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Desulfonylative Transformations of Sulfones by Transition-Metal Catalysis, Photocatalysis, and Organocatalysis

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Download Hi-Res ImageDownload to MS-PowerPointCite This:ACS Catal. 2022, 12, 5, 3013-3032
    Review

    Desulfonylative Transformations of Sulfones by Transition-Metal Catalysis, Photocatalysis, and Organocatalysis
    Click to copy article linkArticle link copied!

    • Masakazu Nambo*
      Masakazu Nambo
      Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University, Chikusa, Nagoya, Japan, 464-8602
      *E-mail: [email protected] (M. Nambo).
      More by Masakazu Nambo
      Orcidhttps://orcid.org/0000-0003-0153-3178
    • Yuuki Maekawa
      Yuuki Maekawa
      Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University, Chikusa, Nagoya, Japan, 464-8602
      Department of Chemistry, Queen’s University, Chernoff Hall, Kingston, Ontario, Canada, K7L 4 V1
      More by Yuuki Maekawa
    • Cathleen M. Crudden*
      Cathleen M. Crudden
      Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University, Chikusa, Nagoya, Japan, 464-8602
      Department of Chemistry, Queen’s University, Chernoff Hall, Kingston, Ontario, Canada, K7L 4 V1
      *E-mail: [email protected] (C. M. Crudden).
      More by Cathleen M. Crudden
      Orcidhttps://orcid.org/0000-0003-2154-8107
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    ACS Catalysis

    Cite this: ACS Catal. 2022, 12, 5, 3013–3032
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    https://doi.org/10.1021/acscatal.1c05608
    Published February 18, 2022
    Copyright © 2022 American Chemical Society
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    Abstract

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    Sulfones are common, readily available reagents that have recently attracted attention as versatile reagents for cross-coupling reactions. This Review summarizes advances in desulfonylative transformations of sulfones affected by molecular catalysis, including transition-metal catalysts, photocatalysts, and organocatalysts. In addition to catalyst choice, the design of the sulfonyl group is a critical factor to control reactivity. The concepts presented herein will provide new strategies to construct diverse molecules with high efficiency and modularity.

    Copyright © 2022 American Chemical Society

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    Cited By

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    This article is cited by 27 publications.

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    ACS Catalysis

    Cite this: ACS Catal. 2022, 12, 5, 3013–3032
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acscatal.1c05608
    Published February 18, 2022
    Copyright © 2022 American Chemical Society
    Request reuse permissions

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