nanotubes for Asymmetric Hydrogenation. ChemNanoMat 2025, 11 (2) https://doi.org/10.1002/cnma.202400125
    20. Qianqian Pan, Qing Liu, Yuling Shi, Danlong Yang, Yangeng Lan, Tao Wang. A facile strategy for freeze-drying preparation of silica aerogel from sodium silicate. Ceramics International 2025, 51 (4) , 5342-5350. https://doi.org/10.1016/j.ceramint.2024.11.508
    21. Shengjin Tan, Shangyuan Zhao, Panpan Zhang, Peisen Liu, Qizhong Xiong, Chaochun Zhang, Gang Xu, Xian-Lei Shi, Yusef Kianpoor Kalkhajeh, Xinxin Ye. Polyacrylonitrile fiber supported nano zero-valent iron activated persulfate to degrade organophosphorus and simultaneously adsorb the produced phosphate. Environmental Technology & Innovation 2025, 37 , 103912. https://doi.org/10.1016/j.eti.2024.103912
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    25. A. V. Nartova, R. I. Kvon, L. M. Kovtunova, A. M. Dmitrachkov, I. V. Skovpin, V. I. Bukhtiyarov. XPS study of the stability variations of [M(COD)Cl]2 (M = Ir, Rh) complexes anchored on modified silica in reactions of spin-selective hydrogenation of unsaturated hydrocarbons by parahydrogen. Kinetika i kataliz 2024, 65 (2) , 214-223. https://doi.org/10.31857/S0453881124020096
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    51. M. DeJong, A. J. A. Price, E. Mårsell, G. Tom, G. D. Nguyen, E. R. Johnson, S. A. Burke. Small molecule binding to surface-supported single-site transition-metal reaction centres. Nature Communications 2022, 13 (1) https://doi.org/10.1038/s41467-022-35193-6
    52. Yeonjoon Kim, Mohammed A. Jabed, David M. Price, Dmitri Kilin, Seonah Kim. Toward rational design of supported vanadia catalysts of lignin conversion to phenol. Chemical Engineering Journal 2022, 446 , 136965. https://doi.org/10.1016/j.cej.2022.136965
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    54. Lingmin Sun, Junshu Wu, Jinshu Wang, Yunfei Yang, Wenyuan Zhou, Yilong Yang, Yucheng Du, Peng Hu, Yongli Li, Hongyi Li. CO2-assisted ‘Weathering’ of Steel Slag-Derived Calcium Silicate Hydrate: A Generalized Strategy for Recycling Noble Metals and Constructing SiO2-Based Nanocomposites. Journal of Colloid and Interface Science 2022, 622 , 1008-1019. https://doi.org/10.1016/j.jcis.2022.04.182
    55. Dake Zhang, Haiting Cai, Yize Su, Wei Sun, Deren Yang, Geoffrey A. Ozin. Silica samurai: Aristocrat of energy and environmental catalysis. Chem Catalysis 2022, 2 (8) , 1893-1918. https://doi.org/10.1016/j.checat.2022.06.001
    56. Elena Bekyarova, Matthew P. Conley. The coordination chemistry of oxide and nanocarbon materials. Dalton Transactions 2022, 51 (22) , 8557-8570. https://doi.org/10.1039/D2DT00459C
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    ACS Catalysis

    Cite this: ACS Catal. 2021, 11, 19, 11985–12018
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acscatal.1c03426
    Published September 13, 2021
    Copyright © 2021 American Chemical Society
    Request reuse permissions

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